US6004524A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Lowering of the nitrogen oxide levels in exhaust gases by controlled addition of NH3
Assignee: BASF SE
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Filing: 1993-02-05
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Granted: 1999-12-21
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Expires: 2013-02-05
Abstract
Abstract A process for selective catalytic reduction of nitrogen oxides from exhaust gases, preferably those from diesel engines in vehicles, using pulsed superstoichiometric addition of NH 3 or NH 3 -releasing substances, comprises controlling the pulsed superstoichiometric addition of NH 3 in such a way that, after it has started, the addition is interrupted again only when the amount of NH 3 stored in the catalyst has reached a specific upper threshold value which is predetermined in accordance with the catalyst properties and the catalyst volume, the amount of NH 3 stored being calculated from the difference between the metered amount of NH 3 and the amount of NO x separated off, which is determined from the NO x concentration in the exhaust gas and the average degree of separation, and the addition of NH 3 is resumed only when the amount of NH 3 stored in the catalyst, which is determined in the same way, has reached a predetermined lower threshold value, this pulsed addition of NH 3 being interrupted after a predetermined number of cycles until the amount of NH 3 stored in the catalyst, which is determined in the manner described, has completely reacted, this completing one entire cycle of the pulsed addition of NH 3 .
Inventors
- 👤 Bernd Morsbach
- 👤 Helmut Daudel
- 👤 Uwe Gaertner
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 04:55
CPC Classifications
F; F01; F01N; F01N11/00; B; B01; B01D; B01D53/00; B01D53/30; B01D53/34; B01D53/92; B01D53/94; B01D53/9404; B01D53/9409; B01D53/9495; F01N3/00; F01N3/08; F01N3/10; F01N3/18; F01N3/20; F01N3/206; F01N3/208; F01N2560/00; F01N2560/02; F01N2560/026; F01N2560/06; F01N2570/00; F01N2570/18; F01N2610/00; F01N2610/02; F01N2610/14; F01N2610/1453; F01N2610/146; F01N2900/00; F01N2900/04; F01N2900/0421; F01N2900/06; F01N2900/08; F01N2900/14; F01N2900/16; F01N2900/1622; F02; F02B; F02B3/00; F02B3/06; Y; Y02; Y02A; Y02A50/00; Y02A50/20; Y02T; Y02T10/00; Y02T10/10; Y02T10/12; Y02T10/40
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
237 words
A process for selective catalytic reduction of nitrogen oxides from exhaust gases using pulsed superstoichiometric addition of NH 3 or NH 3 -releasing substances, which comprises controlling the pulsed superstoichiometric addition of NH 3 in such a way that, after it has started, the addition is interrupted again only when the amount of NH 3 stored in the catalyst has reached a specific upper threshold value which is predetermined in accordance with the catalyst properties and the catalyst volume, the amount of NH 3 stored being calculated from the difference between the metered amount of NH 3 and the amount of NO x separated off, which is determined from the NO x concentration in the exhaust gas and the average degree of separation, and the addition of NH 3 is resumed only when the amount of NH 3 stored in the catalyst, which is determined in the same way, has reached a predetermined lower threshold value, this pulsed addition of NH 3 being interrupted after a predetermined number of cycles until the amount of NH 3 stored in the catalyst, which is determined in the manner described, has either completely reacted or reached a defined loading as determined by the increase of NO x concentration downstream of the catalyst to a predetermined threshold value which corresponds to said defined loading of N 3 , this completing one entire cycle of the pulsed addition of NH 3 .
Claim 2
Dependent Claim
237 words
A process for selective catalytic reduction of nitrogen oxides from exhaust gases using pulsed superstoichiometric addition of NH 3 or NH 3 -releasing substances, which comprises controlling the pulsed superstoichiometric addition of NH 3 in such a way that, after it has started, the addition is interrupted again only when the amount of NH 3 stored in the catalyst has reached a specific upper threshold value which is predetermined in accordance with the catalyst properties and the catalyst volume, the amount of NH 3 stored being calculated from the difference between the metered amount of NH 3 and the amount of NO x separated off, which is determined from the NO x concentration in the exhaust gas and the average degree of separation, and the addition of NH 3 is resumed only when the amount of NH 3 stored in the catalyst, which is determined in the same way, has reached a predetermined lower threshold value, this pulsed addition of NH 3 being interrupted after a predetermined number of cycles until the amount of NH 3 stored in the catalyst, which is determined in the manner described, has either completely reacted or reached a defined loading as determined by the increase of NO x concentration downstream of the catalyst to a predetermined threshold value which corresponds to said defined loading of N 3 , this completing one entire cycle of the pulsed addition of NH 3 .
Claim 3
Dependent Claim
51 words
The process as of claim 1, wherein the exhaust gases are from diesel engines and wherein the NO x concentration in the exhaust gas is calculated from the relevant process parameters of the process in which the exhaust gas is formed, based on engine speed, control rod travel and loading pressure.
Claim 4
Dependent Claim
40 words
The process of claim 1, wherein the average degree of separation is determined from separation performance characteristics based on the catalyst temperature, the amount of exhaust gas, the NO x concentration in the exhaust gas and the NH 3 loading.
Claim 5
Dependent Claim
41 words
The process of claim 1, wherein the upper and lower threshold values for switching on and switching off the addition of NH 3 are specified in the form of performance characteristics as a function of engine speed and exhaust gas temperature.
Claim 6
Dependent Claim
65 words
The process of claim 1, wherein the NO x concentration downstream of the catalyst is measured and the interruption in NH 3 metering after the predetermined number of cycles does not continue until the NH 3 stored in the catalyst has completely reacted but the addition of NH 3 is resumed when the NO x concentration downstream of the catalyst exceeds a predetermined threshold value.
Claim 7
Dependent Claim
45 words
The process of claim 5, wherein the threshold value of the NO x concentration downstream of the catalyst is determined as a function of the instantaneous values of the NO x concentration upstream of the catalyst, the amount of exhaust gas and the catalyst temperature.
References Cited (Backward Citations)
US4963332A
Cited
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 2002-12-20 | 2003-06-21 | 2003-12-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2006-12-20 | 2007-06-21 | 2007-12-21 | $3760.00 | Window Closed / Lapsed |
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