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Patent EP0024099B1 successfully refreshed from Google Patents.
EP0024099B1
Expired / Lapsed
EP
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Non-fused aluminium oxide-based abrasive mineral, a process for its production and abrasive products comprising the said abrasive mineral
Assignee: 3M Co
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Filing: 1980-06-16
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Granted: 1984-01-25
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Expires: 2000-06-16
Abstract
No abstract record available.
Inventors
- 👤 Harold G. Sowman
- 👤 Melvin A. Leitheiser
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-08 07:01
CPC Classifications
C; C09; C09K; C09K3/00; C09K3/14; C09K3/1409; C09K3/1418; C04; C04B; C04B35/00; C04B35/01; C04B35/10; C09K3/1427
Claims Analysis
Total Claims: 31
Claim 1
Independent Claim
220 words
Method of making, synthetic, aluminum oxide-based abrasive mineral characterized by having a dense, granular, substantially homogeneous microcrystalline structure of randomly oriented crystallites comprising modifying component in a dominant continuous alumina phase comprising alpha-alumina, said method characterized by the steps of: (a) gelling a substantially calcium ion- and alkali metal ion-free homogeneous mixture of an alumina source compound and at least one precursor of at least one modifying component selected from (i) zirconia, hafnia, or a combination of zirconia and hafnia, and (ii) a spinel derived from alumina and at least one oxide of a metal selected from cobalt, nickel, zinc, or magnesium, said precursor being present in an amount to provide in said mineral a dominant continuous alumina phase comprising alpha-alumina and a modifying component content, on a volume percent of fired solids of the mineral, of either (a) at least 10% of said (i), (b), at least 1% of said (ii), or (c) at least 1% of said (ii) and 1-45% of said (i), (b) drying the gelled mixture to form chunky pieces of solid material, and (c) firing said solid material in a non-reducing atmosphere to a temperature of at least 1250°C., but not above the melting point of said mineral, to remove fugitive materials and to nondestructively convert said solid material to a dense aluminum oxide-based mineral.
Claim 2
Dependent Claim
220 words
Method of making, synthetic, aluminum oxide-based abrasive mineral characterized by having a dense, granular, substantially homogeneous microcrystalline structure of randomly oriented crystallites comprising modifying component in a dominant continuous alumina phase comprising alpha-alumina, said method characterized by the steps of: (a) gelling a substantially calcium ion- and alkali metal ion-free homogeneous mixture of an alumina source compound and at least one precursor of at least one modifying component selected from (i) zirconia, hafnia, or a combination of zirconia and hafnia, and (ii) a spinel derived from alumina and at least one oxide of a metal selected from cobalt, nickel, zinc, or magnesium, said precursor being present in an amount to provide in said mineral a dominant continuous alumina phase comprising alpha-alumina and a modifying component content, on a volume percent of fired solids of the mineral, of either (a) at least 10% of said (i), (b), at least 1% of said (ii), or (c) at least 1% of said (ii) and 1-45% of said (i), (b) drying the gelled mixture to form chunky pieces of solid material, and (c) firing said solid material in a non-reducing atmosphere to a temperature of at least 1250°C., but not above the melting point of said mineral, to remove fugitive materials and to nondestructively convert said solid material to a dense aluminum oxide-based mineral.
Claim 3
Dependent Claim
27 words
The method of claim 1 further characterized by including, prior to the firing step, the step of crushing the solid material to produce a desired particle size.
Claim 4
Dependent Claim
24 words
The method of claim 1, further characterized by including the step of crushing said dense α-aluminum oxide-based mineral to produce a desired particle size.
Claim 5
Dependent Claim
16 words
The method of claim 1 further characterized in that said precursor is a precursor of zirconia.
Claim 6
Dependent Claim
14 words
The method of claim 4 further characterized in that said precursor is an alkanate.
Claim 7
Dependent Claim
16 words
The method of claim 5 further characterized in that said alkanate is the acetate or formate.
Claim 8
Dependent Claim
13 words
The method of claim 1 further characterized in that said metal is magnesium.
Claim 9
Dependent Claim
13 words
The method of claim 1 further characterized in that said metal is zinc.
Claim 10
Dependent Claim
17 words
The method of claim 1 further characterized in that said precursor is magnesium acetate, chloride, or nitrate.
Claim 11
Dependent Claim
21 words
The method of claim 1 further characterized in that said precursor is a precursor of zirconia and of magnesium aluminum spinel.
Claim 12
Dependent Claim
25 words
The method of claim 1 further characterized in that said firing is effected in a kiln having means for moving said solid material during firing.
Claim 13
Dependent Claim
15 words
The method of claim 11 further characterized in that said kiln is a rotary kiln.
Claim 14
Dependent Claim
126 words
An a-aluminum oxide-based granular abrasive mineral including a modifying component characterized by being substantially calcium ion- and alkali metal ion-free, non-fused, synthetic and dense and having a substantially homogeneous microcrystalline structure comprising a secondary phase of randomly oriented crystallites comprising modifying component in a dominant continuous alumina phase comprising alpha-alumina, said modifying component, on a volume percent of fired solids of the mineral, being selected from: (i) at least 10% of zirconia, hafnia, or a combination of zirconia and hafnia, (ii) at least 1% of a spinel derived from alumina and at least one oxide of a metal selected from cobalt, nickel, zinc, or magnesium, or (iii) 1-45% of said zirconia, hafnia, or the combination of zirconia and hafnia and at least 1% of said spinel.
Claim 15
Dependent Claim
126 words
An a-aluminum oxide-based granular abrasive mineral including a modifying component characterized by being substantially calcium ion- and alkali metal ion-free, non-fused, synthetic and dense and having a substantially homogeneous microcrystalline structure comprising a secondary phase of randomly oriented crystallites comprising modifying component in a dominant continuous alumina phase comprising alpha-alumina, said modifying component, on a volume percent of fired solids of the mineral, being selected from: (i) at least 10% of zirconia, hafnia, or a combination of zirconia and hafnia, (ii) at least 1% of a spinel derived from alumina and at least one oxide of a metal selected from cobalt, nickel, zinc, or magnesium, or (iii) 1-45% of said zirconia, hafnia, or the combination of zirconia and hafnia and at least 1% of said spinel.
Claim 16
Dependent Claim
18 words
The mineral of claim 13 further characterized by said secondary phase comprising spinel formed from magnesia and alumina.
Claim 17
Dependent Claim
13 words
The mineral of claim 13 further characterized by said secondary phase comprising zirconia.
Claim 18
Dependent Claim
19 words
The mineral of claim 13 further characterized by said secondary phase comprising spinel formed from zinc oxide and alumina.
Claim 19
Dependent Claim
37 words
The mineral of claim 13 further characterized by said secondary phase comprising zirconia crystallites having diameters less than 2500 Angstroms (250 nm) and said a-alumina phase comprises a-alumina crystallites having diameters less than 3000 (300 nm) Angstroms.
Claim 20
Dependent Claim
11 words
The mineral of claim 13 further characterized by having conchoidal fractures.
Claim 21
Dependent Claim
15 words
The mineral of claim 13 further characterized by said secondary phase comprising zirconia and samaria.
Claim 22
Dependent Claim
12 words
The mineral of claim 13 characterized by being transparent to visible light.
Claim 23
Dependent Claim
34 words
The mineral of claim 13 further characterized by said secondary phase comprising spinel formed by alumina and magnesia and another metal oxide selected from the group consisting of titania, ceria, zirconia and combinations thereof.
Claim 24
Dependent Claim
24 words
An abrasive article containing granular abrasive mineral characterized by at least a portion thereof being the abrasive mineral of any one of claims 13-21.
Claim 25
Dependent Claim
27 words
The abrasive article of claim 22 further characterized in that said granular abrasive mineral is adhered to a flexible backing sheet to form a coated abrasive product.
Claim 26
Dependent Claim
23 words
The abrasive article of claim 22 further characterized in that said granular abrasive mineral is adhered together to form a rotatable grinding wheel.
Claim 27
Dependent Claim
25 words
The abrasive article of claim 22 further characterized in that said granular abrasive mineral is adhered to and within a lofty nonwoven fibrous support web.
Claim 28
Dependent Claim
25 words
The abrasive article of claim 22 further characterized in that said secondary phase of said granular abrasive mineral comprises spinel formed of magnesia and alumina.
Claim 29
Dependent Claim
31 words
The abrasive article of claims 22, 23, 24, or 25 further characterized in that said granular abrasive mineral consists essentially of said aluminum oxide-based granular abrasive mineral defined in claims 13-21.
Claim 30
Dependent Claim
34 words
The abrasive article of claim 22 or 25 further characterized in that said granular abrasive mineral comprises at least two types, one of said types being said aluminum oxide-based mineral defined in claims 13-21.
Claim 31
Dependent Claim
16 words
The method of claim 1 further characterized in that said non-reducing atmosphere is an oxidizing atmosphere.
References Cited (Backward Citations)
No citation records indexed.
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