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US6001318A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for lowering nitrogen oxide levels in combustion engine exhaust gas

Assignee: DMC2 Degussa Metals Catalysts Cerdec AG
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Filing: 1997-12-22
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Granted: 1999-12-14
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Expires: 2017-12-22
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Abstract

Abstract A process is disclosed for lowering nitrogen oxide levels in combustion engine exhaust gas by a reduction catalyst and by controlling the exhaust gas temperature upstream from the catalyst to a constant value, at which the catalyst exhibits maximum conversion for nitrogen oxides. It is possible to maintain maximum conversion over a wide range of engine outlet temperatures of the exhaust gas.

Inventors

  • 👤 Hans Van Den Tillaart
  • 👤 Jurgen Leyrer
  • 👤 Egbert Lox
  • 👤 Thomas Kreuzer
  • 👤 Stephan Eckhoff

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 08:51
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9404; B01D53/9409; B01D53/9495; F; F01; F01N; F01N3/00; F01N3/08; F01N3/10; F01N3/18; F01N3/20; F01N2610/00; F01N2610/03

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 133 words
A process for lowering levels of nitrogen oxides in the exhaust gas stream of lean burn combustion engines comprising catalytically reducing said nitrogen oxides in the presence of a reduction catalyst which reduces nitrogen oxides to nitrogen, using the hydrocarbons and carbon monoxide also present in the exhaust gas as reducing agents, measuring exhaust gas temperature at a point in said stream upstream from said catalyst, and upstream from said point injecting fresh air into the exhaust gas stream to control the temperature of the exhaust gas upstream from the reduction catalyst to a value at which the conversion rate for the nitrogen oxides into nitrogen as the exhaust gas passes in contact with said reduction catalyst is at its maximum to thereby yield nitrogen, water and carbon dioxide in the exhaust gas.
Claim 2
Dependent Claim 133 words
A process for lowering levels of nitrogen oxides in the exhaust gas stream of lean burn combustion engines comprising catalytically reducing said nitrogen oxides in the presence of a reduction catalyst which reduces nitrogen oxides to nitrogen, using the hydrocarbons and carbon monoxide also present in the exhaust gas as reducing agents, measuring exhaust gas temperature at a point in said stream upstream from said catalyst, and upstream from said point injecting fresh air into the exhaust gas stream to control the temperature of the exhaust gas upstream from the reduction catalyst to a value at which the conversion rate for the nitrogen oxides into nitrogen as the exhaust gas passes in contact with said reduction catalyst is at its maximum to thereby yield nitrogen, water and carbon dioxide in the exhaust gas.
Claim 3
Dependent Claim 25 words
The process according to claim 1 wherein as a preliminary step, determining the maximum conversion rate for nitrogen oxide into nitrogen for said reduction catalyst.
Claim 4
Dependent Claim 21 words
The process according to claim 1, further comprising mixing additional reducing agents in gaseous or vapor form into the fresh air.
Claim 5
Dependent Claim 14 words
The process according to claim 1 wherein the reduction catalyst is a DENOX catalyst.
Claim 6
Dependent Claim 20 words
The process according to claim 1 further comprising: measuring the temperature of the exhaust gas upstream from the reduction catalyst.
Claim 7
Dependent Claim 16 words
The process according to claim 1 wherein the air fuel ratio is approximately 1.2 and above.
Claim 8
Dependent Claim 32 words
The process according to claim 1 wherein the exhaust gas is cooled before entry into the reduction catalyst to a temperature at which said catalyst exhibits its maximum conversion for nitrogen oxides.
Claim 9
Dependent Claim 125 words
A process for improving conversion of nitrogen oxides in an exhaust gas stream of a lean burn combustion engine into harmless components by catalytic reduction on a reduction catalyst which reduces nitrogen oxides to nitrogen comprising passing said exhaust gas in contact with said reduction catalyst capable of reducing nitrogen oxides into nitrogen, measuring the temperature of said exhaust gas upstream from the reduction catalyst, and controlling the temperature of said exhaust gas upstream from said reduction catalyst based on said measuring by injecting air into the exhaust gas stream, to thereby bring the temperature of said exhaust gas to a value at which the conversion rate for the nitrogen oxides into harmless components is at its maximum, as previously determined for said reduction catalyst.
Claim 10
Dependent Claim 125 words
A process for improving conversion of nitrogen oxides in an exhaust gas stream of a lean burn combustion engine into harmless components by catalytic reduction on a reduction catalyst which reduces nitrogen oxides to nitrogen comprising passing said exhaust gas in contact with said reduction catalyst capable of reducing nitrogen oxides into nitrogen, measuring the temperature of said exhaust gas upstream from the reduction catalyst, and controlling the temperature of said exhaust gas upstream from said reduction catalyst based on said measuring by injecting air into the exhaust gas stream, to thereby bring the temperature of said exhaust gas to a value at which the conversion rate for the nitrogen oxides into harmless components is at its maximum, as previously determined for said reduction catalyst.
Claim 11
Dependent Claim 30 words
The process according to claim 8 further comprising using the hydrocarbons and carbon monoxide also present in the exhaust gas as reducing agents to yield nitrogen, water and carbon dioxide.
Claim 12
Dependent Claim 25 words
The process according to claim 8, wherein the exhaust gas temperature is cooled to the temperature at which the conversion rate is at a maximum.
Claim 13
Dependent Claim 14 words
The process according to claim 8 wherein the reduction catalyst is a DENOX catalyst.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2002-12-13 2003-06-14 2003-12-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2006-12-13 2007-06-14 2007-12-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2010-12-13 2011-06-14 2011-12-14 $7700.00 Window Closed / Lapsed

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