Curable resin composition

Claim 1

A curable resin composition which comprises (I) a reactive silicon group-containing polyether oligomer, (II) a copolymer comprising a molecular chain substantially composed of one or more acrylate ester monomer units and/or methacrylate ester monomer units and (III) an accelerator, said reactive silicon group-containing polyether oligomer having, within the molecule thereof, a partial structure represented by the general formula (1): —O—R 1 —CH(R 2 )—CH 2 —(Si(R 3 2−b )(X b )O) m Si(R 4 3−a )X a (1) wherein R 1 represents a divalent organic group of 1 to 20 carbon atoms containing at least one constituent element selected from the group consisting of hydrogen, oxygen and nitrogen, R 2 represents an alkyl group of 1 to 10 carbon atoms, R 3 and R 4 may be the same or different and each represents an alkyl group of 1 to 20 carbon atoms, an aryl group of 6 to 20 carbon atoms or an aralky) group of 7 to 20 carbon atoms or a triorganosiloxy group of the formula (R′) 3 SiO—, in which R′ is a monovalent hydrocarbon group of 1 to 20 carbon atoms and the three R′ groups may be the same or different, and where there are two or more R 3 or R 4 groups, they may be the same or different; X represents a hydroxyl group or hydrolyzable group and, where there are two or more X groups, they may be the same or different; a represents 0, 1, 2 or 3, b represents 0, 1 or 2, m represents an integer of 0 to 19, and the b's in the m —(Si(R 3 2−b )(X b )—O)— groups may be the same or different, provided that the condition a+Σb≧1 is satisfied; wherein said component (I) is obtained by reacting a polyether oligomer having an unsaturated bond introduced therein of the general formula (2): —O—R 1 —C(CH 3 )═CH 2 (2) wherein R 1 is as defined above, with a reactive silicon group-containing compound represented by the general formula (3): H—(Si(R 3 2−b )(X b )—O) m Si(R 4 3−a )X a (3) wherein R 3 , R 4 , a, b, m and X are as defined above, in an oxygen-containing atmosphere in the presence of a catalyst and elemental sulfur.

Claim 17

A method of adhesion of an adherend, which comprises applying a curable resin composition to said adherend, allowed it to stand in the air to develop tack in the adhesive layer, and conducting adhesion of said adherends during the tack is retained in the adhesive layer, wherein said curable resin composition comprises (I) a reactive silicon group-containing polyether oligomer, (II) a copolymer comprising a molecular chain substantially composed of one or more acrylate ester monomer units and/or methacrylate ester monomer units and (III) an accelerator, said reactive silicon group-containing polyether oligomer having, within the molecule thereof, a partial structure represented by the general formula (1): —O—R 1 —CH(R 2 )—CH 2 —(Si(R 3 2−b )(X b )O) m Si(R 4 3−a )X a (1) wherein R 1 represents a divalent organic group of 1 to 20 carbon atoms containing at least one constituent element selected from the group consisting of hydrogen, oxygen and nitrogen, R 2 represents an alkyl group of 1 to 10 carbon atoms, R 3 and R 4 may be the same or different and each represents an alkyl group of 1 to 20 carbon atoms, an aryl group of 6 to 20 carbon atoms or an aralkyl group of 7 to 20 carbon atoms or a triorganosiloxy group of the formulas (R′) 3 SiO—, in which R′ is a monovalent hydrocarbon group of 1 to 20 carbon atoms and the three R′ groups may be the same or different, and where there are two or more R 3 or R 4 groups, they may be the same or different; X represents a hydroxyl group or a hydrolyzable group and, where there are two or more X Groups, they may be the same or different; a represents 0, 1, 2 or 3, b represents 0, 1 or 2, m represents an integer of 0 to 19, and the b's in the m —(Si(R 3 2−b )(X b )—O)— groups may b the same or different, provided that the condition a+Σb≧1 is satisfied.

Claim 18

A method of adhesion of an adherend, which comprises applying a curable resin composition to said adherend, allowed it to stand in the air to develop tack in the adhesive layer, and conducting adhesion of said adherends during the tack is retained in the adhesive layer, wherein said curable resin composition comprises (I) a reactive silicon group-containing polyether oligomer, (II) a copolymer comprising a molecular chain substantially composed of one or more acrylate ester monomer units and/or methacrylate ester monomer units and (III) an accelerator, said reactive silicon group-containing polyether oligomer having, within the molecule thereof, a partial structure represented by the general formula (1): —O—R 1 —CH(R 2 )—CH 2 —(Si(R 3 2−b )(X b )O) m Si(R 4 3−a )X a (1) wherein R 1 represents a divalent organic group of 1 to 20 carbon atoms containing at least one constituent element selected from the group consisting of hydrogen, oxygen and nitrogen, R 2 represents an alkyl group of 1 to 10 carbon atoms, R 3 and R 4 may be the same or different and each represents an alkyl group of 1 to 20 carbon atoms, an aryl group of 6 to 20 carbon atoms or an aralkyl group of 7 to 20 carbon atoms or a triorganosiloxy group of the formulas (R′) 3 SiO—, in which R′ is a monovalent hydrocarbon group of 1 to 20 carbon atoms and the three R′ groups may be the same or different, and where there are two or more R 3 or R 4 groups, they may be the same or different; X represents a hydroxyl group or a hydrolyzable group and, where there are two or more X Groups, they may be the same or different; a represents 0, 1, 2 or 3, b represents 0, 1 or 2, m represents an integer of 0 to 19, and the b's in the m —(Si(R 3 2−b )(X b )—O)— groups may b the same or different, provided that the condition a+Σb≧1 is satisfied.