US6461773B1
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Electrolyte for electrochemical device
Assignee: Central Glass Co Ltd
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Filing: 2001-05-08
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Granted: 2002-10-08
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Expires: 2021-05-08
Abstract
Abstract The invention relates to an electrolyte for an electrochemical device. This electrolyte includes a first compound that is an ionic metal complex represented by the general formula (1); and at least one compound selected from special second to fourth compounds, fifth to ninth compounds respectively represented by the general formulas A a+ (PF 6 − ) a , A a+ (ClO 4 − ) a , A a+ (BF 4 − ) a , A a+ (AsF 6 − ) a , and A a+ (SbF 6 − ) a , and special tenth to twelfth compounds, The electrolyte is superior in cycle characteristics and shelf life as compared with conventional electrolytes.
Inventors
- 👤 Shoichi Tsujioka
- 👤 Hironari Takase
- 👤 Mikihiro Takahashi
- 👤 Hiromi Sugimoto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 20:34
CPC Classifications
H; H01; H01G; H01G11/00; H01G11/54; H01G11/56; H01G11/58; H01G11/62; H01M; H01M10/00; H01M10/05; H01M10/052; H01M10/0525; H01M10/056; H01M10/0564; H01M10/0566; H01M10/0568; Y; Y02; Y02E; Y02E60/00; Y02E60/10; Y02E60/13
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
471 words
An electrolyte for an electrochemical device, said electrolyte comprising: a first compound that is an ionic metal complex represented by the general formula (1); and at least one compound selected from the group consisting of compounds corresponding to any one of the formulas wherein A a+ represents a metal ion, onium ion or hydrogen ion; M is a transition metal selected from the group consisting of elements of groups 3 11 of the periodic table, or an element selected from the group consisting of elements of groups 12-15 of the periodic table; a represents a number from 1 to 3; b represents a number from 1 to 3; p is b/a; m represents a number from 1 to 4; n represents a number from 0 to 8; q is 0 or 1; X 1 represents 0, NR 5 or NR 5 R 6; R 1 and R 2 each independently represent H, a halogen, a C 1 -C 10 alkyl group or C 1 -C 10 halogenated alkyl group; R 3 represents a C 1 -C 10 halogenated alkylene group, C 4 -C 20 arylene group or C 4 -C 20 halogenated arylene group, wherein the alkylene and arylene groups of R 3 optionally may carry substituents or include hetero atoms, and one group R 3 optionally may be bonded with another group R 3 ; R 4 represents a halogen, C 1 -C 10 alkyl group, C 1 -C 10 halogenated alkyl group, C 4 -C 20 aryl group, C 4 -C 20 halogenated aryl group of X 2 R 7 , wherein the alkyl and aryl groups of R 4 optionally may carry substituents or hetero atoms, and one group R 4 optionally may be bonded with another group R 4 ; X 2 represents O, S, NR 5 or NR 5 R 6 ; R 5 and R 6 each independently represent H or a C 1 -C 10 alkyl group; R 7 represents a C 1 -C 10 alkyl group, C 1 -C 10 alkyl group, C 1 -C 10 alkyl group, C 1 -C 10 halogenated alkyl group, C 4 -C 20 aryl group, or C 4 -C 20 halogenated aryl group; x, y and z each independently represent a number from 1 to 8; Y 1 , Y 2 and Y 3 each independently represent an SO 2 group or CO group; and R 8 , R 9 and R 10 each independently represent an electron-attracting organic substituent optionally carrying a substituent or including a hetero atom, wherein two or more of R 8 , R 9 and R 10 optionally may be bonded together to form a ring, and wherein one or more of R 8 , R 9 and R 10 optionally may be bonded with an adjacent molecule to form a polymer.
Claim 2
Dependent Claim
471 words
An electrolyte for an electrochemical device, said electrolyte comprising: a first compound that is an ionic metal complex represented by the general formula (1); and at least one compound selected from the group consisting of compounds corresponding to any one of the formulas wherein A a+ represents a metal ion, onium ion or hydrogen ion; M is a transition metal selected from the group consisting of elements of groups 3 11 of the periodic table, or an element selected from the group consisting of elements of groups 12-15 of the periodic table; a represents a number from 1 to 3; b represents a number from 1 to 3; p is b/a; m represents a number from 1 to 4; n represents a number from 0 to 8; q is 0 or 1; X 1 represents 0, NR 5 or NR 5 R 6; R 1 and R 2 each independently represent H, a halogen, a C 1 -C 10 alkyl group or C 1 -C 10 halogenated alkyl group; R 3 represents a C 1 -C 10 halogenated alkylene group, C 4 -C 20 arylene group or C 4 -C 20 halogenated arylene group, wherein the alkylene and arylene groups of R 3 optionally may carry substituents or include hetero atoms, and one group R 3 optionally may be bonded with another group R 3 ; R 4 represents a halogen, C 1 -C 10 alkyl group, C 1 -C 10 halogenated alkyl group, C 4 -C 20 aryl group, C 4 -C 20 halogenated aryl group of X 2 R 7 , wherein the alkyl and aryl groups of R 4 optionally may carry substituents or hetero atoms, and one group R 4 optionally may be bonded with another group R 4 ; X 2 represents O, S, NR 5 or NR 5 R 6 ; R 5 and R 6 each independently represent H or a C 1 -C 10 alkyl group; R 7 represents a C 1 -C 10 alkyl group, C 1 -C 10 alkyl group, C 1 -C 10 alkyl group, C 1 -C 10 halogenated alkyl group, C 4 -C 20 aryl group, or C 4 -C 20 halogenated aryl group; x, y and z each independently represent a number from 1 to 8; Y 1 , Y 2 and Y 3 each independently represent an SO 2 group or CO group; and R 8 , R 9 and R 10 each independently represent an electron-attracting organic substituent optionally carrying a substituent or including a hetero atom, wherein two or more of R 8 , R 9 and R 10 optionally may be bonded together to form a ring, and wherein one or more of R 8 , R 9 and R 10 optionally may be bonded with an adjacent molecule to form a polymer.
Claim 3
Dependent Claim
119 words
An electrolyte according to claim 1 , wherein in formula (1) m represents a number from 1 to 3; n represents a number from 0 to 4; R 3 represents a C 1 -C 10 alkylene group, C 1 -C 10 halogenated alkylene group, C 4 -C 20 arylene group, or C 4 -C 20 halogenated arylene group; and represents a halogen, C 1 -C 10 alkyl group, C 1 -C 10 halogenated alkyl group, C 4 -C 20 aryl group, C 4 -C 20 halogenated aryl group, or X 2 R 7 , and wherein said at least one compound is selected from the group consisting of compounds corresponding to any one of formulas (2), (3), and (4).
Claim 4
Dependent Claim
155 words
An electrolyte according to claim 1 , wherein in formula (1) m represents a number from 1 to 3; n represents a number from 0 to 4; R 3 represents a C 1 -C 10 alkylene group, C 1 -C 10 halogenated alkylene group, C 4 -C 20 arylene group or C 4 -C 20 halogenated arylene group; and R 4 represents a halogen, C 1 -C 10 alkyl group, C 1 -C 10 halogenated alkyl group, C 4 -C 20 aryl group, C 4 -C 20 halogenated aryl group, or X 2 R 7 , and wherein said at least one compound is selected from the group consisting of compounds corresponding to any one of formulas: A a+ (PF 6 − ) a A a+ (ClO 4 − ) a A a+ (BF 4 − ) a A a+ (AsF 6 − ) a , and A a+ (SbF 6 − ) a .
Claim 5
Dependent Claim
39 words
An electrolyte according to claim 1 , wherein M represents an element selected from the group consisting of Al, B, V, Ti, Si, Zr, Ge, Sn, Cu, Y, Zn, Ga, Nb, Ta, Bi, P, As, Sc, Hf, and Sb.
Claim 6
Dependent Claim
22 words
An electrolyte according to claim 4 , wherein M represents an element selected from the group consisting of Al, B and P.
Claim 7
Dependent Claim
21 words
An electrolyte according to claim 1 , wherein said A a+ is a lithium ion, quaternary ammonium ion or hydrogen ion.
Claim 8
Dependent Claim
22 words
An electrolyte according to claim 1 , wherein at least one of R 1 and R 2 is a fluorinated alkyl group.
Claim 9
Dependent Claim
15 words
An electrolyte according to claim 7 , wherein said fluorinated alkyl group is trifluoromethyl group.
Claim 10
Dependent Claim
29 words
An electrolyte according to claim 1 , wherein R 3 is such that a chelate ring containing M in formula (1) is a closed loop of 5-10 bonded atoms.
Claim 11
Dependent Claim
19 words
An electrolyte according to claim 1 , wherein R 7 is a C 1 -C 10 fluorinated alkyl group.
Claim 12
Dependent Claim
28 words
An electrolyte according to claim 1 , wherein said first compound and said at least one compound are present in a molar ratio of from 1:99 to 99:1.
Claim 13
Dependent Claim
45 words
An ion conductor for an electrochemical device, said ion conductor comprising: an electrolyte according to claim 1 ; and a further constituent selected from the group consisting of a nonaqueous solvent, a polymer and a mixture thereof, wherein electrolyte is dissolved in said further constituent.
Claim 14
Dependent Claim
25 words
An ion conductor according to claim 12 , wherein said further constituent is an aprotic nonaqueous solvent, and said ion conductor is an electrolytic solution.
Claim 15
Dependent Claim
43 words
An ion conductor according to claim 13 , wherein said further constituent comprises a nonaqueous solvent mixture of a first aprotic solvent having a dielectric constant of 20 or greater and a second aprotic solvent having a dielectric constant of 10 or less.
Claim 16
Dependent Claim
16 words
An ion conductor according to claim 12 , wherein A a + is a lithium ion.
Claim 17
Dependent Claim
24 words
An ion conductor according to claim 12 , wherein said further constituent comprises an aprotic polymer, and said ion conductor is a solid electrolyte.
Claim 18
Dependent Claim
28 words
An ion conductor according to claim 12 , wherein said electrolyte is present in a concentration within a range of from 0.1 mol/dm 3 to a saturated concentration.
Claim 19
Dependent Claim
29 words
An ion conductor according to claim 17 , wherein said electrolyte is present in a concentration within a range of from 0.5 mol/dm 3 to 1.5 mol/dm 3 .
Claim 20
Dependent Claim
61 words
An electrochemical device comprising: (a) an ion conductor, and (b) first and second electrodes received in said ion conductor; wherein said ion conductor comprises: (1) an electrolyte according to claim 1 ; and (2) a further constituent selected from the group consisting of a nonaqueous solvent, a polymer and a mixture thereof, wherein said electrolyte is dissolved in said further constituent.
Claim 21
Dependent Claim
17 words
An electrochemical device according to claim 19 , which is a cell or an electrical double-layer capacitor.
Claim 22
Dependent Claim
20 words
An electrochemical device according to claim 20 , wherein said cell is a lithium cell or a lithium ion cell.
References Cited (Backward Citations)
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