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EP0061823A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Synergistically thickened water-based hydraulic or metal-working fluid

Assignee: BASF Corp
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Filing: 1982-01-25
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Granted: —
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Expires: 2002-01-25
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Abstract

Abstract Water-based hydraulic fluids and metalworking lubricants are disclosed which are thickened with a polyether polyol having a molecular weight of about 1000 to about 75,000 modified with an alpha-olefin epoxide having about 12 to about 18 carbon atoms. Unexpectedly, synergistic thickening results from a combination of said polyether polyol with the components of a water-based hydraulic fluid or metalworking lubricant. The particularly effective components of the hydraulic fluid or metalworking lubricant are the phosphate ester and water-soluble amine corrosion inhibitor components. The hydraulic fluid and metalworking fluids of the invention also contain a water-soluble polyoxyethylated ester of an aliphatic acid and a monohydric or polyhydric aliphatic alcohol, either one or both said acid and said alcohol being polyoxyethylated, a sulfurized molybdenum or antimony compound and a metal deactivator as well as other adjuvants conventional in this art.

Inventors

  • 👤 Assadullah Nassry
  • 👤 Jerrold F. Maxwell
  • 👤 John W. Compton
  • 👤 Edward J. Panek
  • 👤 Pauls Davis

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 23:18
CPC Classifications
C; C10; C10M; C10M173/00; C10M173/02; C10M2201/00; C10M2201/02; C10M2201/08; C10M2201/081; C10M2201/082; C10M2201/084; C10M2207/00; C10M2207/10; C10M2207/14; C10M2207/141; C10M2209/00; C10M2209/10; C10M2209/103; C10M2209/104; C10M2209/107; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/042; C10M2215/14; C10M2215/22; C10M2215/221; C10M2215/225; C10M2215/226; C10M2215/24; C10M2215/26; C10M2215/30; C10M2219/00; C10M2219/04; C10M2219/044; C10M2219/10; C10M2219/102; C10M2219/104; C10M2219/106; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/042; C10M2223/043; C10M2223/045; C10M2225/00; C10M2225/02; C10N; C10N2010/00; C10N2010/10; C10N2010/12; C10N2040/00; C10N2040/08; C10N2040/20; C10N2040/22; C10N2050/00; C10N2050/01; C10N2070/00; C10N2070/02

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 407 words
A hydraulic fluid or metalworking fluid concentrate capable of imparting to water the properties of a lubricant such as resistance to extreme pressure and corrosion inhibition, said concentrate consisting essentially of: A. a water-soluble polyoxyethylated aliphatic ester consisting of esters of ethoxylated aliphatic monohydric and polyhydric alcohols and ethoxylated aliphatic acids wherein said acids have about 5 to about 20 moles of ethylene oxide added per mole of acid and wherein said alcohols and acids have carbon chain lengths of 8 to 36 carbon atoms and wherein said esters are produced by first polyoxyethylating at least one of said acids or alcohols and second, obtaining the ester reaction product thereof, B. a sulfurized metallic compound of the formula: wherein M is molybdenum or antimony and wherein R is selected from the group consisting of alkyl, aryl, alkylaryl radicals and mixtures thereof having 3 to 20 carbon atoms in the alkyl group and wherein the ratio of said water-soluble ester to said sulfurized metallic compound is from 5:1 to 2:1 by weight based upon the weight of the sulfur in said metallic compound, C. a phosphate ester salt selected from the group consisting of and mixtures thereof, wherein EO is ethylene oxide; R is selected from the group consisting of linear or branched chain alkyl groups having about 6 to 30 carbon atoms or alkylaryl groups wherein said alkyl groups have 6 to 30 carbon atoms; X is selected from the residue of ammonia, an amine and an alkali or alkaline earth metal or mixtures thereof, n is a number from 1 to 50 and wherein the proportion of said phosphate ester to said sulfurized metallic compound is about 0.1:1 to about 2:1 based upon the weight of the sulfur in said metallic compound, D. a polyether polyol thickener having a molecular weight of about 1000 to about 75,000, prepared by reacting ethylene oxide or ethylene oxide and at least one lower alkylene oxide having 3 to 4 carbon atoms with at least one active hydrogen-containing compound containing at least two active hydrogens and at least one alpha-olefin oxide or at least one glycidyl ether having a carbon chain length of about 12 to about 18 aliphatic carbon atoms and wherein said alpha-olefin oxide or glycidyl ether is present in the amount of 1 to about 20 percent by weight based upon the total weight of said thickener, and optionally E. a corrosion inhibitor and a metal deactivator.
Claim 2
Dependent Claim 407 words
A hydraulic fluid or metalworking fluid concentrate capable of imparting to water the properties of a lubricant such as resistance to extreme pressure and corrosion inhibition, said concentrate consisting essentially of: A. a water-soluble polyoxyethylated aliphatic ester consisting of esters of ethoxylated aliphatic monohydric and polyhydric alcohols and ethoxylated aliphatic acids wherein said acids have about 5 to about 20 moles of ethylene oxide added per mole of acid and wherein said alcohols and acids have carbon chain lengths of 8 to 36 carbon atoms and wherein said esters are produced by first polyoxyethylating at least one of said acids or alcohols and second, obtaining the ester reaction product thereof, B. a sulfurized metallic compound of the formula: wherein M is molybdenum or antimony and wherein R is selected from the group consisting of alkyl, aryl, alkylaryl radicals and mixtures thereof having 3 to 20 carbon atoms in the alkyl group and wherein the ratio of said water-soluble ester to said sulfurized metallic compound is from 5:1 to 2:1 by weight based upon the weight of the sulfur in said metallic compound, C. a phosphate ester salt selected from the group consisting of and mixtures thereof, wherein EO is ethylene oxide; R is selected from the group consisting of linear or branched chain alkyl groups having about 6 to 30 carbon atoms or alkylaryl groups wherein said alkyl groups have 6 to 30 carbon atoms; X is selected from the residue of ammonia, an amine and an alkali or alkaline earth metal or mixtures thereof, n is a number from 1 to 50 and wherein the proportion of said phosphate ester to said sulfurized metallic compound is about 0.1:1 to about 2:1 based upon the weight of the sulfur in said metallic compound, D. a polyether polyol thickener having a molecular weight of about 1000 to about 75,000, prepared by reacting ethylene oxide or ethylene oxide and at least one lower alkylene oxide having 3 to 4 carbon atoms with at least one active hydrogen-containing compound containing at least two active hydrogens and at least one alpha-olefin oxide or at least one glycidyl ether having a carbon chain length of about 12 to about 18 aliphatic carbon atoms and wherein said alpha-olefin oxide or glycidyl ether is present in the amount of 1 to about 20 percent by weight based upon the total weight of said thickener, and optionally E. a corrosion inhibitor and a metal deactivator.
Claim 3
Dependent Claim 43 words
The composition of claim 1, wherein said phosphate ester is the ester of the reaction product of 4 moles of ethylene oxide with 1 mole of oleyl alcohol esterified by reacting 1 mole of said reaction product with 2 moles of phosphorus pentoxide.
Claim 4
Dependent Claim 38 words
A hydraulic fluid or metalworking lubricant fluid consisting essentially of water and the concentrate of claim 2,wherein said fluid consists of about 60 percent to about 99 percent water and about 40 percent to about 1 percent concentrate.
Claim 5
Dependent Claim 32 words
A hydraulic fluid or metalworking composition consisting essentially of water and the concentrate of claim 2 , wherein said concentrate consists of about 50 percent to about 80 percent of said thickener.
Claim 6
Dependent Claim 30 words
The hydraulic fluid of claim 3, wherein said corrosion inhibitor is selected from the group consisting of an alkali metal benzoate, nitrate and nitrite, an amine, and . mixtures thereof.
Claim 7
Dependent Claim 13 words
The hydraulic fluid of claim 5, wherein said amine corrosion inhibitor is morpholine.
Claim 8
Dependent Claim 15 words
The composition of claim 6, wherein said metal deactivator is the triethanolamine salt of 2-mercaptobenzothiazole.
Claim 9
Dependent Claim 24 words
The thickener of claim 2, wherein said polyether polyol is prepared by copolymerizing a mixture of said reactants to produce a liquid heteric copolymer.
Claim 10
Dependent Claim 66 words
The thickener of claim 2, wherein said polyether polyol is prepared by copolymerizing a mixture of ethylene oxide and at least one of said lower alkylene oxides in the presence of said initiator selected from the group consisting of alkane monoalcohols, alkene monoalcohols, and alkyne monoalcohols to produce a liquid heteric copolymer intermediate and subsequently reacting said intermediate with at least one of said alpha-olefin oxides.
Claim 11
Dependent Claim 47 words
. . 10. The thickener of claim 2, wherein said polyether polyol is prepared by sequentially reacting ethylene oxide with at least one of said lower alkylene oxides to produce a block copolymer intermediate and subsequently reacting said intermediate with at least one of said alpha-olefin oxides.
Claim 12
Dependent Claim 55 words
The thickener of claim 9 wherein said lower alkylene oxides are selected from the group consisting of propylene oxide,1,2-butylene oxide, 1 + 3 butylene oxide,1,4-butylene oxide, 2,3-butylene oxide, and tetrahydrofuran and wherein the proportion of ethylene oxide residue in said thickener is at least 10 percent by weight of the total weight of said thickener.
Claim 13
Dependent Claim 70 words
The thickener of claim 11 whereinthe proportion of ethylene oxide residue to the residue of said lower alkylene oxides is from about 70 to about 99 percent by weight of ethylene oxide residue to about 30 to about 1 percent by weight of said lower alkylene oxide residue and said active hydrogen-containing compound is a polyhydric alcoholhaving from 2 to 10 carbon atoms and from 2 to 6 hydroxyl groups.
Claim 14
Dependent Claim 62 words
The thickener of claim 12wherein said initiator is an alkane polyol selected from the group consisting of at least one of trimethylolpropane, glycerol,2,3,5,6-hexane- tetrol, sorbitol, and pentaerythritol and the molar ratio of said initiator to the combined molar amounts of said ethylene oxide, said lower alkylene oxides, and said alpha-olefin oxide is in a mole ratio of about 1:5 to about 1:15.
Claim 15
Dependent Claim 17 words
A process of metalworking comprising working metal in the presence of the metalworking composition of claim 4.
Claim 16
Dependent Claim 18 words
A process for the transmitting of force hydraulically comprising transmitting force utilizing the hydraulic fluid of claim 3.

References Cited (Backward Citations)

US3829506A Cited
US4151099A Cited

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