Electrochemical capacitor

Claim 2

An electrochemical capacitor comprising an anode and a cathode, the anode and the cathode comprising: an electrode substrate; a porous coating on the substrate, the coating comprising a metal oxide and having a surface area of greater than 30 m 2 /g, a porosity in the range of 10 to 80%, a mean grain size between 2 and 100 nm, and a mean pore size of between 0.5 and 20 nm; and an electrolyte in contact with the coating, wherein the metal oxide comprises an anion and a cation in a non-stoichiometric ratio.

Claim 3

An electrochemical capacitor as claimed in claim 1 wherein the coating is selected from a group consisting of a single metal oxide, a mixed metal oxide, a doped metal oxide, and a metal oxide/metal composite.

Claim 4

An electrochemical capacitor as claimed in claim 1 wherein the metal oxide is selected from a group consisting of nickel oxide, silica, titania, aluminum oxide, iron oxide, molybdenum oxide, manganese oxide, ruthenium oxide, rhodium oxide, iridium oxide, osmium oxide, chromium oxide, rhenium oxide, vanadium oxide and tungsten oxide.

Claim 5

An electrochemical capacitor as claimed in claim 1 wherein the metal oxide is nickel oxide.

Claim 6

An electrochemical capacitor as claimed in claim 1 wherein the electrolyte comprises an intercalating ion.

Claim 7

An electrochemical capacitor as claimed in claim 5 wherein the intercalating ion is lithium.

Claim 8

An electrochemical capacitor as claimed in claim 1 comprising a separator in contact with the porous coating.

Claim 9

An electrochemical capacitor as claimed in claim 7 wherein the separator comprises a material selected from the group consisting of a non-conducting polymer and a metal oxide insulating film.

Claim 10

An electrochemical capacitor as claimed in claim 1 having a specific electrochemical capacitance between 10 and 2000 F/g.

Claim 11

An electrochemical capacitor as claimed in claim 1 having a conductivity between 10 -5 per ohm-cm and 10 4 per ohm-cm.

Claim 12

An electrochemical capacitor formed according to a process comprising the steps of: coating onto a pair of electrode substrates a sol comprising metal oxide colloidal particles of between 2 and 100 nm in diameter; drying the sol onto the substrates to form a xerogel; firing the xerogel in an atmosphere at a temperature that does not destroy the porous microstructure of the xerogel, for a time sufficient to yield on the substrates a porous metal oxide material that comprises an anion and a cation in a non-stoichiometric ratio, the material having a surface area of greater than 30 m 2 /g, a porosity in the range of 10 to 80%, a mean grain size between 2 and 100 nm, and a mean pore size of between 0.5 and 20 nm, to form a pair of electrodes; and immersing the electrodes into an electrolyte.

Claim 13

An electrochemical capacitor formed according to a process comprising the steps of: coating onto a pair of electrode substrates a sol comprising metal oxide colloidal particles of between 2 and 100 nm in diameter; drying the sol onto the substrates to form a xerogel; firing the xerogel in an atmosphere at a temperature that does not destroy the porous microstructure of the xerogel, for a time sufficient to yield on the substrates a porous metal oxide material that comprises an anion and a cation in a non-stoichiometric ratio, the material having a surface area of greater than 30 m 2 /g, a porosity in the range of 10 to 80%, a mean grain size between 2 and 100 nm, and a mean pore size of between 0.5 and 20 nm, to form a pair of electrodes; and immersing the electrodes into an electrolyte.

Claim 14

An electrochemical capacitor as claimed in claim 11 wherein the atmosphere comprises a gas selected from the group consisting of an oxidizing gas, a reducing gas and an inert gas.

Claim 15

An electrochemical capacitor as claimed in claim 11 wherein the firing temperature is between 200 and 1000° C.

Claim 16

An electrochemical capacitor as claimed in claim 11 wherein the electrolyte is selected from a group consisting of a non-aqueous electrolyte and an aqueous electrolyte.

Claim 17

An electrochemical capacitor as claimed in claim 11 wherein the electrolyte comprises an intercalating ion.

Claim 18

An electrochemical capacitor as claimed in claim 15 wherein the intercalating ion is lithium.

Claim 19

An electrode comprising: an electrode substrate; a porous coating on the substrate, the coating comprising a metal oxide that comprises an anion and a cation in a non-stoichiometric ratio, the coating having a surface area of greater than 50 m 2 /g, a porosity in the range of 10 to 80%, and a mean pore size of between 0.5 and 20 nm.

Claim 20

An electrode comprising: an electrode substrate; a porous coating on the substrate, the coating comprising a metal oxide that comprises an anion and a cation in a non-stoichiometric ratio, the coating having a surface area of greater than 50 m 2 /g, a porosity in the range of 10 to 80%, and a mean pore size of between 0.5 and 20 nm.

Claim 21

An electrode as claimed in claim 17 wherein the substrate is selected from a group consisting of a foil, a foam, and gauze.

Claim 22

An electrode as claimed in claim 17 wherein the substrate comprises a material selected from the group consisting of aluminum, nickel, and a conductive polymer.

Claim 23

An electrode as claimed in claim 17 wherein the metal oxide comprises nickel oxide.

Claim 24

An electrochemical capacitor consisting of: a pair of electrode substrates; a porous coating on the substrates, the coating comprising a metal oxide that comprises an anion and a cation in a non-stoichiometric ratio, the coating having a surface area of greater than 30 m 2 /g, a porosity in the range of 10 to 80%, a mean grain size between 2 and 100 nm, and a mean pore size of between 0.5 and 20 nm; and an electrolyte in contact with the coating.

Claim 25

An electrochemical capacitor consisting of: a pair of electrode substrates; a porous coating on the substrates, the coating comprising a metal oxide that comprises an anion and a cation in a non-stoichiometric ratio, the coating having a surface area of greater than 30 m 2 /g, a porosity in the range of 10 to 80%, a mean grain size between 2 and 100 nm, and a mean pore size of between 0.5 and 20 nm; and an electrolyte in contact with the coating.