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EP0048439A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Norbornene polymers containing bound antioxidant

Assignee: Goodrich Corp
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Filing: 1981-09-16
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Granted: —
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Expires: 2001-09-16
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Abstract

Abstract A polymeric composition of matter formed by ring opening copolymerization using a metathesis catalyst comprising bound antioxidant which is a reaction product of a norbornene-type monomer and a norbornenyl phenolic antioxidant.

Inventors

  • 👤 Robert Wesley Layer
  • 👤 Linwood Powers Tenney

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-05 15:08
CPC Classifications
C; C08; C08L; C08L65/00; C08G; C08G61/00; C08G61/02; C08G61/04; C08G61/06; C08G61/08

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 154 words
A polymeric composition of matter comprising a reaction product obtained by ring opening polymerization of a norbornene-type monomer or a mixture thereof and a norbornenyl phenolic antioxidant or a mixture thereof defined as follows: where R 1 , R 2 , and R are individually selected from hydrogen and alkyl groups of 1 to 3 carbon atoms; R 4 is selected from hydrogen, alkyl groups containing 1 to 12 carbon atoms, and substituted and unsubstituted alicyclic groups of 4 to 8 carbon atoms; R 5 is selected from alkyl groups of 1 to 6 carbon atoms, and substituted and unsubstituted alicyclic groups of 4 to 8 carbon atoms; R 6 is selected from alkylene and alkenylene groups containing 1 to 8 carbon atoms; and R 7 is selected from hydrogen, and alkenyl groups of 1 to 8 carbon atoms, amount of said norbornenyl phenolic being sufficient to improve antioxidant properties of said reaction product;
Claim 2
Dependent Claim 154 words
A polymeric composition of matter comprising a reaction product obtained by ring opening polymerization of a norbornene-type monomer or a mixture thereof and a norbornenyl phenolic antioxidant or a mixture thereof defined as follows: where R 1 , R 2 , and R are individually selected from hydrogen and alkyl groups of 1 to 3 carbon atoms; R 4 is selected from hydrogen, alkyl groups containing 1 to 12 carbon atoms, and substituted and unsubstituted alicyclic groups of 4 to 8 carbon atoms; R 5 is selected from alkyl groups of 1 to 6 carbon atoms, and substituted and unsubstituted alicyclic groups of 4 to 8 carbon atoms; R 6 is selected from alkylene and alkenylene groups containing 1 to 8 carbon atoms; and R 7 is selected from hydrogen, and alkenyl groups of 1 to 8 carbon atoms, amount of said norbornenyl phenolic being sufficient to improve antioxidant properties of said reaction product;
Claim 3
Dependent Claim 75 words
Composition of Claim 1 wherein R 1 , R 2 and R 3 are individually selected from hydrogen and methyl groups, R 4 is selected from alkyl groups of 1 to 6 carbon atoms, R 5 is selected from alkyl groups of 1 to 6 carbon atoms, R is selected from alkylene and alkenylene groups of 1 to 4 carbon atoms, and R 7 is selected from alkyl groups of 1 to 4 carbon atoms.
Claim 4
Dependent Claim 25 words
Composition of Claim 2 wherein said norbornene type monomers are selected from norbornenes, dicyclopentadienes, dihydrodicyclopentadienes, tetracyclododecenes and symmetrical and unsymmetrical trimers and tetramers of cyclopentadiene.
Claim 5
Dependent Claim 27 words
Composition of Claim 3 wherein said norbornene-type monomers are selected from substituted and unsubstituted monomers, wherein said substituents are selected from ester, nitrile, phenyl, and halogen groups.
Claim 6
Dependent Claim 21 words
Composition of Claim 2 wherein said norbornene-type monomers are selected from monomers characterized by the presence of the following norbornene moiety:
Claim 7
Dependent Claim 31 words
Composition of Claim 3 formed by a metathesis ring opening catalyst wherein amount of said norbornenyl phenolic is 0.05 to 10 parts by weight per 100 parts of said norbornene-type monomers.
Claim 8
Dependent Claim 36 words
Composition of Claim 5 wherein amount of said norbornenyl phenolic is 0.05 to 10 parts by weight per 100 parts of said norbornene-type monomers, R 4 being in the open ortho position to the hydroxyl group.

References Cited (Backward Citations)

DE2103326A1 Cited
JPS54150500A Cited

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