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A method of producing a silyl group-containing venyl resin and a paint containing the resin

Assignee: Kanegafuchi Chemical Industry Co Ltd
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Filing: 1981-07-09
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Granted: —
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Expires: 2001-07-09
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Abstract

Abstract A paint comprises a silyl group-containing vinyl resin having a main chain composed substantially of a vinyl polymer. The resin has at least one silyl group bonded to a hydrolyzable group, and contains 0.1 to 20% by weight of maleic anhydride by copolymerization. The resin has a molecular weight of 300 to 30,000. A method of manufacturing such a resin is also disciosed.

Inventors

  • 👤 Yasushi Kato
  • 👤 Hisao Furukawa
  • 👤 Naotami Ando

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 05:29
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/42

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 56 words
A paint comprising a silyl group-containing vinyl resin having a main chain composed substantially of a vinyl polymer, said resin having in each molecule at least one silyl group bonded to a hydrolyzable group, said resin containing 0.1 to 20% by weight of maleic anhydride by copolymerization, and having a molecular weight of 1,000 to 30,000.
Claim 2
Dependent Claim 56 words
A paint comprising a silyl group-containing vinyl resin having a main chain composed substantially of a vinyl polymer, said resin having in each molecule at least one silyl group bonded to a hydrolyzable group, said resin containing 0.1 to 20% by weight of maleic anhydride by copolymerization, and having a molecular weight of 1,000 to 30,000.
Claim 3
Dependent Claim 57 words
A paint as set forth in claim 1, wherein said silyl group is represented by the formula in which X stands for said hydrolyzable group, (R 1 ) and(R 2 ) each stand for a hydrogen atom, or an alkyl, aryl or aralkyl group having 1 to 10 carbon atoms, and n is 1, 2 or 3.
Claim 4
Independent Claim 117 words
A method of manufacturing a silyl group-containing vinyl resin having a molecular weight of 300 to 30,000, said method comprising reacting a vinyl polymer containing 0.1 to 20% by weight of maleic anhydride by copolymerization, and having a carbon-carbon double bond at its terminal or in its side chain with a hydrosilane compound of the general formula in which (R 1 )stands for a hydrogen atom or a monovalent hydrocarbon group selected from the group consisting of alkyl, aryl and aralkyl groups, and having 1 to 10 carbon atoms, X stands for a hydrolyzable group, and n is an integer of 1 to 3, at a temperature of 50°C to 150°C in the presence of a catalyst.
Claim 5
Independent Claim 117 words
A method of manufacturing a silyl group-containing vinyl resin having a molecular weight of 300 to 30,000, said method comprising reacting a vinyl polymer containing 0.1 to 20% by weight of maleic anhydride by copolymerization, and having a carbon-carbon double bond at its terminal or in its side chain with a hydrosilane compound of the general formula in which (R 1 )stands for a hydrogen atom or a monovalent hydrocarbon group selected from the group consisting of alkyl, aryl and aralkyl groups, and having 1 to 10 carbon atoms, X stands for a hydrolyzable group, and n is an integer of 1 to 3, at a temperature of 50°C to 150°C in the presence of a catalyst.
Claim 6
Dependent Claim 35 words
4 . A method as set forth in claim 3, wherein said catalyst is selected from the group consisting of transition metals belonging to Group VIII of the periodic table, and the complex compounds thereof.
Claim 7
Dependent Claim 102 words
5 . A method of manufacturing a silyl group-containing vinyl resin having a molecular weight of 300 to 30,000, said method comprising radically polymerizing a silane compound of the general formula in which (R 1 )stands for a hydrogen atom or a monovalent hydrocarbon group selected from the group consisting of alkyl, aryl and aralkyl groups, and having 1 to 10 carbon atoms, (R 2 )stands for an organic residue having a polymerizable double bond, X stands for a hydrolyzable group, and n is an integer of 1 to 3, 0.1 to 20% by weight of maleic anhydride, and a vinyl compound.
Claim 8
Dependent Claim 102 words
5 . A method of manufacturing a silyl group-containing vinyl resin having a molecular weight of 300 to 30,000, said method comprising radically polymerizing a silane compound of the general formula in which (R 1 )stands for a hydrogen atom or a monovalent hydrocarbon group selected from the group consisting of alkyl, aryl and aralkyl groups, and having 1 to 10 carbon atoms, (R 2 )stands for an organic residue having a polymerizable double bond, X stands for a hydrolyzable group, and n is an integer of 1 to 3, 0.1 to 20% by weight of maleic anhydride, and a vinyl compound.
Claim 9
Dependent Claim 22 words
A paint as set forth in claim 1, wherein said molecule has a molecular weight of 300 to 4,000 per silyl group.
Claim 10
Dependent Claim 16 words
A paint as set forth in claim 2, wherein said hydrolyzable group is a methoxy group.
Claim 11
Dependent Claim 39 words
A paint comprising 100 parts by weight of a vinyl polymer set forth in claim 2 and 1 to 50 parts by weight of alkyl alcohol, wherein said two components are admixed at a temperature from.room temperature to 100°C.

References Cited (Backward Citations)

FR2401176A1 Cited

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