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EP0070634A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Visible light curable sealants

Assignee: Dentsply Sirona Inc
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Filing: 1982-06-28
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Granted: —
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Expires: 2002-06-28
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Abstract

Abstract Visible light curable dental sealants are provided having improved color stability. According to a preferred embodiment, such materials are formulated from about 30% to about 60% by weight of particulate, inorganic fillers and a resin component comprising a binder resin, a diluent, and a two-component photosensitizing system comprising an alpha diketone and an amine reducing agent. Sealing processes employing such sealants are also disclosed.

Inventors

  • 👤 Wu Lan Wang

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-27 12:01
CPC Classifications
A; A61; A61K; A61K6/00; A61K6/80; A61K6/884; A61K6/887

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 76 words
A dental sealant curable by irradiation with visible light comprising: from about 30% to about 60% by weight of a particulate, inorganic filler,, and from about 40% to about 70% of a polymerizable resin component comprising: a binder resin, a diluent monomer, and a photosensitizing system comprising: an alpha diketone, and an amine reducing agent, said photosensitizing system being present in an amount sufficient to cause substantial polymerization of said sealant upon irradiation with visible light.
Claim 2
Dependent Claim 76 words
A dental sealant curable by irradiation with visible light comprising: from about 30% to about 60% by weight of a particulate, inorganic filler,, and from about 40% to about 70% of a polymerizable resin component comprising: a binder resin, a diluent monomer, and a photosensitizing system comprising: an alpha diketone, and an amine reducing agent, said photosensitizing system being present in an amount sufficient to cause substantial polymerization of said sealant upon irradiation with visible light.
Claim 3
Dependent Claim 68 words
The sealant of claim 1 wherein said binder resin is selected from the group consisting of acrylated polyesters, acrylated polyesters reacted with isocyanates, and hydroxyalkyl acrylic species reacted with isocyanates, said alpha diketone is selected from the group consisting of camphoroquinone, benzil, biacetyl, 9,10-phenanthrenequinone, and naphthoquinone, said amine is either N-alkyl dialkanolamine or trialkanolamine, and said fillers are selected from the group consisting of inorganic glasses and silica.
Claim 4
Dependent Claim 36 words
The sealant of claim 1 or 2 wherein said alpha diketone is present in an amount of from about 0.05% to about 0.30% based upon the total weight of said binder resin, diluent and photosensitizing system.
Claim 5
Dependent Claim 22 words
The sealant of claim 1 wherein said filler is present in an amount of from about 45% to about 55% by weight.
Claim 6
Dependent Claim 15 words
The sealant of claim 1 having a viscosity between about 35,000 and about 70,000 centipoises.
Claim 7
Dependent Claim 91 words
A process of sealing teeth comprising: applying to a prepared tooth a dental sealant curable by irradiation with visible light comprising: from about 30% to about 60% of a particulate, inorganic filler, and a polymerizable resin component comprising: a binder resin, a diluent monomer, and a photosensitizing system comprising: an alpha diketone, and an amine reducing agent, said photosensitizing system being present in an amount sufficient to cause substantial polymerization of said composition upon irradiation with visible light, and . exposing said composition to visible light to effect substantial polymerization thereof.
Claim 8
Dependent Claim 91 words
A process of sealing teeth comprising: applying to a prepared tooth a dental sealant curable by irradiation with visible light comprising: from about 30% to about 60% of a particulate, inorganic filler, and a polymerizable resin component comprising: a binder resin, a diluent monomer, and a photosensitizing system comprising: an alpha diketone, and an amine reducing agent, said photosensitizing system being present in an amount sufficient to cause substantial polymerization of said composition upon irradiation with visible light, and . exposing said composition to visible light to effect substantial polymerization thereof.
Claim 9
Dependent Claim 68 words
The process of claim 6 wherein said binder resin is selected from the group consisting of acrylated polyesters, acrylated polyesters reacted with isocyanates, and hydroxyalkyl acrylic species reacted with isocyanates, said alpha diketone is selected from the group consisting of camphoroquinone, benzil, biacetyl, 9,10-phenanthrenequinone, and naphthoquinone, said amine is either N-alkyl dialkanolamine or trialkanolamine, and said fillers are selected from the group consisting of inorganic glasses and silica.
Claim 10
Dependent Claim 36 words
The process of claim 6 or 7 wherein said alpha diketone is present in an amount of from about 0.05% to about 0.30% based upon the total weight of said binder resin, diluent, and photosensitizing system.
Claim 11
Dependent Claim 20 words
The process of claim 6 or 7 wherein said light is composed predominantly of wavelengths longer than about 4,000 angstroms.
Claim 12
Dependent Claim 21 words
The process of claim 6 wherein said filler is present in amount of from about 45% to about 55% by weight.
Claim 13
Dependent Claim 19 words
The process of claim 6 wherein said sealant has a viscosity of from about 35,000 to about 70,000 centipoises.

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