Patent EP0016285A2 successfully refreshed from Google Patents.
EP0016285A2
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EP
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Process for the production of valeraldehydes by hydroformylation of butene-1
Assignee: Johnson Matthey Davy Technologies Ltd
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Filing: 1979-11-28
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Granted: —
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Expires: 1999-11-28
Abstract
Abstract A rhodium-catalysed hydroformylation process is disclosed in which an overhead vapour stream is recovered from the hydroformylation zone containing reactant alkene, hydrogen, carbon monoxide, alkene hydrogenation product(s), aldehyde product and aldehyde condensation products. This vapour stream is subjected to condensation conditions in one or two stages to condense therefrom condensible components comprising unreacted alkene, aldehyde product, and aldehyde condensation products. Non-condensed components of the vapour stream (e.g. H 2 and CO) are recycled to the hydroformylation zone. Unreacted alkene is also recycled in liquid form to the hydroformylation zone.
Inventors
- 👤 Thomas Frederick Shevels
- 👤 Norman Harris
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-08 19:33
CPC Classifications
C; C07; C07C; C07C45/00; C07C45/49; C07C45/50
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
172 words
A process for the production of an aldehyde by hydroformylation of an alkene in the presence of a rhodium complex catalyst comprising: providing a hydroformylation zone containing a liquid charge comprising (a) a rhodium complex catalyst wherein rhodium is in complex combination with carbon monoxide and a triorganophosphine, (b) excess triorganophosphine, (c) liquid aldehyde product, and (d) polymeric aldehyde condensation products; feeding liquid reactant alkene to the hydroformylation zone; supplying make up hydrogen and carbon monoxide to the hydroformylation zone; maintaining in the hydroformylation zone temperature and pressure conditions effective for the hydroformylation of the reactant alkene; recovering from the hydroformylation zone an overhead vapour stream containing reactant alkene, hydrogen, carbon monoxide, alkene hydrogenation product(s), aldehyde product and aldehyde condensation products; subjecting the vapour stream to condensation condition to condense therefrom condensible components comprising unreacted alkene, aldehyde product, and aldehyde condensation products; recycling non-condensed components of the vapour stream comprising hydrogen and carbon monoxide to the hydroformylation zone; recovering aldehyde product; and recycling unreacted alkene in liquid form to the hydroformylation zone.
Claim 2
Dependent Claim
172 words
A process for the production of an aldehyde by hydroformylation of an alkene in the presence of a rhodium complex catalyst comprising: providing a hydroformylation zone containing a liquid charge comprising (a) a rhodium complex catalyst wherein rhodium is in complex combination with carbon monoxide and a triorganophosphine, (b) excess triorganophosphine, (c) liquid aldehyde product, and (d) polymeric aldehyde condensation products; feeding liquid reactant alkene to the hydroformylation zone; supplying make up hydrogen and carbon monoxide to the hydroformylation zone; maintaining in the hydroformylation zone temperature and pressure conditions effective for the hydroformylation of the reactant alkene; recovering from the hydroformylation zone an overhead vapour stream containing reactant alkene, hydrogen, carbon monoxide, alkene hydrogenation product(s), aldehyde product and aldehyde condensation products; subjecting the vapour stream to condensation condition to condense therefrom condensible components comprising unreacted alkene, aldehyde product, and aldehyde condensation products; recycling non-condensed components of the vapour stream comprising hydrogen and carbon monoxide to the hydroformylation zone; recovering aldehyde product; and recycling unreacted alkene in liquid form to the hydroformylation zone.
Claim 3
Dependent Claim
52 words
A process according to claim 1, in which the vapour stream from the hydroformylation zone is cooled to effect condensation of a mixture of the condensible components which is then distilled in a distillation zone to separate an overhead product comprising unreacted alkene from a bottoms product comprising aldehyde product and aldehyde.
Claim 4
Dependent Claim
39 words
A process according to claim 2, in which the overhead product from the distillation zone is cooled by air cooling, by external water cooling, or by refrigeration in order to condense unreacted alkene for return to the hydroformylation zone.
Claim 5
Dependent Claim
48 words
A process according to claim 1, in which the vapour stream from the hydroformylation zone is cooled to produce an aldehyde-rich condensate containing also aldehyde condensation products, whereupon the uncondensed components comprising unreacted alkene(s) are further cooled to condense unreacted alkene(s) therefrom for recycle to the hydroformylation zone.
Claim 6
Dependent Claim
46 words
A process according to any one of claims 1 to 4, in which the rate of recycle of non-condensed components of the vapour stream to the hydroformylation zone is at least sufficient to remove aldehyde product in the vapour stream as fast as it is formed.
Claim 7
Dependent Claim
31 words
A process according to claim 5, in which the gas cycle rate is at least sufficient to remove aldehyde condensation products in the vapour stream as fast as they are produced.
Claim 8
Dependent Claim
16 words
process according to any one of claims 1 to 6, in which the triorganophosphine is triphenylphosphine.
Claim 9
Dependent Claim
26 words
A process according to any one of claims 1 to 7, in which the temperature in the hydroformylation zone ranges from about 70°C to about 140°C.
Claim 10
Dependent Claim
102 words
A process according to any one of claims 1 to 8, in which the total pressure in the hydroformylation zone is-less than about 20 kg/cm 2 absolute, the partial pressure attributable to the olefin is less than about 1.5 kg/cm 2 absolute, the total partial pressure attributable to hydrogen and carbon monoxide is less than about 10 kg/cm 2 absolute, the partial pressure attributable to carbor monoxide ranges from about 0 . 1 kg/cm 2 absolute to about 1.5 kg/cm 2 absolute and the partial pressure attributable to hydrogen ranges from about 1.5 kg/cm 2 absolute to about 7.5 kg/cm 2 absolute.
Claim 11
Dependent Claim
17 words
A process according to any one of claims 1 to 9, in which the alkene comprises butene-1.
References Cited (Backward Citations)
No citation records indexed.
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