US6003305A
Expired / Lapsed
US
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Method of reducing internal combustion engine emissions, and system for same
Assignee: Linde Engineering North America Inc
•
Filing: 1997-09-02
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Granted: 1999-12-21
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Expires: 2017-09-02
Abstract
Abstract A process is provided for preparing oxymorphone from morphine by: (1) reacting morphine with (1a) an acyl halide or anhydride to form 3-acylmorphine, or (1b) reacting morphine with benzyl-halide to form 3-benzylmorphine; (2) Oxidizing the 6-hydroxy group of the 3-acyl or 3-benzylmorphine so as to form the corresponding 3-acyl or 3-benzylmorphinone; and thereafter either by (3a) or (3b): (3a) introducing a β-oriented hydroxy group at the 14-position of the 3-acyl- or 3-benzyl-morphinone with aqueous hydrogen peroxide and an acid at a temperature of about 15° to about 70° C. to form the 3-acyl or 3-benzyl-14-hydroxymorphinone; (3b) acylating the 3-acyl or 3-benzyl-morphinone with an acylating agent so as to form the dienol acylate followed by oxidizing the dienol acetate to the corresponding 3-acyl or 3-benzyl-14 -hydroxymorphinone; (4) hydrogenating the 3-acyl-14-hydroxymorphinone with a catalyst so as to form the 3-acyloxymorphone; (5) hydrolyzing the 3-acyl-oxymorphone with aqueous acidic or basic solution to form oxymorphone; (6) hydrogenating the 3-benzyl-14-hydroxymorphinone with a catalyst so as to form oxymorphone.
Inventors
- 👤 Richard J. Martin
- 👤 John D. Stilger
- 👤 Mark R. Holst
- 👤 John D. Young
- 👤 Michael P. Barkdoll
- 👤 Bradley L. Edgar
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 17:28
CPC Classifications
F; F01; F01N; F01N9/00; F01N9/002; B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9404; B01D53/9409; B01D53/9431; F01N13/00; F01N13/009; F01N13/0097; F01N3/00; F01N3/02; F01N3/021; F01N3/023; F01N3/025; F01N3/0253; F01N3/027; F01N3/033; F01N3/035; F01N3/037; F01N3/08; F01N3/10; F01N3/24; F01N3/26; F01N3/28; F01N3/2882; F01N2240/00; F01N2240/02; F01N2240/16; F01N2330/00; F01N2330/08; F01N2610/00; F01N2610/02; F01N2610/03; Y; Y02; Y02T; Y02T10/00; Y02T10/10; Y02T10/12; Y02T10/40
Claims Analysis
Total Claims: 67
Claim 1
Independent Claim
119 words
A method for destroying soot in an exhaust stream from an internal combustion engine, comprising the steps of: providing a flameless thermal oxidizer including a matrix of heat-resistant media; directing the engine exhaust stream into the matrix; heating at least a portion of the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot to initiate oxidizing at least a portion of the soot within the matrix in a substantially self-sustaining reaction wave; monitoring at least one temperature within the matrix; and controlling the location of a reaction wave within the matrix in response to the temperature monitoring step to stabilize the oxidation reaction within the reaction wave.
Claim 2
Independent Claim
119 words
A method for destroying soot in an exhaust stream from an internal combustion engine, comprising the steps of: providing a flameless thermal oxidizer including a matrix of heat-resistant media; directing the engine exhaust stream into the matrix; heating at least a portion of the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot to initiate oxidizing at least a portion of the soot within the matrix in a substantially self-sustaining reaction wave; monitoring at least one temperature within the matrix; and controlling the location of a reaction wave within the matrix in response to the temperature monitoring step to stabilize the oxidation reaction within the reaction wave.
Claim 3
Dependent Claim
29 words
The method of claim 1 wherein the matrix bed within the reaction wave is maintained at a temperature within the range of about 1400° F. to about 3500° F.
Claim 4
Dependent Claim
19 words
The method of claim 1 wherein the reaction within the reaction wave is characterized by lack of a flame.
Claim 5
Dependent Claim
48 words
The method of claim 1 wherein the reaction forms at least one of: a substantially planar reaction wave that is approximately perpendicular to an engine exhaust stream flow direction; a substantially cylindrical reaction wave; an inverted -V reaction wave; a Bunsen reaction wave; and a Burke-Schumann reaction wave.
Claim 6
Dependent Claim
88 words
The method of claim 1 wherein the step of heating at least a portion of the matrix comprises at least one of: electric resistance heating of at least a portion of the matrix by passing an electric current through a conductive portion of the matrix; introducing combustible gas into the matrix and igniting the combustible gas therein; producing an electric arc; and catalyzing at least a portion of the exhaust stream to react while maintaining the catalyst below the temperature at which thermal deactivation of the catalyst occurs.
Claim 7
Dependent Claim
37 words
The method of claim 1 wherein the engine exhaust stream comprises at least one of: an exhaust stream from an internal combustion engine burning gasoline and an exhaust stream from an internal combustion engine burning diesel fuel.
Claim 8
Dependent Claim
30 words
The method of claim 1 further comprising a step of adding heat to the matrix and to incoming gases to control stability and location of the reaction within the matrix.
Claim 9
Dependent Claim
71 words
The method of claim 1 wherein the media is selected from a group comprising at least one of a random ceramic packing, ceramic balls, ceramic saddles, a structured ceramic packing, a ceramic foam material, a ceramic honeycomb shaped material, a metal matrix, a random metal packing, a structured metal packing, and an engineered matrix having a plurality of flow control portions that are defined by the linear gas velocity characteristics thereof.
Claim 10
Dependent Claim
25 words
The method of claim 1 further comprising the step of controlling stability and location of the reaction wave with a waveholder disposed within the matrix.
Claim 11
Dependent Claim
31 words
The method of claim 1 further comprising the step of directing an air stream into the matrix, the air stream supplying at least a portion of reactants for the oxidizing step.
Claim 12
Dependent Claim
23 words
The method of claim 10 further comprising the step of pre-heating the air stream prior to directing the air stream into the matrix.
Claim 13
Dependent Claim
38 words
The method of claim 11 wherein the adjusting step includes the step of adjusting a location of the reaction wave by adjusting at least one of the air stream flow rate and the engine exhaust stream flow rate.
Claim 14
Dependent Claim
36 words
The method of claim 10 further comprising the step of producing a pre-mixed process stream by substantially mixing the engine exhaust stream and the air stream together within an inlet plenum disposed upstream of the matrix.
Claim 15
Dependent Claim
41 words
The method of claim 10 further comprising the step of: adjusting a flow rate of at least one of the engine exhaust stream and the air stream in response to the temperature monitoring step so as to enhance the oxidizing step.
Claim 16
Dependent Claim
47 words
The method of claim 1 further comprising the steps of: supplying a supplemental fuel stream to the matrix from at least one of a vapor and a liquid fuel from a fuel tank; and reacting at least a portion of the supplemental fuel stream within the matrix.
Claim 17
Dependent Claim
61 words
The method of claim 15 wherein the heating step comprises the step of heating at least a portion of the matrix of heat-resistant media to an initial temperature above an autoignition temperature of at least one of a group comprising the engine exhaust stream, the supplemental fuel stream, and a mixture of the engine exhaust stream and the supplemental fuel stream.
Claim 18
Dependent Claim
41 words
The method of claim 16 further comprising the step of: adjusting a flow rate of at least one of the engine exhaust stream and the supplemental fuel stream in response to the monitoring step so as to enhance the oxidizing step.
Claim 19
Dependent Claim
17 words
The method of claim 1 wherein the internal combustion engine is a part of a mobile vehicle.
Claim 20
Independent Claim
142 words
A method for destroying soot in an exhaust stream from an internal combustion engine, comprising the steps of: providing a thermal oxidizer including a matrix of heat-resistant media and at least one longitudinal feed tube, the matrix being disposed substantially in an annulus surrounding the at least one feed tube; directing the engine exhaust stream substantially longitudinally into the at least one feed tube; directing the engine exhaust stream from the at least one feed tube through the matrix in a substantially longitudinal direction that is substantially counter-current to the flow direction through the feed tube; heating at least one of the at least one feed tube and the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot; and oxidizing at least a portion of the soot within the matrix.
Claim 21
Independent Claim
142 words
A method for destroying soot in an exhaust stream from an internal combustion engine, comprising the steps of: providing a thermal oxidizer including a matrix of heat-resistant media and at least one longitudinal feed tube, the matrix being disposed substantially in an annulus surrounding the at least one feed tube; directing the engine exhaust stream substantially longitudinally into the at least one feed tube; directing the engine exhaust stream from the at least one feed tube through the matrix in a substantially longitudinal direction that is substantially counter-current to the flow direction through the feed tube; heating at least one of the at least one feed tube and the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot; and oxidizing at least a portion of the soot within the matrix.
Claim 22
Dependent Claim
18 words
The method of claim 19 wherein each one of the at least one feed tube houses heat-resistant media.
Claim 23
Dependent Claim
59 words
The method of claim 19 wherein the step of directing the engine exhaust stream from the at least one feed tube into the matrix comprises the step of directing the engine exhaust stream from the at least one feed tube through the matrix in a substantially longitudinal direction that is opposite to the flow direction through the feed tube.
Claim 24
Independent Claim
157 words
A method for destroying soot in an exhaust stream from an internal combustion engine, comprising the steps of: providing a thermal oxidizer including a first matrix of heat-resistant media and at least one longitudinal feed tube, the first matrix being disposed substantially in an annulus surrounding the at least one feed tube, the at least one longitudinal feed tube housing a second matrix of heat resistant media; directing the engine exhaust stream substantially longitudinally through the at least one feed tube through at least a portion of the first matrix; directing the engine exhaust stream from the at least one feed tube through the second matrix in a substantially radial direction; heating at least one of the at least one feed tube and the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot; and oxidizing at least a portion of the soot within the matrix.
Claim 25
Independent Claim
157 words
A method for destroying soot in an exhaust stream from an internal combustion engine, comprising the steps of: providing a thermal oxidizer including a first matrix of heat-resistant media and at least one longitudinal feed tube, the first matrix being disposed substantially in an annulus surrounding the at least one feed tube, the at least one longitudinal feed tube housing a second matrix of heat resistant media; directing the engine exhaust stream substantially longitudinally through the at least one feed tube through at least a portion of the first matrix; directing the engine exhaust stream from the at least one feed tube through the second matrix in a substantially radial direction; heating at least one of the at least one feed tube and the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot; and oxidizing at least a portion of the soot within the matrix.
Claim 26
Independent Claim
155 words
A method for destroying soot in an exhaust stream from an internal combustion engine, comprising the steps of: providing at least one longitudinal tube that is disposed within a matrix of heat-resistant media; directing the engine exhaust stream to flow substantially longitudinally through the media; directing the engine exhaust stream to flow from the matrix into the at least one longitudinal tube; heating at least one of the at least one longitudinal tube and the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot to initiate oxidizing at least a portion of the soot within at least one of the matrix and the at least one longitudinal tube; monitoring at least one temperature within the matrix; and controlling the location of a reaction wave within the matrix in response to the temperature monitoring step to stabilize the oxidation reaction within the reaction wave.
Claim 27
Independent Claim
155 words
A method for destroying soot in an exhaust stream from an internal combustion engine, comprising the steps of: providing at least one longitudinal tube that is disposed within a matrix of heat-resistant media; directing the engine exhaust stream to flow substantially longitudinally through the media; directing the engine exhaust stream to flow from the matrix into the at least one longitudinal tube; heating at least one of the at least one longitudinal tube and the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot to initiate oxidizing at least a portion of the soot within at least one of the matrix and the at least one longitudinal tube; monitoring at least one temperature within the matrix; and controlling the location of a reaction wave within the matrix in response to the temperature monitoring step to stabilize the oxidation reaction within the reaction wave.
Claim 28
Dependent Claim
60 words
The method of claim 23 wherein the step of providing at least one longitudinal tube includes providing at least one longitudinal tube that houses a second matrix of heat-resistant media and the step of directing the engine exhaust stream to flow from the matrix into the at least one longitudinal tube includes directing the engine exhaust through the second matrix.
Claim 29
Independent Claim
170 words
A system for destroying soot in an exhaust stream from an internal combustion engine for combusting at least one of a diesel fuel, a gasoline, and a gaseous fuel, comprising: a thermal oxidizer in fluid communication with the exhaust stream and having a matrix of heat-resistant media disposed therein, the matrix having an upstream side and a downstream side; a heater coupled thereto for heating at least a portion of the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot to initiate oxidizing at least a portion of the soot within the matrix; and a control system including at least one temperature sensor that is disposed within the matrix and for providing a signal that represents a temperature within a portion of the matrix, the control system operatively coupled to the heater and the temperature sensor, and for receiving the temperature signal and stabilizing a reaction wave in the matrix within which oxidation of the exhaust stream occurs.
Claim 30
Independent Claim
170 words
A system for destroying soot in an exhaust stream from an internal combustion engine for combusting at least one of a diesel fuel, a gasoline, and a gaseous fuel, comprising: a thermal oxidizer in fluid communication with the exhaust stream and having a matrix of heat-resistant media disposed therein, the matrix having an upstream side and a downstream side; a heater coupled thereto for heating at least a portion of the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot to initiate oxidizing at least a portion of the soot within the matrix; and a control system including at least one temperature sensor that is disposed within the matrix and for providing a signal that represents a temperature within a portion of the matrix, the control system operatively coupled to the heater and the temperature sensor, and for receiving the temperature signal and stabilizing a reaction wave in the matrix within which oxidation of the exhaust stream occurs.
Claim 31
Dependent Claim
124 words
The system of claim 25 wherein the heater comprises at least one of: an electric resistance heater; a conductive portion of the matrix for receiving an electric current; a burner for providing hot gas; an electric arc element; and a catalytic section of the matrix for catalyzing at least a portion of the exhaust stream to react while maintaining the catalyst below the temperature at which thermal deativation of the catalyst occurs, whereby the heater is for heating at least a portion of the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot to initiate oxidizing at least a portion of the soot within the matrix in a substantially self-sustaining reaction wave.
Claim 32
Dependent Claim
25 words
The system of claim 25 further comprising a waveholder coupled to the matrix, whereby the waveholder stabilizes and controls the location of the reaction wave.
Claim 33
Dependent Claim
53 words
The system of claim 27 wherein the waveholder comprises at least one of an electric resistance heater; a conductive portion of the matrix for receiving an electric current; a burner for providing hot gas; electric arc element, an air nozzle, a raw fuel nozzle, a combination air and fuel nozzle, and a pilot.
Claim 34
Dependent Claim
70 words
The system of claim 25 wherein the media is selected from a group comprising at least one of a random ceramic packing, ceramic balls, ceramic saddles, a structured ceramic packing, a ceramic foam material, a ceramic honeycomb-shaped material, a metal matrix, a random metal packing, a structured metal packing, and an engineered matrix having a plurality of flow control portions that are defined by the linear gas velocity characteristics thereof.
Claim 35
Dependent Claim
32 words
The system of claim 25 further comprising a matrix shell substantially surrounding the matrix and having at least one inlet in fluid communication with the exhaust stream and at least one outlet.
Claim 36
Dependent Claim
54 words
The system of claim 30 further comprising an inlet plenum disposed between the engine and the upstream side of the matrix and that is formed by the matrix shell and a support member; the support member disposed between the plenum and the matrix, for enabling flow communication therebetween, and coupled to the matrix shell.
Claim 37
Dependent Claim
22 words
The system of claim 31 wherein the inlet plenum includes a plenum matrix of heat-resistant media for directing and distributing flow therein.
Claim 38
Dependent Claim
25 words
The system of claim 31 further comprising means for providing a supplemental fuel stream to the upstream side of the matrix proximate the inlet plenum.
Claim 39
Dependent Claim
40 words
The system of claim 31 wherein the thermal oxidizer includes at least one tube in flow communication with the process stream and disposed within the matrix, each one of the at least one tube having an inlet and an outlet.
Claim 40
Dependent Claim
17 words
The system of claim 34 wherein each one of the at least one tube contains heat-resistant media.
Claim 41
Dependent Claim
25 words
The system of claim 34 wherein the tube inlet is in flow communication with the engine and the tube outlet is disposed in the matrix.
Claim 42
Dependent Claim
14 words
The system of claim 34 wherein the tube inlet is disposed within the matrix.
Claim 43
Dependent Claim
52 words
The system of claim 34 wherein the thermal oxidizer includes an intermediate plenum that is formed by the matrix shell and the matrix, the intermediate plenum having an inlet portion and an adjacent outlet portion that are substantially mutually opposite, whereby the exhaust stream turns approximately 180 degrees within the intermediate plenum.
Claim 44
Dependent Claim
24 words
The system of claim 38 further comprising means for supplying hot gas for increasing the temperature of the process gas into the intermediate plenum.
Claim 45
Dependent Claim
35 words
The system of claim 38 further comprising an outlet plenum formed by the matrix shell and an outlet support member; the outlet support member separating the outlet plenum from the downstream side of the matrix.
Claim 46
Dependent Claim
17 words
The system of claim 38 further comprising means for supplying a supplemental fuel into the intermediate plenum.
Claim 47
Dependent Claim
13 words
The system of claim 38 wherein the intermediate plenum is devoid of media.
Claim 48
Dependent Claim
63 words
The system of claim 30 wherein the control system is in informational communication with the at least one temperature sensor; the control system having an actuating means for controlling a flow rate of at least one of the engine exhaust stream, an air stream in fluid communication with the inlet plenum, and a supplemental fuel stream in fluid communication with the inlet plenum.
Claim 49
Dependent Claim
86 words
The system of claim 30 further comprising: a feed tube having an inlet in flow communication with the engine exhaust stream, an enclosed end opposing the inlet, and plural exit ports longitudinally disposed along the feed tube; the matrix disposed in an annulus around the feed tube, the matrix shell having a plurality of holes therethrough and substantially enclosing the matrix; and, an outer shell disposed around the matrix shell, the feed tube inlet, and the matrix, and the outer shell being in flow communication theretogether.
Claim 50
Dependent Claim
35 words
The system of claim 44 further comprising a heat-resistant media disposed within the feed tube wherebv heat is transferred between the media disposed within the feed tube and the media disposed around the feed tube.
Claim 51
Independent Claim
214 words
A system for destroying soot in an exhaust stream from an internal combustion engine for combusting at least one of a diesel fuel, a gasoline, and a gaseous fuel, comprising: a thermal oxidizer in fluid communication with the exhaust stream and having a matrix of heat-resistant media disposed therein, the matrix having an upstream side and a downstream side, and a heater coupled thereto for heating at least a portion of the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot; a matrix shell substantially surrounding the matrix and having at least one inlet in fluid communication with the exhaust stream and at least one outlet; the matrix shell comprises cooling tubes spaced approximately equidistant apart, housing at least part of the matrix; a feed tube having an inlet in flow communication with the engine exhaust stream, an enclosed end opposing the inlet, and plural exit ports longitudinally disposed along the feed tube, the matrix disposed in an annulus around the feed tube, the matrix shell having a plurality of holes therethrough and substantially enclosing the matrix; and, an outer shell disposed around the matrix shell, the feed tube inlet, and the matrix, and the outer shell being in flow communication theretogether.
Claim 52
Independent Claim
214 words
A system for destroying soot in an exhaust stream from an internal combustion engine for combusting at least one of a diesel fuel, a gasoline, and a gaseous fuel, comprising: a thermal oxidizer in fluid communication with the exhaust stream and having a matrix of heat-resistant media disposed therein, the matrix having an upstream side and a downstream side, and a heater coupled thereto for heating at least a portion of the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot; a matrix shell substantially surrounding the matrix and having at least one inlet in fluid communication with the exhaust stream and at least one outlet; the matrix shell comprises cooling tubes spaced approximately equidistant apart, housing at least part of the matrix; a feed tube having an inlet in flow communication with the engine exhaust stream, an enclosed end opposing the inlet, and plural exit ports longitudinally disposed along the feed tube, the matrix disposed in an annulus around the feed tube, the matrix shell having a plurality of holes therethrough and substantially enclosing the matrix; and, an outer shell disposed around the matrix shell, the feed tube inlet, and the matrix, and the outer shell being in flow communication theretogether.
Claim 53
Dependent Claim
27 words
The system of claim 25 further comprising means for directing an air stream to the exhaust stream at a point proximate the upstream side of the matrix.
Claim 54
Dependent Claim
28 words
The system of claim 25 further comprising means for providing a supplemental fuel stream to the exhaust stream at a point proximate the upstream side of the matrix.
Claim 55
Dependent Claim
23 words
The system of claim 48 wherein the means for providing a supplemental fuel stream comprises a vaporization device for vaporizing a liquid fuel.
Claim 56
Dependent Claim
52 words
The system of claim 48 wherein the means for providing a supplemental fuel stream comprises: a spray nozzle for atomizing a liquid fuel; and a vaporization chamber that is for receiving the fuel from the spray nozzle and that is disposed within the matrix, the spray nozzle housed within the vaporization chamber.
Claim 57
Dependent Claim
14 words
The system of claim 25 wherein the heater is mechanically connected to the matrix.
Claim 58
Independent Claim
131 words
A method for reducing emissions from an internal combustion engine exhaust stream containing soot, comprising the steps of: providing a thermal oxidizer including a matrix of heat-resistant media; directing a process stream including the engine exhaust stream into the matrix; heating at least a portion of the matrix to an initial temperature above an autoignition temperature of at least one of the process stream and the soot; oxidizing at least a portion of the soot within the matrix; controlling the location of a reaction wave within the matrix in response to monitoring a temperature within the matrix, thereby stabilizing the oxidation reaction within the reaction wave; and directing at least a portion of the process stream from the matrix into contact with a catalyst that enhances destruction of oxides of nitrogen.
Claim 59
Independent Claim
131 words
A method for reducing emissions from an internal combustion engine exhaust stream containing soot, comprising the steps of: providing a thermal oxidizer including a matrix of heat-resistant media; directing a process stream including the engine exhaust stream into the matrix; heating at least a portion of the matrix to an initial temperature above an autoignition temperature of at least one of the process stream and the soot; oxidizing at least a portion of the soot within the matrix; controlling the location of a reaction wave within the matrix in response to monitoring a temperature within the matrix, thereby stabilizing the oxidation reaction within the reaction wave; and directing at least a portion of the process stream from the matrix into contact with a catalyst that enhances destruction of oxides of nitrogen.
Claim 60
Dependent Claim
11 words
The method of claim 52 wherein the reaction wave is self-sustaining.
Claim 61
Dependent Claim
29 words
The method of claim 52 wherein the step of directing the process stream into contact with the catalyst includes catalyzing the reaction to enhance destruction of oxides of nitrogen.
Claim 62
Dependent Claim
35 words
The method of claim 52 wherein the step of directing the process stream into contact with the catalyst includes directing the process stream into a catalyst device that houses the catalyst downstream from the matrix.
Claim 63
Independent Claim
122 words
A system for reducing emissions from an internal combustion engine exhaust stream that includes soot, comprising: a thermal oxidizer having a matrix of heat-resistant media disposed therein and a heater coupled thereto for heating at least a portion of the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot; an upstream side of the matrix being in flow communication with the internal combustion engine; a control system for stabilizing a reaction wave within the matrix, the control system including a temperature sensor disposed within the matrix; and a catalyst, downstream of the matrix and in flow communication therewith, for catalyzing a reaction that uses oxides of nitrogen as a reactant.
Claim 64
Independent Claim
122 words
A system for reducing emissions from an internal combustion engine exhaust stream that includes soot, comprising: a thermal oxidizer having a matrix of heat-resistant media disposed therein and a heater coupled thereto for heating at least a portion of the matrix to an initial temperature above an autoignition temperature of at least one of the engine exhaust stream and the soot; an upstream side of the matrix being in flow communication with the internal combustion engine; a control system for stabilizing a reaction wave within the matrix, the control system including a temperature sensor disposed within the matrix; and a catalyst, downstream of the matrix and in flow communication therewith, for catalyzing a reaction that uses oxides of nitrogen as a reactant.
Claim 65
Dependent Claim
31 words
The system of claim 56 wherein the catalyst includes at least one of a noble metal catalyst and a catalyst for catalyzing a reaction using oxides of nitrogen as a reactant.
Claim 66
Dependent Claim
21 words
The system of claim 56 wherein the catalyst is housed in a catalytic device that is located downstream from the matrix.
Claim 67
Dependent Claim
17 words
The system of claim 56 wherein the catalyst is disposed proximate the matrix within a matrix shell.
References Cited (Backward Citations)
No citation records indexed.
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2002-12-20 | 2003-06-21 | 2003-12-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2006-12-20 | 2007-06-21 | 2007-12-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2010-12-20 | 2011-06-21 | 2011-12-21 | $7700.00 | Window Closed / Lapsed |