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USRE34838E Expired / Lapsed US ⏱️ 0.0 years remaining

Permanent magnet and method for producing same

Assignee: TDK Corp
•
Filing: 1990-08-23
•
Granted: 1995-01-31
•
Expires: 2010-08-23
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Abstract

Abstract In the rare earth-iron-boron permanent magnet, Ce and La decrease the magnetic properties when used alone but synergistically enhance iHc when used in combination. The composition provided by the present invention is generally expressed by [(Ce x La 1-x ) y R 1-y ] 2 [(Fe 1-u-w Co w M u ) 1-v B v ] 1-z with a proviso of 0.4≦x≦0.9, 0.2<y≦1.0, 0.05≦z≦0.3, 0.01≦v≦0.3, 0≦u≦0.2, 0≦w≦0.5, and M is at least one element selected from the group consisting of Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni, W, Cu, and Ag.

Inventors

  • 👤 Kaneo Mohri
  • 👤 Jiro Yamasaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 10:04
CPC Classifications
H; H01; H01F; H01F1/00; H01F1/01; H01F1/03; H01F1/032; H01F1/04; H01F1/047; H01F1/053; H01F1/055; H01F1/057; H01F1/0571; H01F1/0575; H01F1/0577; H01F1/0578

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 73 words
A permanent .[.magnet.]. .Iadd.magnetic powder or ribbon obtained by the rapid cooling method and .Iaddend.having a composition expressed by (Ce x La 1-x ) z (Fe 1-v B v ) 1-z , with a proviso of 0.4≦x≦0.9, 0.05≦z≦0.3, and 0.01≦v≦0.3 and having a coercive force (iHc) of at least 4 kOe. .[.2. A permanent magnet according to claim 1, wherein said permanent magnet is a sintered magnet..]. .[.3. A permanent magnet according to
Claim 2
Dependent Claim 38 words
claim 1, wherein said permanent magnet is a bonded magnet..]. 4. A permanent .[.magnet.]. .Iadd.magnetic powder or ribbon .Iaddend.according to claim 1, wherein x is from 0.6 to 0.8, v is from 0.02 to 0.15, and z is
Claim 3
Dependent Claim 20 words
from 0.1 to 0.2. 5. A permanent .[.magnet.]. .Iadd.magnetic powder or ribbon .Iaddend.according to claim .[.2.]. .Iadd.1.Iaddend., wherein v is
Claim 4
Dependent Claim 20 words
from 0.03 to 0.12. 6. A permanent .[.magnet.]. .Iadd.magnetic powder or ribbon .Iaddend.according to claim .[.2.]. .Iadd.1.Iaddend., wherein x is
Claim 5
Dependent Claim 112 words
approximately 0.65. 7. A permanent magnet .[.according to claim 1, 2, 3, 4, 5, or 6, wherein.]. .Iadd.formed from a rapidly cooled magnetic material having a composition expressed by (Ce x La 1-x ) z (Fe 1-v B v ) 1-z , with a proviso of 0.4≦x≦0.9, 0.05≦z≦0.3, and 0.01≦v≦0.3 and containing .Iaddend.at least one element selected from the group consisting of Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni, W, Cu, and Ag .[.is contained.]. at an atomic ratio .Iadd.u .Iaddend.of .Iadd.0<u≦.Iaddend.0.2 .[.or less.]. based on the sum of said at least one element and Fe .Iadd.and having a coercive force (iHC) of at
Claim 6
Dependent Claim 60 words
least 4 KOe.Iaddend.. 8. A permanent magnet according to claim .[.1, 2, 3, 4, 5, or 6.]. .Iadd.7 or 9.Iaddend., wherein B is partly replaced with at least one element selected from the group consisting of Si, C, P, N, Ge, and S in an atomic ratio of 0.5 or less based on a sum of B and said at
Claim 7
Dependent Claim 83 words
least one element. 9. A permanent magnet according to claim .[.1.]. .Iadd.7.Iaddend., wherein Co is contained at an atomic ratio (w) and at least one element selected from the group consisting of Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni, W, Cu and Ag is contained at an atomic ratio (u), wherein said (w) is from more than 0 to 0.5 and said (u) is from .[.0.]. .Iadd.0.001 .Iaddend.to 0.2, with the proviso that sum of
Claim 8
Dependent Claim 25 words
(u), (w) and atomic ratio of Fe is 1.0. 10. A permanent magnet according to claim .Iadd.7 or .Iaddend.9, wherein said permanent magnet is a
Claim 9
Dependent Claim 11 words
sintered magnet. 11. A permanent magnet according to claim .Iadd.7 or
Claim 10
Dependent Claim 22 words
.Iaddend.9, wherein said permanent magnet is a bonded magnet. 12. A permanent magnet according to claim .Iadd.7 or .Iaddend.9, wherein x is
Claim 11
Dependent Claim 28 words
from 0.6 to 0.8, v is from 0.02 to 0.15, and z is from 0.1 to 0.2. 13. A permanent magnet according to claim .[.10.]. .Iadd.7 or 9.Iaddend.,
Claim 12
Dependent Claim 115 words
wherein v is from 0.03 to 0.12. 14. A permanent magnet according to claim .[.10.]. .Iadd.7 or 9.Iaddend., wherein x is approximately 0.65. .[.15. A permanent magnet having a composition of [(Ce x La 1-x ) y R 1-y ] z (Fe 1-v B v ) 1-z , wherein R is at least one rare earth element except for Ce and La, but including Y with a proviso of 0.4≦x≦0.9, 0.2<y<1.0, 0.05≦z≦0.3, 0.001≦v≦0.3, and having a coercive force (iHc) of at least 4 kOe..]. .[.16. A permanent magnet according to claim 15, wherein said permanent magnet is a sintered magnet..]. .[.17. A permanent magnet according to claim 15, wherein said permanent magnet is a bonded
Claim 13
Dependent Claim 18 words
magnet..]. 18. A permanent .[.magnet.]. .Iadd.magnetic powder or ribbon .Iaddend.according to claim .[.15.]. .Iadd.34.Iaddend., wherein x is from
Claim 14
Dependent Claim 25 words
6 to 0.8, v is from 0.02 to 0.15, and z is from 0.1 to 0.2. 19. A permanent .[.magnet.]. .Iadd.magnetic powder or ribbon .Iaddend.according
Claim 15
Dependent Claim 25 words
6 to 0.8, v is from 0.02 to 0.15, and z is from 0.1 to 0.2. 19. A permanent .[.magnet.]. .Iadd.magnetic powder or ribbon .Iaddend.according
Claim 16
Dependent Claim 90 words
to claim .[.18.]. .Iadd.34.Iaddend., wherein v is from 0.03 to 0.12. 20. A permanent .[.magnet.]. .Iadd.magnetic powder or ribbon .Iaddend.according to claim .[.19.]. .Iadd.34.Iaddend., wherein x is approximately 0.65. .[.21. A permanent magnet according to claim 15, 16, 17, 18, 19, or 20, wherein at least one element selected from the group consisting of Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni, W, Cu, and Ag is contained at an atomic ratio of 0.2 or less based on the sum of said at
Claim 17
Dependent Claim 53 words
least one element and Fe..]. 22. A permanent magnet according to claim .[.15, 16, 17, 18, 19 or 20.]. .Iadd.23 or 31.Iaddend., wherein B is partly replaced with at least one element selected from the group consisting of Si, C, P, N, Ge, and S in an atomic ratio of 0.5 or less
Claim 18
Dependent Claim 100 words
based on a sum of B and said at least one element. 23. A permanent magnet according to claim .[.15.]. .Iadd.31.Iaddend., wherein Co is contained at an atomic ratio (w) and at least one element selected from the group consisting Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni, W, Cu, and Ag is contained at an atomic ratio (u), wherein said (w) is from more than 0 to 0.5 and said (u) is from .[.0.]. .Iadd.0.001 .Iaddend.to 0.2, with the proviso that sum of (u), (w) and atomic ratio of Fe is 1.0.
Claim 19
Dependent Claim 10 words
A permanent magnet according to claim 23 .Iadd.or 31.Iaddend., wherein
Claim 20
Dependent Claim 21 words
said permanent magnet is a sintered magnet. 25. A permanent magnet according to claim 23 .Iadd.or 31.Iaddend., wherein said permanent magnet
Claim 21
Dependent Claim 29 words
is a bonded magnet. 26. A permanent magnet according to claim 23 .Iadd.or 31.Iaddend., wherein x is from 0.6 to 0.8, v is from 0.02 to 0.15, and z
Claim 22
Dependent Claim 13 words
is from 0.1 to 0.2. 27. A permanent magnet according to claim .[.26.].
Claim 23
Dependent Claim 111 words
.Iadd.23 or 31.Iaddend., wherein v is from 0.03 to 0.12. 28. A permanent magnet according to claim .[.26.]. .Iadd.23 or 31.Iaddend., wherein x is approximately 0.65. .[.29. A permanent magnet having a composition of [(Ce x La 1-x ) y R 1-y ] z [(Fe 1-u-w Co w M u ) 1-v B v ] 1-z with a proviso of 0.4≦x≦0.9, 0.2<y≦1.0, 0.05≦z≦0.3, 0.01≦v≦0.3, 0≦u≦0.2, 0≦w≦0.5, and M is at least one element selected from the group consisting of Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni, W, Cu, and Ag, having a coercive force (iHc) of at least 4 kOe, having been plastically
Claim 24
Dependent Claim 336 words
worked. 30. A permanent magnet according to claim .[.29.]. .Iadd.33.Iaddend., wherein the plastic working method is a method selected from the group consisting of hot-pressing, swaging, extruding, forging, and rolling. .Iadd.31. A permanent magnet formed from a rapidly cooled magnetic material having a composition of [((Ce x La 1-x ) y R 1-y ) z ]((Ce x La 1-x ) y R 1-y ) z (Fe 1-v B v ) 1-z wherein R is at least one rare earth element except for Ce and La, but including Y with a proviso of 0.4≦x≦0.9, 0.2<y<1.0, 0.05≦z≦0.3, 0.01≦v≦0.3 containing at least one element selected from the group consisting of Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni, W, Cu, and Ag at an atomic ratio u of 0<u≦0.2 based on the sum of said at least one element and Fe, having a coercive force (iHc) of at least 4 KOe. .Iaddend. .Iadd.32. A permanent magnet formed of a magnetic powder of claims 1 or 34. .Iaddend. .Iadd.33. A permanent magnet having a composition of ((Ce x La 1-x ) y R 1-y ) z (Fe 1-u-w Co w M u ) 1-y B v ] 1-z with a proviso of 0.4≦x≦0.9, 0.2<y<1.0, 0.05≦z≦0.3, 0.01≦v≦0.3, 0≦u≦0.2, 0≦w≦0.5, and M is at least one element selected from the group consisting of Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni, W, Cu, and Ag having a coercive force (IiHc) of at least 4 kOe, comprising a rapidly cooled magnetic material which has been plastically worked. .Iaddend. .Iadd.34. A permanent magnetic powder or ribbon obtained by a rapid cooling method having a composition of ((Ce x La 1-x ) y R 1-y ) z (Fe 1-v B v ) 1-z , wherein R is at least one rare earth element except for Ce and La but including Y with a proviso of 0.4≦x≦0.9, 0.2<y<1.0, 0.5≦z≦0.3, 0.01≦v≦0.3, and having a coercive force (iHc) of at least 4 KOe. .Iaddend.

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