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US5937320A Expired / Lapsed US ⏱️ 0.0 years remaining

Barrier layers for electroplated SnPb eutectic solder joints

Assignee: International Business Machines Corp
•
Filing: 1998-04-08
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Granted: 1999-08-10
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Expires: 2018-04-08
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Abstract

Abstract The present invention provides a means of fabricating a reliable C4 flip-chip structure for low-temperature joining. The electrochemically fabricated C4 interconnection has a barrier layer between the electroplated tin-rich solder bump and the ball-limiting metallurgy that protects the terminal metal in the ball-limiting metallurgy from attack by the Sn in the solder. The barrier layer is electroplated through the same photoresist mask as the solder and thus does not require a separate patterning step. A thin layer of electroplated nickel serves as a reliable barrier layer between a copper-based ball-limiting metallurgy and a tin-lead (Sn--Pb) eutectic C4 ball.

Inventors

  • 👤 Panayotis Constantinou Andricacos
  • 👤 Madhav Datta
  • 👤 Wilma Jean Horkans
  • 👤 Sung Kwon Kang
  • 👤 Keith Thomas Kwietniak

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 16:06
CPC Classifications
H; H10; H10W; H10W72/00; H10W72/90; H10W72/01; H10W72/012; H10W72/019; H10W72/01251; H10W72/01255; H10W72/01931; H10W72/01933; H10W72/01935; H10W72/01938; H10W72/01951; H10W72/01953; H10W72/01955; H10W72/0198; H10W72/20; H10W72/221; H10W72/251; H10W72/252; H10W72/29; H10W72/921; H10W72/923; H10W72/941; H10W72/9415; H10W72/951; H10W95/00

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 138 words
A method of forming C4 bumps on metallic pads embedded in a semiconductor wafer comprising the steps of: (a) depositing a plurality of blanket metal layers on a passivated surface of a semiconductor wafer, wherein said passivated surface of said semiconductor wafer comprises at least one metallic pad embedded therein and a passivating layer having an opening therein on top of said wafer; (b) applying a photoresist material to said plurality of blanket metal layers; (c) patterning said photoresist material to provide a region for C4 solder bump formation; (d) electroplating a metal barrier layer on said region provided in step (c); (e) fabricating a C4 solder bump material on said electroplating metal barrier layer; (f) removing said photoresist material, and (g) etching said plurality of blanket metal layers using said C4 solder bump material as a mask.
Claim 2
Independent Claim 138 words
A method of forming C4 bumps on metallic pads embedded in a semiconductor wafer comprising the steps of: (a) depositing a plurality of blanket metal layers on a passivated surface of a semiconductor wafer, wherein said passivated surface of said semiconductor wafer comprises at least one metallic pad embedded therein and a passivating layer having an opening therein on top of said wafer; (b) applying a photoresist material to said plurality of blanket metal layers; (c) patterning said photoresist material to provide a region for C4 solder bump formation; (d) electroplating a metal barrier layer on said region provided in step (c); (e) fabricating a C4 solder bump material on said electroplating metal barrier layer; (f) removing said photoresist material, and (g) etching said plurality of blanket metal layers using said C4 solder bump material as a mask.
Claim 3
Dependent Claim 27 words
The method of claim 1 wherein said plurality of blanket metal layers includes at least a first adhesion layer and at least a wettable terminal metal layer.
Claim 4
Dependent Claim 29 words
The method of claim 2 wherein said plurality of blanket metal layers further comprises a second adhesion layer between said first adhesion layer and said wettable terminal metal layer.
Claim 5
Dependent Claim 14 words
The method of claim 3 wherein said second adhesion layer is composed of CrCu.
Claim 6
Dependent Claim 33 words
The method of claim 3 wherein the step of etching said plurality of blanket metals includes the step of electrochemical etching of both said wettable terminal metal layer and said second adhesion layer.
Claim 7
Dependent Claim 28 words
The method of claim 5 wherein said electrochemical etching of said wettable terminal metal layer and said second adhesion layer provides an undercut relative to said barrier layer.
Claim 8
Dependent Claim 27 words
The method of claim 2 wherein said first adhesion layer is composed of a metal selected from the group consisting of Ti, W, Cr and alloys thereof.
Claim 9
Dependent Claim 14 words
The method of claim 7 wherein said first adhesion layer is composed of TiW.
Claim 10
Dependent Claim 29 words
The method of claim 2 wherein said wettable terminal metal layer is composed of a metal selected from the group consisting of Cu, Ni, Fe, Au and alloys thereof.
Claim 11
Dependent Claim 15 words
The method of claim 9 wherein said wettable terminal metal layer is composed of Cu.
Claim 12
Dependent Claim 28 words
The method of claim 2 wherein the step of etching said plurality of blanket metal layers includes the step of electrochemical etching of said wettable terminal metal layer.
Claim 13
Dependent Claim 25 words
The method of claim 2 wherein said etching of said plurality of blanket metals includes the step of chemical etching of said first adhesion layer.
Claim 14
Dependent Claim 28 words
The method of claim 1 wherein said electroplated metal barrier layer is composed of a metal selected from the group consisting of Ni, Co, Fe and alloys thereof.
Claim 15
Dependent Claim 15 words
The method of claim 13 wherein said electroplated metal barrier layer is composed of Ni.
Claim 16
Dependent Claim 15 words
The method of claim 13 wherein said electroplated metal barrier layer is composed of NiFe.
Claim 17
Dependent Claim 25 words
The method of claim 1 wherein said C4 solder bump material is a solder selected from the group consisting of Sn, Pb, and alloys thereof.
Claim 18
Dependent Claim 22 words
The method of claim 16 wherein said C4 solder bump material is an alloy of Sn and Pb having a eutectic composition.
Claim 19
Dependent Claim 18 words
The method of claim 1 further comprising reflowing said C4 solder bump material to form a solder ball.

References Cited (Backward Citations)

US5162257A Cited
EP0603296B1 Cited
US5391514A Cited
US5470787A Cited
WO1996030933A2 Cited
US5634268A Cited

USPTO Annuity & Maintenance Windows

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3.5 Years (Year 4) 2002-08-09 2003-02-08 2003-08-10 $2000.00 Window Closed / Lapsed
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