Patent EP0048439A1 successfully refreshed from Google Patents.
EP0048439A1
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Norbornene polymers containing bound antioxidant
Assignee: Goodrich Corp
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Filing: 1981-09-16
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Granted: —
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Expires: 2001-09-16
Abstract
Abstract A polymeric composition of matter formed by ring opening copolymerization using a metathesis catalyst comprising bound antioxidant which is a reaction product of a norbornene-type monomer and a norbornenyl phenolic antioxidant.
Inventors
- 👤 Robert Wesley Layer
- 👤 Linwood Powers Tenney
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-05 15:08
CPC Classifications
C; C08; C08L; C08L65/00; C08G; C08G61/00; C08G61/02; C08G61/04; C08G61/06; C08G61/08
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
154 words
A polymeric composition of matter comprising a reaction product obtained by ring opening polymerization of a norbornene-type monomer or a mixture thereof and a norbornenyl phenolic antioxidant or a mixture thereof defined as follows: where R 1 , R 2 , and R are individually selected from hydrogen and alkyl groups of 1 to 3 carbon atoms; R 4 is selected from hydrogen, alkyl groups containing 1 to 12 carbon atoms, and substituted and unsubstituted alicyclic groups of 4 to 8 carbon atoms; R 5 is selected from alkyl groups of 1 to 6 carbon atoms, and substituted and unsubstituted alicyclic groups of 4 to 8 carbon atoms; R 6 is selected from alkylene and alkenylene groups containing 1 to 8 carbon atoms; and R 7 is selected from hydrogen, and alkenyl groups of 1 to 8 carbon atoms, amount of said norbornenyl phenolic being sufficient to improve antioxidant properties of said reaction product;
Claim 2
Dependent Claim
154 words
A polymeric composition of matter comprising a reaction product obtained by ring opening polymerization of a norbornene-type monomer or a mixture thereof and a norbornenyl phenolic antioxidant or a mixture thereof defined as follows: where R 1 , R 2 , and R are individually selected from hydrogen and alkyl groups of 1 to 3 carbon atoms; R 4 is selected from hydrogen, alkyl groups containing 1 to 12 carbon atoms, and substituted and unsubstituted alicyclic groups of 4 to 8 carbon atoms; R 5 is selected from alkyl groups of 1 to 6 carbon atoms, and substituted and unsubstituted alicyclic groups of 4 to 8 carbon atoms; R 6 is selected from alkylene and alkenylene groups containing 1 to 8 carbon atoms; and R 7 is selected from hydrogen, and alkenyl groups of 1 to 8 carbon atoms, amount of said norbornenyl phenolic being sufficient to improve antioxidant properties of said reaction product;
Claim 3
Dependent Claim
75 words
Composition of Claim 1 wherein R 1 , R 2 and R 3 are individually selected from hydrogen and methyl groups, R 4 is selected from alkyl groups of 1 to 6 carbon atoms, R 5 is selected from alkyl groups of 1 to 6 carbon atoms, R is selected from alkylene and alkenylene groups of 1 to 4 carbon atoms, and R 7 is selected from alkyl groups of 1 to 4 carbon atoms.
Claim 4
Dependent Claim
25 words
Composition of Claim 2 wherein said norbornene type monomers are selected from norbornenes, dicyclopentadienes, dihydrodicyclopentadienes, tetracyclododecenes and symmetrical and unsymmetrical trimers and tetramers of cyclopentadiene.
Claim 5
Dependent Claim
27 words
Composition of Claim 3 wherein said norbornene-type monomers are selected from substituted and unsubstituted monomers, wherein said substituents are selected from ester, nitrile, phenyl, and halogen groups.
Claim 6
Dependent Claim
21 words
Composition of Claim 2 wherein said norbornene-type monomers are selected from monomers characterized by the presence of the following norbornene moiety:
Claim 7
Dependent Claim
31 words
Composition of Claim 3 formed by a metathesis ring opening catalyst wherein amount of said norbornenyl phenolic is 0.05 to 10 parts by weight per 100 parts of said norbornene-type monomers.
Claim 8
Dependent Claim
36 words
Composition of Claim 5 wherein amount of said norbornenyl phenolic is 0.05 to 10 parts by weight per 100 parts of said norbornene-type monomers, R 4 being in the open ortho position to the hydroxyl group.
References Cited (Backward Citations)
DE2103326A1
Cited
JPS54150500A
Cited
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