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Water-based adhesive systems

Assignee: Lord Corp
•
Filing: 1981-06-26
•
Granted: 1984-05-08
•
Expires: 2001-06-26
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Abstract

Abstract ABSTRACT OF THF DISCLOSURE Halogenated conjugated diene-monoalkenyl aromatic alkyl halide copolymer latexes provide adhesive systems which afford adhesive strengths comparable to commercial solvent-based adhesies in bond natural and synthetic elastomers to rigid and non-rigid substrates. Adhesives prepared from such latexes exhibit excellent preheat tolerance and environ-mental resistance.

Inventors

  • 👤 John S. Sadowski

Bibliographic Details

Application Number —
Jurisdiction CA
Data Source google_patents
Last Synchronized 2026-11-08 18:04
CPC Classifications
C; C09; C09J; C09J119/00; C09J119/02; C08; C08F; C08F236/00; C08F236/02; C08F236/04; C08F236/14; C08F236/16; C08K; C08K5/00; C08K5/16; C08K5/32

Claims Analysis

Total Claims: 28
Claim 1
Independent Claim 148 words
An elastomeric copolymer latex composition con-sisting essentially of a) on a dry weight basis, 100 parts by weight of elastomer latex consisting essentially of at least one emul-sion-polymerized copolymer of, (1) at least one halogenated conjugated diene and, (ii), at least one monoalkenyl aroma-tic alkyl halide; and b) on a dry weight basis, from 0.01 to 15 percent by weight of a surfactant system selected from the group con-sisting of anionic surfactant agents and a mixture of at least one anionic surfactant agent and at least one nonionic surfactant agent; the amount of said surfactant system being based on combined weight of said halogenated conjugated diene and said monoalkenyl aromatic alkyl halide comonomers, said copolymer having a monoalkenyl aromatic alkyl halide content in the range from 3 to 33 percent by weight, said copolymer latex having a total solids content in the range from 5 to 70 percent.
Claim 2
Dependent Claim 148 words
An elastomeric copolymer latex composition con-sisting essentially of a) on a dry weight basis, 100 parts by weight of elastomer latex consisting essentially of at least one emul-sion-polymerized copolymer of, (1) at least one halogenated conjugated diene and, (ii), at least one monoalkenyl aroma-tic alkyl halide; and b) on a dry weight basis, from 0.01 to 15 percent by weight of a surfactant system selected from the group con-sisting of anionic surfactant agents and a mixture of at least one anionic surfactant agent and at least one nonionic surfactant agent; the amount of said surfactant system being based on combined weight of said halogenated conjugated diene and said monoalkenyl aromatic alkyl halide comonomers, said copolymer having a monoalkenyl aromatic alkyl halide content in the range from 3 to 33 percent by weight, said copolymer latex having a total solids content in the range from 5 to 70 percent.
Claim 3
Dependent Claim 96 words
An elastomeric copolymer latex composition according to claim 1 wherein said monalkenyl aromatic alkyl halide monomers have the characteristic formula and wherein X is hydrogen, chlorine, bromine or iodine; R is an alkyl group having from 1 to 4 carbon atoms, and the carbon atom of said alkyl group which is attached directly to the aromatic nucleus being substituted with from 1 to 3 halogen atoms selected from the group consisting of chlorine, bromine or iodine; a is 1 or 2; b is 0, 1, or 2; and at least one b is at least 1.
Claim 4
Dependent Claim 15 words
An elastomeric copolymer latex according to claim 1 wherein said halogenated conjugated diene comprises 2,3-dichloro-l,3-butadiene.
Claim 5
Dependent Claim 17 words
An elastomeric copolymer latex according to claim 1 wherein said monoalkenyl aromatic halide comprises vinyl benzyl chloride.
Claim 6
Dependent Claim 18 words
An elastomeric copolymer latex according to claim 3 wherein said monoalkenyl aromatic alkyl halide comprises vinyl benzyl chloride.
Claim 7
Dependent Claim 15 words
An elastomeric copolymer latex according to claim 2 wherein said halogenated conjugated diene comprises 2,3-dichloro-1,3-butadiene.
Claim 8
Dependent Claim 18 words
An elastomeric copolymer latex according to claim 2 wherein said monoalkenyl aromatic alkyl halide com-prises vinyl benzyl chloride.
Claim 9
Dependent Claim 18 words
An elastomeric copolymer latex according to claim 1 having a pH in the range from 4 to 11.
Claim 10
Dependent Claim 18 words
An elastomeric copolymer latex according to claim 2 having a pH in the range from 4 to 11.
Claim 11
Dependent Claim 18 words
An elastomeric copolymer latex according to claim 5 having a pH in the range from 4 to 11.
Claim 12
Dependent Claim 25 words
An elastomeric copolymer latex according to claim 2 having a monoalkenyl aromatic alkyl halide content in the range from 3 to 25 percent by weight.
Claim 13
Dependent Claim 25 words
An elastomeric copolymer latex according to claim 5 having a monoalkenyl aromatic alkyl halide content in the range from 3 to 7 percent by weight.
Claim 14
Dependent Claim 30 words
A copolymer latex composition according to claim 1 having dispersed therein at least one part by weight, per 100 parts of copolymer solids, of at least one aromatic nitroso compound.
Claim 15
Dependent Claim 27 words
A copolymer latex composition according to claim 13 wherein the amount of said aromatic nitroso com-pound is in the range from 1 to 200 parts by weight.
Claim 16
Dependent Claim 94 words
A copolymer latex composition according to claim 14 wherein said monoalkenyl aromatic alkyl halide monomers have the characteristic formulae and wherein X is hydrogen, chlorine, bromine or iodine; R is an alkyl group having from 1 to 4 carbon atoms, the carbon atom of said alkyl group which is attached directly to the aromatic nucleus being substituted with from 1 to 3 halogen atoms selected from the group consisting of chlorine, bromine or iodine; a is 1 or 2; b is 0, 1, or 2; and at least one b, is at least 1.
Claim 17
Dependent Claim 16 words
An elastomeric copolymer latex composition accor-ding to claim 15 wherein said halogenated conjugated diene comprises 2,3-dichloro-1,3-butadiene.
Claim 18
Dependent Claim 19 words
An elastomeric copolymer latex composition according to claim 15 wherein said monoalkenyl aromatic alkyl halide comprises vinyl benzyl chloride.
Claim 19
Dependent Claim 18 words
An elastomeric copolymer latex according to claim 16 wherein said monoalkenyl aromatic alkyl halide comprises vinyl benzyl chloride.
Claim 20
Dependent Claim 18 words
An elastomeric copolymer latex according to claim 14 having a pH in the range from 4 to 11.
Claim 21
Dependent Claim 18 words
An elastomeric copolymer latex according to claim 15 having a pH in the range from 4 to 11.
Claim 22
Dependent Claim 24 words
An elastomeric copolymer latex according to claim 15 having a monoalkenyl aromatic halide content in the range from 3 to 25 percent by weight.
Claim 23
Dependent Claim 18 words
An elastomeric copolymer latex according to claim 21 having a pH in the range from 4 to 11.
Claim 24
Dependent Claim 15 words
An elastomeric copolymer latex according to claim 22 wherein said halogenated conjugated diene comprises 2,3-dichloro-1,3-butadiene.
Claim 25
Dependent Claim 18 words
An elastomeric copolymer latex according to claim 22 wherein said monoalkenyl aromatic alkyl halide comprises vinyl benzyl chloride.
Claim 26
Dependent Claim 18 words
An elastomeric copolymer latex according to claim 23 wherein said monoalkenyl aromatic alkyl halide com-prises vinyl benzyl chloride.
Claim 27
Dependent Claim 25 words
An elastomeric copolymer latex according to claim 18 having a monoalkenyl aromatic alkyl halide content in the range from 3 to 7 percent by weight.
Claim 28
Dependent Claim 18 words
An elastomeric copolymer latex according to claim 26 having a pH in the range from 4 to 11.

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