Patent EP0040286A2 successfully refreshed from Google Patents.
EP0040286A2
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Polyvinyl halide resin compositions containing 1,3 Dicarbonyl compounds
Assignee: Phoenix Chemical Corp
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Filing: 1981-01-13
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Granted: —
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Expires: 2001-01-13
Abstract
Abstract 1,3-Dicarbonyl compounds are provided having the formula: wherein: R 1 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR 1 , ester COOR 1 , alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms, and R 2 is selected from the group consisting of hydrocarbon having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR 1 , ester COOR 1 , alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; R 3 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR 1 , ester COOR 1 , alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; as well as metal and organotin enolate salts thereof. The compounds are effective in enhancing the resistance to deterioration by heat and light of polyvinyl halide resins.
Inventors
- 👤 William E. Leistner
- 👤 Motonobu Minagawa
- 👤 Kouji Tsuruga
- 👤 Masashi Harada
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-09 07:44
CPC Classifications
C; C07; C07C; C07C65/00; C07C65/32; C07C65/34; C08; C08K; C08K5/00; C08K5/04; C08K5/07
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
180 words
1 3-Dicarbonyl compounds having the formula: wherein: R is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR 1 , ester COOR 1 , alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms, and - R 2 is selected from the group consisting of hydrocarbon having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR 1 , ester COOR 1 , alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; and .. R 3 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR 1 ,/ ester COOR 1 , alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms .
Claim 2
Dependent Claim
180 words
1 3-Dicarbonyl compounds having the formula: wherein: R is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR 1 , ester COOR 1 , alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms, and - R 2 is selected from the group consisting of hydrocarbon having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR 1 , ester COOR 1 , alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; and .. R 3 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR 1 ,/ ester COOR 1 , alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms .
Claim 3
Dependent Claim
52 words
- A metal enolate salt, preferably an alkali metal, an alkaline earth metal or a polyvalent metal salt of a 1,3-dicarbonyl compound of claim 1, e.g. a salt of a metal selected from the group consisting of lithium, sodium, potassium, magnesium, strontium, calcium, barium, cadmium, lead, zinc, tin, aluminium, antimony and zirconium.
Claim 4
Dependent Claim
39 words
- An organotin enolate salt of a 1,3-dicarbonyl compound of claim 1, preferably an organotin (R) n Sn wherein n is 1, 2 or 3 and R is a hydrocarbon group having from one to about eighteen carbon atoms.
Claim 5
Dependent Claim
24 words
- A 1,3-dicarbonyl compound according to claim 1 in which both R 1 are hydrogen or/R 1 is hydrogen and the other is alkyl.
Claim 6
Dependent Claim
18 words
- A 1,3-dicarbonyl compound according to claim 1 in whic R 2 is aryl, preferably phenyl, or alkyl.
Claim 7
Dependent Claim
14 words
- A 1,3-dicarbonyl compound according to claim 1 in which R 3 is alkyl.
Claim 8
Dependent Claim
15 words
- A 1,3-dicarbonyl compound according to claim 1, namely 3-carbomethoxybenzoyl-benzoylmethane, 4-carbomethoxybenzoyl-benzoylmethane, 4-carbomethoxybenzoyl-4-t-butylbenzoylmethane, 4-carbomethoxybenzoyl-acetylmethane. or 3-carbomethoxybenzoyl-acetylmethane,
Claim 9
Dependent Claim
78 words
- A polyvinyl halide resin composition having improved resistance to deterioration when heated to 350°F, comprising a polyvinyl halide resin formed at least in part of the recurring group: and having a halogen content in excess of 40 %, where X 1 is halogen and X 2 is'either hydrogen or halogen, preferably a polyvinyl chloride homopolymer or a copolymer of vinyl chloride and a copolymerizable monomer, such as vinyl acetate, and a 1,3-dicarbonyl compound according to claim 1.
Claim 10
Dependent Claim
31 words
- A stabilizer composition capable of enhancing the resistance to deterioration by heat and/or light of polyvinyl halide resins, comprising a 1,3-dicarbonyl compound and an additional polyvinyl halide resin heat stabilizer.
Claim 11
Dependent Claim
31 words
- A stabilizer composition capable of enhancing the resistance to deterioration by heat and/or light of polyvinyl halide resins, comprising a 1,3-dicarbonyl compound and an additional polyvinyl halide resin heat stabilizer.
Claim 12
Dependent Claim
37 words
- A stabilizer composition according to claim 9 in which the additional heat stabilizer is selected from the group consisting of metal salts of carboxylic acids; metal salts of hydrocarbon-substituted phenols; phenolic antioxidants; 1,2-epoxyides and organic phosphites.
References Cited (Backward Citations)
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