USRE29834E
Expired / Lapsed
US
⏱️ 0.0 years remaining
Cationic dyestuffs
Assignee: Bayer AG
•
Filing: 1977-07-20
•
Granted: 1978-11-14
•
Expires: 1997-07-20
Abstract
Abstract Cationic dyestuffs and processes for their manufacture and their use for dyeing, printing and bulk dyeing of natural and synthetic materials, particularly of polyacrylonitrile and copolymers of acrylonitrile with other vinyl compounds, acid modified aromatic polyesters and acid modified polyamides.
Inventors
- 👤 Alfred Brack
- 👤 Ernst Schmitt
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 17:20
CPC Classifications
D; D06; D06P; D06P1/00; D06P1/41; C; C07; C07D; C07D209/00; C07D209/56; C07D209/80; C07D209/90; C09; C09B; C09B57/00; C09B57/06
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
158 words
Cationic dyestuff of the formula ##STR37## wherein R is hydrogen, methyl, .Iadd.ethyl, .Iaddend.n-propyl, i-propyl, n-butyl, -cyanoethyl, or -hydroxyethyl; R 1 is methyl, n-butyl, allyl, phenyl, p-tolyl, o-tolyl, p-chlorophenyl, or m-nitrophenyl; K is ##STR38## N-methyl-tetrahydroquinolinyl, N-ethyl-tetrahydroquinolinyl, N-β-chloroethyl-tetrahydroquinolinyl, N-β-cyanoethyl-tetrahydroquinolinyl; A is p-phenylene, 2,5-diethoxy-p-phenylene, 2,5-dimethoxy-p-phenylene 3-methyl-p-phenylene, 3-methoxy-p-phenylene, 3-chloro-p-phenylene, 3-methoxycarbonyl-amino-p-phenylene, 3-dimethylamido-carbonylamino-p-phenylene, 3-ethoxy-p-phenylene, or 3-methylamido-carbonylamino-p-phenylene; R 2 is methyl, ethyl, n-propyl, n-butyl, i-butyl, β-chloroethyl, diethylaminoethyl, cyclohexyl, phenyl, p-othoxyphenyl, o-methoxyphenyl, o-tolyl, benzyl, or p-methylbenzyl; R 3 is hydrogen, methyl, ethyl, n-propyl, or n-butyl; R 4 is methyl or ethyl; R 5 is hydrogen, 5-chloro, 5-methoxy, or 5-ethoxy; R 6 is methyl, ethyl, or n-butyl; R 7 is hydrogen or 6-methoxy; R 8 is chloro, cyano, methoxy, methoxycarbonyl, β-ethoxyethyl, β-cyanoethyl, β-hydroxycarbonylethyl, dimethylamino, carbanamido, phenyl, piperidyl, pyrrolidinyl, or morpholinyl; R 9 is hydrogen or methyl; R 10 is hydrogen or ethyl; R 11 is methyl or phenyl; B is the remaining portion of morpholinyl, piperidinyl, pyrrolidinyl, 3-methylpyrazolinyl, 3-phenylpyrazolinyl, or N-β-cyanoethylpiperazinyl; and An .sup.(-) is an anion.
Claim 2
Dependent Claim
158 words
Cationic dyestuff of the formula ##STR37## wherein R is hydrogen, methyl, .Iadd.ethyl, .Iaddend.n-propyl, i-propyl, n-butyl, -cyanoethyl, or -hydroxyethyl; R 1 is methyl, n-butyl, allyl, phenyl, p-tolyl, o-tolyl, p-chlorophenyl, or m-nitrophenyl; K is ##STR38## N-methyl-tetrahydroquinolinyl, N-ethyl-tetrahydroquinolinyl, N-β-chloroethyl-tetrahydroquinolinyl, N-β-cyanoethyl-tetrahydroquinolinyl; A is p-phenylene, 2,5-diethoxy-p-phenylene, 2,5-dimethoxy-p-phenylene 3-methyl-p-phenylene, 3-methoxy-p-phenylene, 3-chloro-p-phenylene, 3-methoxycarbonyl-amino-p-phenylene, 3-dimethylamido-carbonylamino-p-phenylene, 3-ethoxy-p-phenylene, or 3-methylamido-carbonylamino-p-phenylene; R 2 is methyl, ethyl, n-propyl, n-butyl, i-butyl, β-chloroethyl, diethylaminoethyl, cyclohexyl, phenyl, p-othoxyphenyl, o-methoxyphenyl, o-tolyl, benzyl, or p-methylbenzyl; R 3 is hydrogen, methyl, ethyl, n-propyl, or n-butyl; R 4 is methyl or ethyl; R 5 is hydrogen, 5-chloro, 5-methoxy, or 5-ethoxy; R 6 is methyl, ethyl, or n-butyl; R 7 is hydrogen or 6-methoxy; R 8 is chloro, cyano, methoxy, methoxycarbonyl, β-ethoxyethyl, β-cyanoethyl, β-hydroxycarbonylethyl, dimethylamino, carbanamido, phenyl, piperidyl, pyrrolidinyl, or morpholinyl; R 9 is hydrogen or methyl; R 10 is hydrogen or ethyl; R 11 is methyl or phenyl; B is the remaining portion of morpholinyl, piperidinyl, pyrrolidinyl, 3-methylpyrazolinyl, 3-phenylpyrazolinyl, or N-β-cyanoethylpiperazinyl; and An .sup.(-) is an anion.
Claim 3
Dependent Claim
53 words
Cationic dyestuffs of the general formula ##STR39## wherein R 14 denotes methyl, ethyl, propyl, or butyl, R 15 denotes methyl, ethyl, propyl, butyl, pentyl, hexyl, phenyl, or benzyl, R 16 and R 17 independently of one another denote methyl, ethyl, propyl, butyl, pentyl, hexyl, (meth)allyl, or propargyl and An .sup.(-) denotes an anion.
Claim 4
Dependent Claim
53 words
Cationic dyestuffs of the general formula ##STR39## wherein R 14 denotes methyl, ethyl, propyl, or butyl, R 15 denotes methyl, ethyl, propyl, butyl, pentyl, hexyl, phenyl, or benzyl, R 16 and R 17 independently of one another denote methyl, ethyl, propyl, butyl, pentyl, hexyl, (meth)allyl, or propargyl and An .sup.(-) denotes an anion.
Claim 5
Dependent Claim
41 words
Cationic dyestuffs of the general formula ##STR40## wherein R 16 and R 17 independently of one another denote methyl, ethyl, propyl, butyl, pentyl, hexyl, (methy)allyl or propargyl. R 18 denotes a methyl or ethyl group and An .sup.(-) denotes an anion.
Claim 6
Dependent Claim
41 words
Cationic dyestuffs of the general formula ##STR40## wherein R 16 and R 17 independently of one another denote methyl, ethyl, propyl, butyl, pentyl, hexyl, (methy)allyl or propargyl. R 18 denotes a methyl or ethyl group and An .sup.(-) denotes an anion.
Claim 7
Dependent Claim
41 words
Cationic dyestuffs of the general formula ##STR41## wherein R 16 and R 17 independently of one another denote methyl, ethyl, propyl, butyl, pentyl, hexyl, (meth)allyl or propargyl, R 18 denotes a methyl or ethyl group and An .sup.(-) denotes an anion.
Claim 8
Dependent Claim
41 words
Cationic dyestuffs of the general formula ##STR41## wherein R 16 and R 17 independently of one another denote methyl, ethyl, propyl, butyl, pentyl, hexyl, (meth)allyl or propargyl, R 18 denotes a methyl or ethyl group and An .sup.(-) denotes an anion.
Claim 9
Dependent Claim
7 words
A cationic dyestuff of the formula ##STR42##
Claim 10
Dependent Claim
7 words
A cationic dyestuff of the formula ##STR42##
Claim 11
Dependent Claim
7 words
A cationic dyestuff of the formula ##STR43##
Claim 12
Dependent Claim
7 words
A cationic dyestuff of the formula ##STR43##
Claim 13
Dependent Claim
7 words
A cationic dyestuff of the formula ##STR44##
Claim 14
Dependent Claim
7 words
A cationic dyestuff of the formula ##STR44##
Claim 15
Dependent Claim
7 words
A cationic dyestuff of the formula ##STR45##
Claim 16
Dependent Claim
7 words
A cationic dyestuff of the formula ##STR45##
Claim 17
Dependent Claim
7 words
A cationic dyestuff of the formula ##STR46##
Claim 18
Dependent Claim
7 words
A cationic dyestuff of the formula ##STR46##
References Cited (Backward Citations)
US3687972A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-11-13 | 1982-05-15 | 1982-11-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-11-13 | 1986-05-15 | 1986-11-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-11-13 | 1990-05-15 | 1990-11-14 | $7700.00 | Window Closed / Lapsed |