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CA1045127A Expired / Lapsed CA ⏱️ 0.0 years remaining

Absorbent cellulosic product

Assignee: Personal Products Co
•
Filing: 1975-06-09
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Granted: 1978-12-26
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Expires: 1995-06-09
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Abstract

Abstract Abstract of the Disclosure An insoluble etherified cellulose graft copolymer is provided comprising etherified cellulose which is soluble group consisting of carboxyalkyl cellulose, sulfoalkyl cellu-lose and phosphonoalkyl cellulose and salts thereof. The etherified cellulose has grafted onto its cellulose backbone side chains of polymer moieties in sufficient quantities to render the grafted etherified cellulose insoluble. The products of this invention are used alone or mixed with other absorbent materials such as unmodified cellulose, in the manufacture of absorbent napkins, tampons, sponges and the like.

Inventors

  • 👤 Robert F. Schwenker (Jr.)
  • 👤 Pronoy K. Chatterjee

Bibliographic Details

Application Number —
Jurisdiction CA
Data Source google_patents
Last Synchronized 2026-11-07 13:52
CPC Classifications
C; C08; C08F; C08F251/00; C08F251/02; A; A61; A61L; A61L15/00; A61L15/16; A61L15/22; A61L15/28

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 119 words
An improvement in an absorbent product for absorbing body fluids comprising water-insoluble, cellulose ether selected from the group consisting of carboxyalkyl cellulose, sulfoalkyl cellulose and phosphonoalkyl cellulose, said ether having a degree of substitution ranging from about 0.4 to about 1.3 average number of ether groups per anhydroglucose unit; the improvement comprising said ether having grafted onto its cellulose backbone side chains of hydrophilic polymer moieties in an amount which ranges from about 10 to about 90% by weight, based on the weight of the grafted cellulose ether and sufficient to render said grafted cellulose ether insoluble and to provide said grafted cellulose ether with an XOW in 1.5% by weight aqueous sodium chloride solution of at least 30.
Claim 2
Dependent Claim 119 words
An improvement in an absorbent product for absorbing body fluids comprising water-insoluble, cellulose ether selected from the group consisting of carboxyalkyl cellulose, sulfoalkyl cellulose and phosphonoalkyl cellulose, said ether having a degree of substitution ranging from about 0.4 to about 1.3 average number of ether groups per anhydroglucose unit; the improvement comprising said ether having grafted onto its cellulose backbone side chains of hydrophilic polymer moieties in an amount which ranges from about 10 to about 90% by weight, based on the weight of the grafted cellulose ether and sufficient to render said grafted cellulose ether insoluble and to provide said grafted cellulose ether with an XOW in 1.5% by weight aqueous sodium chloride solution of at least 30.
Claim 3
Dependent Claim 46 words
The absorbent product of claim 1 wherein the hydro-philic polymer moieties are selected from the group consisting of poly(acrylic acid), sodium poly (acrylate), poly (methacrylic acid), potassium poly (methacrylate), poly (vinyl alcohol sulfate), poly (phosphoric acid), poly (vinyl amine), poly (4-vinyl pyridine), and hydrolyzed poly (acrylonitrile).
Claim 4
Dependent Claim 15 words
The absorbent product of claim 2 wherein the hydro-philic polymer moiety comprises hydrolyzed poly (acrylonitrile).
Claim 5
Dependent Claim 20 words
The absorbent product of claim 1 wherein said chains of polymer moieties are copolymers of hydrophilic and hydro-pholic polymer moieties.
Claim 6
Dependent Claim 42 words
The absorbent product of claim 4 wherein said hydro-phobic polymer moieties comprise polymer moieties selected from the group consisting of poly (methyl methacrylate), poly (ethyl methacrylate), poly (ethyl acrylate), poly (butyl acrylate), poly (vinyl acetate), poly (styrene), poly (butadiene), and poly (isoprene).
Claim 7
Dependent Claim 11 words
The absorbent product of claim 1 which is a sanitary napkin.
Claim 8
Dependent Claim 11 words
The absorbent product of claim 1 which is a catamenial tampon.
Claim 9
Dependent Claim 10 words
The absorbent product of claim 1 which is a diaper.
Claim 10
Dependent Claim 105 words
An improvement in an absorbent product for absorbing body fluids comprising water-insoluble carboxyalkyl cellulose having a degree of substitution ranging from about 0.4 to about 1.3 average number of carboxyalkyl groups per anhydroglucose unit; the improvement comprising said carboxyalkyl cellulose having grafted unto its cellulose backbone side chains of hydro-philic polymer moieties in an amount which ranges from about 10 to about 90% by weight, based on the weight of the grafted carboxyalkyl cellulose and sufficient to render said grafted carboxyalkyl cellulose insoluble and to provide said grafted carboxyalkyl cellulose with an XOW in 1.5% by weight aqueous sodium chloride solution of at least 30.
Claim 11
Dependent Claim 105 words
An improvement in an absorbent product for absorbing body fluids comprising water-insoluble carboxyalkyl cellulose having a degree of substitution ranging from about 0.4 to about 1.3 average number of carboxyalkyl groups per anhydroglucose unit; the improvement comprising said carboxyalkyl cellulose having grafted unto its cellulose backbone side chains of hydro-philic polymer moieties in an amount which ranges from about 10 to about 90% by weight, based on the weight of the grafted carboxyalkyl cellulose and sufficient to render said grafted carboxyalkyl cellulose insoluble and to provide said grafted carboxyalkyl cellulose with an XOW in 1.5% by weight aqueous sodium chloride solution of at least 30.
Claim 12
Dependent Claim 47 words
The absorbent product of claim 9 wherein the hydro-philic polymer moieties are selected from the group consisting of poly (acrylic acid), sodium poly (acrylate), poly (meth-acrylic acid), potassium poly (methacrylate), poly (vinyl alcohol sulfate), poly (phosphoric acid), poly (vinyl amine), poly (4-vinyl pyridine) and hydrolyzed poly (acrylonitrile).
Claim 13
Dependent Claim 15 words
The absorbent product of claim 10 wherein the hydro-philic polymer moiety comprises hydrolyzed poly (acrylonitrile).
Claim 14
Dependent Claim 13 words
The absorbent product of claim 9 wherein said carb-oxyalkyl cellulose comprises carboxymethyl cellulose.
Claim 15
Dependent Claim 62 words
The absorbent product of claim 12 wherein said polymer moieties are present in at least the quantities defined by the relationship Degree of Sub-stitution of Carboxymethyl Cellulose 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1,0 1.1 1.2 1.3 Minimum Polymer (% by weight based on weight of said grafted carboxymethyl cellulose) 0 9 12 13 14 15 17 19 21 23 27
Claim 16
Dependent Claim 20 words
The absorbent product of claim 9 wherein said chains of polymer moieties are copolymers of hydrophilic and hydro-phobic polymer moieties.
Claim 17
Dependent Claim 42 words
The absorbent product of claim 14 wherein said hydrophobic polymer moieties comprise polymer moieties selected from the group consisting of poly (methyl methacrylate) poly (ethyl methacrylate), poly (ethyl acrylate), poly (butyl acrylate), poly (vinyl acetate), poly (styrene), poly (butadiene), and poly (isoprene).
Claim 18
Dependent Claim 11 words
The absorbent product of claim 9 which is a sanitary napkin.
Claim 19
Dependent Claim 11 words
The absorbent product of claim 9 which is a catamenial tampon.
Claim 20
Dependent Claim 10 words
The absorbent product of claim 9 which is a diaper.

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