Patent EP0032307A2 successfully refreshed from Google Patents.
EP0032307A2
Expired / Lapsed
EP
⏱️ 0.0 years remaining
Catalyst component
Assignee: Imperial Chemical Industries Ltd
•
Filing: 1980-12-22
•
Granted: —
•
Expires: 2000-12-22
Abstract
Abstract A component for an olefin polymerisation catalyst which component is the product of treating a particulate support material with (a) an organomagnesium compound, (b) a transition metal compound of Groups IVA, VA or VIA, e.g. bis-butoxy titanium dichloride, (c) a pacifying agent, e.g. HCl and (d) optionally an aluminium compound, e.g. ethyl aluminium dichloride, an organometallic compound, e.g. zirconium tetrabenzyl, a halogenating agent e.g. carbon tetrachloride, or a Lewis Base compound, e.g. ethyl benzoate.
Inventors
- 👤 Angus John Hartshorn
- 👤 Eric Jones
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-01 16:16
CPC Classifications
C; C08; C08F; C08F10/00
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
518 words
A catalyst component which is the product of treating at least one particulate support material with at least one organomagnesium compound, at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table, at least one pacifying agent, and optionally one or more compounds selected from the group consisting of: i) an aluminium compound of the general formula: R n AlY 3 _ n wherein R, each of which may be the same or different, represents a hydrocarbyl group, or substituted hydrocarbyl group, such as alkyl, aryl, cycloalkyl, aralkyl, alkenyl or alkadienyl, n is 0, 1, 2, 3 or a fraction less than 3, and Y is a singly charged ligand such as hydride, fluoride, chloride, bromide, iodide or oxyhydrocarbyl, ii) an organometallic compound of the general formula: R 1 m MX p wherein M is a metal of Groups IA, IIA, IIB IIIB, IVA, VA or VIA of the Periodic Table, R 1 is a hydrocarbyl or a substituted hydrocarbyl group, X is a singly charged anionic ligand or a mono- dentate neutral ligand, m is an integer up to the highest valency of the metal M and p is 0 or an integer up to 2 less than the valency of the metal M, except that when M is a metal from Group VIA, p is always O, and m has a value from 2 to the highest'valency of the metal, and when M is a metal from Groups IVA or VA m has a value from 2 to the highest valency of the metal and p has a value from O to a value of 2 less than the valency of the metal M, iii) a halogen containing compound and iv) a Lewis Base compound with the proviso (i) that the at least one particulate support material is treated with the at least one organomagnesium compound, the at least one transition metal compound of Groups IVA, VA or VIA and the one or more optional compounds, where one or more is used, prior to being treated with the at least one pacifying agent, except that where (a) the at least one pacifying agent is a hydrogen halide, (b) the at least one particulate support material is treated with at least one aluminium compound of general formula RnA l Y3-n and (c) the at least one particulate support material is treated with the at least one aluminium compound of general formula R n AlY 3-n and the at least one organomagnesium compound separately, the at least one pacifying agent may be added to the at least one particulate support material after it has been treated with the at least one organomagnesium compound and the at least one aluminium compound of general formula R n AlY 3-n and before it is treated with the at least one transition metal compound of Groups IVA, VA or VIA and (ii) that where the at least one particulate support material is treated with two compounds selected from the optional compounds they are not exclusively an aluminium compound R n AlY 3-n and an organometallic compound RmMXp.
Claim 2
Dependent Claim
518 words
A catalyst component which is the product of treating at least one particulate support material with at least one organomagnesium compound, at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table, at least one pacifying agent, and optionally one or more compounds selected from the group consisting of: i) an aluminium compound of the general formula: R n AlY 3 _ n wherein R, each of which may be the same or different, represents a hydrocarbyl group, or substituted hydrocarbyl group, such as alkyl, aryl, cycloalkyl, aralkyl, alkenyl or alkadienyl, n is 0, 1, 2, 3 or a fraction less than 3, and Y is a singly charged ligand such as hydride, fluoride, chloride, bromide, iodide or oxyhydrocarbyl, ii) an organometallic compound of the general formula: R 1 m MX p wherein M is a metal of Groups IA, IIA, IIB IIIB, IVA, VA or VIA of the Periodic Table, R 1 is a hydrocarbyl or a substituted hydrocarbyl group, X is a singly charged anionic ligand or a mono- dentate neutral ligand, m is an integer up to the highest valency of the metal M and p is 0 or an integer up to 2 less than the valency of the metal M, except that when M is a metal from Group VIA, p is always O, and m has a value from 2 to the highest'valency of the metal, and when M is a metal from Groups IVA or VA m has a value from 2 to the highest valency of the metal and p has a value from O to a value of 2 less than the valency of the metal M, iii) a halogen containing compound and iv) a Lewis Base compound with the proviso (i) that the at least one particulate support material is treated with the at least one organomagnesium compound, the at least one transition metal compound of Groups IVA, VA or VIA and the one or more optional compounds, where one or more is used, prior to being treated with the at least one pacifying agent, except that where (a) the at least one pacifying agent is a hydrogen halide, (b) the at least one particulate support material is treated with at least one aluminium compound of general formula RnA l Y3-n and (c) the at least one particulate support material is treated with the at least one aluminium compound of general formula R n AlY 3-n and the at least one organomagnesium compound separately, the at least one pacifying agent may be added to the at least one particulate support material after it has been treated with the at least one organomagnesium compound and the at least one aluminium compound of general formula R n AlY 3-n and before it is treated with the at least one transition metal compound of Groups IVA, VA or VIA and (ii) that where the at least one particulate support material is treated with two compounds selected from the optional compounds they are not exclusively an aluminium compound R n AlY 3-n and an organometallic compound RmMXp.
Claim 3
Dependent Claim
237 words
A catalyst component which is the product of treating at least one particulate support material with at least one aluminium compound of general formula R n AlY 3-n , wherein R, Y and n have the meanings ascribed to them in claim 1, at least one organomagnesium compound, at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table and at least one pacifying agent with the proviso that the at least one particulate support material is treated with the at least one aluminium compound R n AlY 3-n , the at least one organomagnesium compound and the at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table prior to being-treated with the at least one pacifying agent except that where the at least one pacifying agent is a hydrogen halide and the at least one particulate support material is treated with the at least one aluminium compound of general formula R n AlY 3-n and the at least one organomagnesium compound separately the at least one pacifying agent may be added to the at least one particulate support material after it has been treated with the at least one aluminium compound R n AlY 3-n and the at least one organomagnesium compound and before it is treated with the at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table.
Claim 4
Dependent Claim
40 words
A catalyst component as claimed in claim 2 wherein the at least one particulate support material is treated with the at least one aluminium compound R n AlY 3-n prior to being treated with the at least one organomagnesium compound.
Claim 5
Dependent Claim
115 words
A catalyst component as claimed in claim 1 wherein the at least one particulate support material is treated with at least one halogen-containing compound which is a halohydrocarbon of general formula R 5 a CX 1 ( 4-a ) wherein R 5 , each of which may be the same or different, is hydrogen, a hydrocarbyl residue or a substituted hydrocarbyl residue, X l is.a halide and a is 0 or an integer from 1 up to 3, at elevated temperature, prior to treatment with the at least one organomagnesium compound, the at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table and the at least one pacifying agent.
Claim 6
Dependent Claim
23 words
A catalyst component as claimed in claim 4 wherein in the formula RaCX 1 ( 4-a ) a is O, 1 or 2.
Claim 7
Dependent Claim
36 words
A catalyst component as claimed in any one of the preceding claims wherein the at least one pacifying agent comprises carbon dioxide, carbon monoxide, oxygen, a halohydrocarbon as defined in claim 4 or a protic agent.
Claim 8
Dependent Claim
33 words
A catalyst component as claimed in claim 6 wherein the at least one pacifying agent is an aliphatic alcohol having from 1 to 6 carbon atoms, an anhydrous hydrogen halide, or a halohydrocarbon.
Claim 9
Dependent Claim
41 words
An olefin polymerisation catalyst comprising a catalyst component as claimed in any one of the preceding claims activated with a suitable activator which is at least one organometallic compound of a metal of Groups I to IV of the Periodic Table.
Claim 10
Dependent Claim
32 words
A process for the polymerisation or copolymerisation of an olefinically unsaturated monomer which process comprises contacting, under polymerisation conditions, at least one olefin monomer with a catalyst as claimed in claim 8.
Claim 11
Dependent Claim
14 words
A process as claimed in claim 9 whenever effected in a fluidised bed reactor.
References Cited (Backward Citations)
No citation records indexed.
USPTO Annuity & Maintenance Windows
Maintenance schedule is calculated for granted US utility patents.