Infrared reflective optical interference film

Claim 2

An optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum comprising multiple alternating layers of at least first, second, and third "diverse", substantially transparent polymeric materials A, B, and C, each of said layers being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n i , and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials.

Claim 3

The optical interference film of claim 1 in which there is a layer thickness gradient across the thickness of said film.

Claim 4

The optical interference film of claim 2 in which said layer thicknesses increase monotonically across the thickness of said film.

Claim 5

The optical interference film of claim 1 in which the polymeric materials form a repeating unit ABCB.

Claim 6

The optical interference film of claim 1 in which said second polymeric material is a copolymer of said first and third polymeric materials.

Claim 7

The optical interference film of claim 1 in which said second polymeric material is a miscible blend of said first and third polymeric materials.

Claim 8

The optical interference film of claim 6 in which said first polymeric material is polyvinylidene fluoride, said third polymeric material is polymethyl methacrylate.

Claim 9

The optical interference film of claim 6 in which said first polymeric material is a polycarbonate and said third polymeric material is a copolyester based on 1,4-cyclohexanedimethylene terephthalate.

Claim 10

The optical interference film of claim 1 in which said first polymeric material is polystyrene, said second polymeric material is a copolymer of styrene and methyl methacrylate, and said third polymeric material is polymethyl methacrylate.

Claim 11

The optical interference film of claim 1 in which one of said polymeric materials is a copolymer of thiodiphenol and bisphenol A.

Claim 12

The optical interference film of claim 1 in which one of said polymeric materials is polyethylene 2,6 naphthalate.

Claim 13

The optical interference film of claim 1 in which one of said polymeric materials is a copolymer of gluterimide and methyl methacrylate.

Claim 14

The optical interference film of claim 1 in which the optical thickness ratio of material A, f A , is 1/3, the optical thickness ratio of material B, f B , is 1/6, the optical thickness ratio of material C, f C , is 1/3, and ##EQU11##

Claim 15

The optical interference film of claim 1 in which said first polymeric material differs in refractive index from said second polymeric material by at least about 0.03.

Claim 16

The optical interference film of claim 14 in which said second polymeric material differs in refractive index from said third polymeric material by at least about 0.03.

Claim 17

A laminate comprising an optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum, including multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials A, B, and C, said layers being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n i , and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials, laminated to a glass substrate.

Claim 18

A laminate comprising an optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum, including multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials A, B, and C, said layers being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n i , and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials, laminated to a glass substrate.

Claim 19

The laminate of claim 16 in which the optical thickness ratio of material A, f A , is 1/3, the optical thickness ratio of material B, f B , is .[.1/3.]. .Iadd.1/6, the optical thickness ratio of material C, f C , is 1/3, and ##EQU12##

Claim 20

A laminate comprising an optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum, including multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials A, B, and C, said layers being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n i , and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials, laminated to a polymeric resin substrate.

Claim 21

A laminate comprising an optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum, including multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials A, B, and C, said layers being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n i , and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials, laminated to a polymeric resin substrate.

Claim 22

The laminate of claim 18 in which the optical thickness ratio of material A, f A , is 1/3, the optical thickness ratio of material B, f B , is .[.1/3.]. .Iadd.1/6, the optical thickness ratio of material C, f C , is 1/3, and ##EQU13##

Claim 23

The laminate of claim 18 in which said laminate is in the form of a profile. .Iadd.

Claim 24

An optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum comprising multiple alternating layers of at least first, second, and third "diverse", substantially transparent polymeric materials A, B, and C, said layers of first and third polymeric materials being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n i , and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials. .Iaddend. .Iadd.22. A laminate comprising an optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum, including multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials A, B, C, said layers of first and third polymeric materials being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n i , and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials, laminated to a glass substrate. .Iaddend. .Iadd.23. A laminate comprising an optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum, including multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials, A, B, C, said layers of first and third polymeric materials being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n i , and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials, laminated to a polymeric resin substrate. .Iaddend.

Claim 25

An optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum comprising multiple alternating layers of at least first, second, and third "diverse", substantially transparent polymeric materials A, B, and C, said layers of first and third polymeric materials being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n i , and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials. .Iaddend. .Iadd.22. A laminate comprising an optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum, including multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials A, B, C, said layers of first and third polymeric materials being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n i , and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials, laminated to a glass substrate. .Iaddend. .Iadd.23. A laminate comprising an optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum, including multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials, A, B, C, said layers of first and third polymeric materials being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n i , and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials, laminated to a polymeric resin substrate. .Iaddend.