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EP0030084A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Method for preparing phenylalkanes

Assignee: Mobil Oil AS
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Filing: 1980-10-31
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Granted: —
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Expires: 2000-10-31
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Abstract

Abstract A process for the selective alkylation of aromatic compounds with an alkylating agent comprising an aliphatic or aromatic organic compound having at least one available reactive alkyl group of at least a 5 carbon atom hydrocarbon chain to produce phenylalkanes having an improved yield of the more external phenyl isomers. The reaction is carried out in the presence of crystalline zeolite catalysts, such as ZSM-4, ZSM-20, ZSM-38, mazzite, Linde Type L and zeolite Beta.

Inventors

  • 👤 Lewis Brewster Young

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-03 23:24
CPC Classifications
C; C07; C07C; C07C2/00; C07C2/54; C07C2/64; C07C2/66; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/70

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 106 words
, 1. A process for the selective alkylation of aromatic compounds with an alkylating agent comprising an aliphatic or aromatic organic compound having one or more available reactive alkyl groups of at least five carbons in the hydrocarbon chain; said process comprising contacting said aromatic compound with said alkylating agent in the presence of a crystalline zeolite catalyst, at a temperature of between 50°C and 500°C and a pressure within the range of 2.5x10 4 Pa to 2.5x10 Pa; said crystalline zeolite catalyst being chosen from the group consisting of: mazzite, Linde Type L, zeolite Beta, ZSM-4, ZSM-20, ZSM-38 and synthetic and naturally occurring isotypes thereof.
Claim 2
Dependent Claim 23 words
A process as described in Claim 1 wherein said alkyl groups have between six and twenty carbon atoms in the linear hydrocarbon chain.
Claim 3
Dependent Claim 13 words
A process as described in Claim 1 wherein said aromatic compound is benzene.
Claim 4
Dependent Claim 22 words
A process as described in Claim 1 wherein said aromatic compound comprises a benzene ring having from one to two substituents thereon.
Claim 5
Dependent Claim 35 words
A process as described in Claim 1 wherein said temperature is within the approximate range of from 100°C to 350°C and said pressure is between about 1 0 5 Pa and about 5×10 6 Pa.
Claim 6
Dependent Claim 17 words
A process as described in any preceding Claim wherein said zeolite has the crystal structure of mazzite.
Claim 7
Dependent Claim 20 words
A process as described in any Claim 1 through 5 wherein said zeolite has the crystal structure of,Type L zeolite.
Claim 8
Dependent Claim 20 words
A process as described in any Claim 1 through 5 wherein said zeolite has the crystal structure of zeolite Beta.
Claim 9
Dependent Claim 19 words
A process as described in any Claim 1 through 5 wherein said zeolite has the crystal structure of ZSM-4.
Claim 10
Dependent Claim 19 words
A process as described in any Claim 1 through 5 wherein said zeolite has the crystal structure of ZSM-20.
Claim 11
Dependent Claim 19 words
A process as described in any Claim 1 through 5 wherein said zeolite has the crystal structure of ZSM-38.
Claim 12
Dependent Claim 16 words
A process as described in any preceding Claim wherein said zeolite is steamed prior to use.
Claim 13
Dependent Claim 18 words
A process as described in any preceding Claim wherein said zeolite is combined with a binder therefor. 1501N

References Cited (Backward Citations)

DE1443516B Cited
GB1069242A Cited
FR2312479A1 Cited
US4136128A Cited
DE2730949A1 Cited

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