← Back to Patent Explorer
US6022679A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic support and a method of manufacturing the same

Assignee: Fujifilm Holdings Corp
•
Filing: 1998-01-09
•
Granted: 2000-02-08
•
Expires: 2018-01-09
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract There is disclosed a method of manufacturing a photographic polyester film, comprising forming an unstretched film controlling; each of the temperature of the inlet of a melt extruder, at a temperature in the range from "the melting point of the polymer (Tm)"-10 DEG C. to the Tm+15 DEG C.; the temperature of the central part of a screw, at a temperature in the range from the Tm to the Tm+30 DEG C.; and the temperature of the outlet thereof, at a temperature in the range from the Tm+10 DEG C. to the Tm+35 DEG C., followed by biaxial stretching and heat-setting, and a photographic support manufactured by the method. The thus obtained photographic polyester support excels in photographic properties, adhesiveness, and mechanical strength, and that moreover hardly causes a core set curl and fog formation.

Inventors

  • 👤 Fumio Kawamoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 11:58
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/795; G03C1/7954; G03C2200/00; G03C2200/43; G03C2200/60; Y; Y10; Y10S; Y10S430/00; Y10S430/136

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 229 words
A photographic support, wherein the support comprises a polyester whose content of acetaldehyde is 5 ppm or less, and/or wherein an amount of the remaining oligomer in the support is 1.5 mg/m 2 or less, wherein the polyester is made by a method comprising subjecting polyester pellets, whose ratio of surface area (mm 2 ) to volume (mm 3 ) is not less than 0.5, to heat treatment at a temperature in the range of from the Tg+10° C. to the Tm-20° C. and forming an unstretched film controlling; each of the temperature of the inlet of a melt extruder, in the range of from the melting point of the polyester (Tm)-10° C. to the Tm+15° C.; the temperature of the central part of a screw, in the range of from the Tm to the Tm+30° C.; and the temperature of the outlet thereof, in the range of from the Tm+10° C. to the Tm+35° C., followed by biaxially stretching and heat-setting, wherein the polyester is (i) a blend of polyethylene naphthalate and polyethylene terephthalate, or (ii) a polyester produced by polymerizing monomers consisting essentially of a dicarboxylic acid selected from the group consisting of terephthalic acid and 2,6-naphthalene dicarboxylic acid and a diol of ethylene glycol, wherein a molar ratio of terephthalic acid to 2,6-naphthalene dicarboxylic acid is in the range of from about 0.5:0.5 to about 0:1.0.
Claim 2
Dependent Claim 229 words
A photographic support, wherein the support comprises a polyester whose content of acetaldehyde is 5 ppm or less, and/or wherein an amount of the remaining oligomer in the support is 1.5 mg/m 2 or less, wherein the polyester is made by a method comprising subjecting polyester pellets, whose ratio of surface area (mm 2 ) to volume (mm 3 ) is not less than 0.5, to heat treatment at a temperature in the range of from the Tg+10° C. to the Tm-20° C. and forming an unstretched film controlling; each of the temperature of the inlet of a melt extruder, in the range of from the melting point of the polyester (Tm)-10° C. to the Tm+15° C.; the temperature of the central part of a screw, in the range of from the Tm to the Tm+30° C.; and the temperature of the outlet thereof, in the range of from the Tm+10° C. to the Tm+35° C., followed by biaxially stretching and heat-setting, wherein the polyester is (i) a blend of polyethylene naphthalate and polyethylene terephthalate, or (ii) a polyester produced by polymerizing monomers consisting essentially of a dicarboxylic acid selected from the group consisting of terephthalic acid and 2,6-naphthalene dicarboxylic acid and a diol of ethylene glycol, wherein a molar ratio of terephthalic acid to 2,6-naphthalene dicarboxylic acid is in the range of from about 0.5:0.5 to about 0:1.0.
Claim 3
Dependent Claim 40 words
The photographic support as claimed in claim 1, wherein the support comprises a polyester comprising naphthalenedicarboxylic acid and ethylene glycol as a main component and the support has a glass transition temperature (Tg) of from 90° C. to 200° C.
Claim 4
Dependent Claim 12 words
The photographic support as claimed in claim wherein the support comprises polyethylene-2,6-naphthalate.
Claim 5
Dependent Claim 29 words
The photographic support as claimed in claim 1, wherein the support is subjected to heat treatment at a temperature of from 50° C. to the glass transition temperature (Tg).
Claim 6
Dependent Claim 32 words
The photographic support as claimed in claim 4, wherein the heat treatment is carried out before coating a subbing layer of a light-sensitive layer, but after a surface treatment of the support.
Claim 7
Dependent Claim 250 words
A silver halide photographic light-sensitive material, comprising at least one light-sensitive silver halide emulsion layer on at least one surface of a photographic support, wherein the support comprises a polyester whose content of acetaldehyde is 5 ppm or less, and/or wherein an amount of the remaining oligomer in the support is 1.5 mg/m 2 or less, wherein the polyester is made by a method comprising subjecting polyester pellets, whose ratio of surface area (mm 2 ) to volume (mm 3 ) is not less than 0.5, to heat treatment at a temperature in the range of from the Tg+10° C. to the Tm-20° C. and forming an unstretched film controlling; each of the temperature of the inlet of a melt extruder, in the range of from the melting point of the polyester (Tm)-10° C. to the Tm+15° C.; the temperature of the central part of a screw, in the range of from the Tm to the Tm+30° C.; and the temperature of the outlet thereof, in the range of from the Tm+10° C. to the Tm+35° C., followed by biaxially stretching and heat-setting, wherein the polyester is (i) a blend of polyethylene naphthalate and polyethylene terephthalate, or (ii) a polyester produced by polymerizing monomers consisting essentially of a dicarboxylic acid selected from the group consisting of terephthalic acid and 2,6-naphthalene dicarboxylic acid and a diol of ethylene glycol, wherein a molar ratio of terephthalic acid to 2,6-naphthalene dicarboxylic acid is in the range of from about 0.5:0.5 to about 0:1.0.
Claim 8
Dependent Claim 250 words
A silver halide photographic light-sensitive material, comprising at least one light-sensitive silver halide emulsion layer on at least one surface of a photographic support, wherein the support comprises a polyester whose content of acetaldehyde is 5 ppm or less, and/or wherein an amount of the remaining oligomer in the support is 1.5 mg/m 2 or less, wherein the polyester is made by a method comprising subjecting polyester pellets, whose ratio of surface area (mm 2 ) to volume (mm 3 ) is not less than 0.5, to heat treatment at a temperature in the range of from the Tg+10° C. to the Tm-20° C. and forming an unstretched film controlling; each of the temperature of the inlet of a melt extruder, in the range of from the melting point of the polyester (Tm)-10° C. to the Tm+15° C.; the temperature of the central part of a screw, in the range of from the Tm to the Tm+30° C.; and the temperature of the outlet thereof, in the range of from the Tm+10° C. to the Tm+35° C., followed by biaxially stretching and heat-setting, wherein the polyester is (i) a blend of polyethylene naphthalate and polyethylene terephthalate, or (ii) a polyester produced by polymerizing monomers consisting essentially of a dicarboxylic acid selected from the group consisting of terephthalic acid and 2,6-naphthalene dicarboxylic acid and a diol of ethylene glycol, wherein a molar ratio of terephthalic acid to 2,6-naphthalene dicarboxylic acid is in the range of from about 0.5:0.5 to about 0:1.0.
Claim 9
Dependent Claim 43 words
The silver halide photographic light-sensitive material as claimed in claim 6, wherein the support comprises a polyester comprising naphthalenedicarboxylic acid and ethylene glycol as a main component and the support has a glass transition temperature (Tg) of from 90° C. to 200° C.
Claim 10
Dependent Claim 16 words
The silver halide photographic light-sensitive material as claimed in claim 6, wherein the support comprises polyethylene-2,6-naphthalate.
Claim 11
Dependent Claim 32 words
The silver halide photographic light-sensitive material as claimed in claim 6, wherein the support is subjected to heat treatment at a temperature of from 50° C. to the glass transition temperature (Tg).
Claim 12
Dependent Claim 35 words
The silver halide photographic light-sensitive material as claimed in claim 9, wherein the heat treatment is carried out before coating a subbing layer of a light-sensitive layer, but after a surface treatment of the support.
Claim 13
Dependent Claim 44 words
The silver halide photographic light-sensitive material as claimed in claim 9, wherein the light-sensitive material is wound around a spool having an external diameter of 3 to 10 mm, and wherein a thickness of the photographic support is of from 60 to 100 μm.

References Cited (Backward Citations)

US5270160A Cited
US5472831A Cited
US5294473A Cited
JPH06116378A Cited
US5736309A Cited
US5677116A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2003-02-07 2003-08-09 2004-02-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2007-02-07 2007-08-09 2008-02-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2011-02-07 2011-08-09 2012-02-08 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag