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EP0054587A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Metal diphthalocyanine electrochromic displays and electrolytes therefor

Assignee: International Business Machines Corp
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Filing: 1980-12-19
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Granted: —
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Expires: 2000-12-19
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Abstract

Abstract The lifetime of a metal diphthalocyanine electrochromic display can be substantially extended by employing a predominantly non-aqueous low hydroxyl ion electrolyte. A preferred electrolyte solvent is ethylene glycol and preferred conductivity salts are tetraethyl ammonium fluoride and sodium chloride. In the case of sodium chloride, conductivity is improved by the addition of up to 25% water to the electrolyte.

Inventors

  • 👤 Gilbert Christopher Collins
  • 👤 David Jorge Schiffrin

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-28 22:22
CPC Classifications
C; C09; C09K; C09K9/00; C09K9/02; G; G02; G02F; G02F1/00; G02F1/01; G02F1/15; G02F1/1514; G02F1/1516

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 61 words
An electrochromic display having display electrodes and a counter electrode, a layer on the display electrodes comprising an electrochromic metal diphthalocyanine or modified diphthalocyanine and a liquid electrolyte in contact with the electrochromic layer and comprising a conductivity salt dissolved in a solvent, characterised in that the solvent is predominantly non-aqueous and the electrolyte contains no other source of hydroxyl ions.
Claim 2
Dependent Claim 61 words
An electrochromic display having display electrodes and a counter electrode, a layer on the display electrodes comprising an electrochromic metal diphthalocyanine or modified diphthalocyanine and a liquid electrolyte in contact with the electrochromic layer and comprising a conductivity salt dissolved in a solvent, characterised in that the solvent is predominantly non-aqueous and the electrolyte contains no other source of hydroxyl ions.
Claim 3
Dependent Claim 21 words
An electrochromic display as claimed in claim 1 in which the solvent contains no more than 25% by weight of water.
Claim 4
Dependent Claim 18 words
An electrochromic display as claimed in claim 2 in which the solvent is substantially free of hydroxyl ions.
Claim 5
Dependent Claim 32 words
An electrochromic display as claimed in any preceeding claim in which the solvent or its non-aqueous portion is either a polyhydric alcohol, a polyhydric ether or a glyme or a mixture thereof.
Claim 6
Dependent Claim 19 words
An electrochromic display as claimed in claim 4 in which the solvent or its non-aqueous portion is ethylene glycol.
Claim 7
Dependent Claim 35 words
An electrochromic display as claimed in any preceeding claim in which the conductivity salt is sodium chloride and the solvent is a mixture of ethylene glycol and no more than 25% by weight of water.
Claim 8
Dependent Claim 25 words
An electrochromic display as claimed in any one of claims 1 to 5 in which the conductivity salt is an organic ionic chloride or fluoride.
Claim 9
Dependent Claim 24 words
An electrochromic display as claimed in claim 7 in which the solvent consists of ethylene glycol and the conductivity salt is tetraethyl ammonium fluoride.
Claim 10
Dependent Claim 19 words
An electrochromic display as claimed in any preceeding claim in which the electrochromic metal diphthalocyanine complex is lutetium diphthalocyanine.
Claim 11
Dependent Claim 18 words
An electrochromic display as claimed in any preceeding claim in which the display electrodes are made of platinum.

References Cited (Backward Citations)

DE2125337A1 Cited
GB1356120A Cited
US3960740A Cited
DE2523832A1 Cited
GB1535594A Cited
DE2707099A1 Cited
US4192581A Cited
DE2756551A1 Cited
US4184751A Cited
WO1980002462A1 Cited

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