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EP0049155A2
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Production of silane modified copolymers of alkylene-alkyl acrylates, polysiloxanes having combined therein organo titanates used in their production, process for producing such polysiloxanes, and electrical conductors insulated by cured silane modified copolymers
Assignee: Union Carbide Corp
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Filing: 1981-09-29
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Granted: —
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Expires: 2001-09-29
Abstract
Abstract The disclosure of this application is directed to the production of silane modified copolymers of alkylene-alkyl acrylates by reacting a mixture containing a polysiloxane and a copolymer of alkylene-alkyl acrylate to produce a water-curable, silane modified copolymer. The polysiloxanes have the repeating unit: wherein R is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group and Z is a hydrolyzable group, n is an integer having a value of 1 to 18 inclusive, Z is a hydrolyzable group, and x is an integer having a value of at least 2. The silane modified copolymers can be extruded about electrical conductors, e.g. wires and cables, to provide insulation thereon characterized by improved surface characteristics.
Inventors
- 👤 Michael John Keogh
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-10 01:27
CPC Classifications
C; C08; C08G; C08G81/00; C08G81/02; H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/46; A; A61; A61K; A61K36/00; A61K36/18; A61K36/185; A61K36/68; A61K9/00; A61K9/14; A61K9/16; A61K9/1605; A61K9/1629; A61K9/1635; A61K9/1641; A61K9/48; A61K9/50; A61K9/5005; A61K9/5021; A61K9/5026; A61K9/5031; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; C08F; C08F8/00; C08F8/42; C08G77/00; C08G77/60; C08G81/024; C08L; C08L83/00; C08L83/16; H01B3/44; H01B3/441
Claims Analysis
Total Claims: 33
Claim 1
Independent Claim
83 words
A process of producing a water-curable, silane modified alkylene-alkyl acrylate copolymer which comprises reacting a mixture containing an alkylene-alkyl acrylate copolymer; a polysiloxane having the repeating unit: wherein R is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group and Z is a hydrolyzable group, n is an integer having a value of 1 to 18 inclusive, Z is a hydrolyzable group, and x is an integer having a value of at least 2; and an organic titanate.
Claim 2
Dependent Claim
83 words
A process of producing a water-curable, silane modified alkylene-alkyl acrylate copolymer which comprises reacting a mixture containing an alkylene-alkyl acrylate copolymer; a polysiloxane having the repeating unit: wherein R is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group and Z is a hydrolyzable group, n is an integer having a value of 1 to 18 inclusive, Z is a hydrolyzable group, and x is an integer having a value of at least 2; and an organic titanate.
Claim 3
Dependent Claim
18 words
A process as claimed in claim 1 when conducted at a temperature of about 80°C to about 300°C.
Claim 4
Dependent Claim
18 words
A process as claimed in claim 2 when conducted at a temperature of about 150°C to about 230°C.
Claim 5
Dependent Claim
28 words
A process as claimed in any one of the preceding claims wherein the organo titanate has the formula: wherein each R 2 is hydrogen or a hydrocarbon radical.
Claim 6
Dependent Claim
22 words
A process as claimed in claim 4 wherein each R 2 is an alkyl radical having 1 to 18 carbon atoms inclusive.
Claim 7
Dependent Claim
21 words
A process as claimed in any one of the preceding claims wherein the said copolymer is a copolymer of ethylene-ethyl acrylate.
Claim 8
Dependent Claim
31 words
A process as claimed in any one of the preceding claims wherein R in the repeating unit of the silane is an alkylene radical having 1 to 18 carbon atoms inclusive.
Claim 9
Dependent Claim
22 words
A process as claimed in claim 7 wherein R in the repeating unit of the silane is -CH 2 -CH 2 -.
Claim 10
Dependent Claim
23 words
A process as claimed in any one of the preceding claims wherein each V in the repeating unit of the silane is methoxy.
Claim 11
Dependent Claim
21 words
A process as claimed in any one of the preceding claims wherein the organo titanate is tetraisopropyl titanate or tetrabutyl titanate.
Claim 12
Dependent Claim
38 words
A process as claimed in any one of the preceding claims wherein the organo titanate is present in an amount of about 0.001 to about 25 percent by weight based on the combined weight of copolymer and polysiloxane.
Claim 13
Dependent Claim
35 words
A process as claimed in any one of the preceding claims wherein the polysiloxane is present in an amount of about 0.5 to about 10 percent by weight based on the weight of the copolymer.
Claim 14
Dependent Claim
18 words
A process as claimed in any one of the preceding claims wherein the polysiloxane contains combined organo titanate.
Claim 15
Dependent Claim
59 words
A polysiloxane having the repeating unit wherein R is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group, Z is a hydrolyzable group, n is an integer having a value of 1 to 18 inclusive and x is an integer having a value of at least 2, and containing an organo titanate combined therein.
Claim 16
Dependent Claim
59 words
A polysiloxane having the repeating unit wherein R is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group, Z is a hydrolyzable group, n is an integer having a value of 1 to 18 inclusive and x is an integer having a value of at least 2, and containing an organo titanate combined therein.
Claim 17
Dependent Claim
20 words
A polysiloxane as claimed in claim 14 wherein R is an alkylene radical having 1 to 18 carbon atoms inclusive.
Claim 18
Dependent Claim
24 words
A polysiloxane as claimed in claim 14 or claim 15 wherein each V is an alkoxy radical having 1 to 18 carbon atoms inclusive.
Claim 19
Dependent Claim
25 words
A polysiloxane as claimed in any one of claims 14 to 16 wherein Z is an alkoxy radical having 1 to 18 carbon atoms inclusive.
Claim 20
Dependent Claim
21 words
A polysiloxane as claimed in claim 17 wherein R is -CH 2 CH 2 -, and V and Z are methoxy.
Claim 21
Dependent Claim
24 words
A polysiloxane as claimed in claim 17 wherein R is -CH 2 CH 2 -, Z is methoxy, one V is methoxy and dodecoxy.
Claim 22
Dependent Claim
24 words
A polysiloxane as claimed in claim 17 wherein R is -CH 2 CH 2 -, Z is methoxy and V is alkyl and methoxy.
Claim 23
Dependent Claim
22 words
A polysiloxane as claimed in any one of claims 14 to 20 wherein the organo titanate is tetraisopropyl titanate or tetrabutyl titanate.
Claim 24
Dependent Claim
22 words
A polysiloxane as claimed in any one of claims 14 to 21 wherein x has a value of 5 to 25 inclusive.
Claim 25
Dependent Claim
88 words
A polysiloxane having the repeating unit wherein R is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group, Z is a hydrolyzable group, n is an integer having a value of 1 to 18 inclusive and x is an integer having a value of at least 2, and containing an organo titanate combined therein, produced by reacting a mixture containing an organic titanate and a silane having the formula: wherein R is a hydrocarbon radical and the other variables are as previously defined.
Claim 26
Dependent Claim
88 words
A polysiloxane having the repeating unit wherein R is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group, Z is a hydrolyzable group, n is an integer having a value of 1 to 18 inclusive and x is an integer having a value of at least 2, and containing an organo titanate combined therein, produced by reacting a mixture containing an organic titanate and a silane having the formula: wherein R is a hydrocarbon radical and the other variables are as previously defined.
Claim 27
Dependent Claim
75 words
A process of producing an organo titanate modified polysiloxane which comprises reacting a mixture containing an organo titanate and a silane of the formula: wherein R is a hydrocarbon radical, R is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group, Z is a hydrolyzable group, n is an integer having a value of 1 to 18 inclusive, and x is an integer having a value of at least 2.
Claim 28
Dependent Claim
75 words
A process of producing an organo titanate modified polysiloxane which comprises reacting a mixture containing an organo titanate and a silane of the formula: wherein R is a hydrocarbon radical, R is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group, Z is a hydrolyzable group, n is an integer having a value of 1 to 18 inclusive, and x is an integer having a value of at least 2.
Claim 29
Dependent Claim
33 words
A process as claimed in claim 24 wherein the organo titanate is present in an amount of about 0.001 to about 25 percent by weight based on the weight of the said silane.
Claim 30
Dependent Claim
21 words
A process as claimed in claim 24 or claim 25 when conducted at a temperature of about 0°C to about 250°C.
Claim 31
Dependent Claim
29 words
A process as claimed in any one of claims 24 to 26 wherein the organo titanate has the formula: wherein each R 2 is hydrogen or a hydrocarbon radical.
Claim 32
Dependent Claim
30 words
A process as claimed in any one of claims 24 to 27 wherein said mixture contains an end blocker having the formula: wherein each R 3 is a hydrocarbon radical.
Claim 33
Dependent Claim
36 words
An electrical conductor, such as a wire or cable, having an insulation formed by water-curing a water-curable silane modified alkylene-alkyl acrylate copolymer produced by a process as claimed in any one of claims 1 to 13.
References Cited (Backward Citations)
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