US5936150A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Thin film resonant chemical sensor with resonant acoustic isolator
Assignee: Teledyne Scientific and Imaging LLC
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Filing: 1998-04-13
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Granted: 1999-08-10
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Expires: 2018-04-13
Abstract
Abstract A miniature chemical sensor using a thin film acoustic resonator coated with a chemically sensitive sorbent coating. The thin film acoustic resonator has electrodes separated by a thin piezoelectric layer and is supported by a multilayer resonant acoustic isolator. The resonant acoustic isolator has alternating layers of high and low acoustic impedance material, each layer being one quarter acoustic wavelength thick or an odd multiple thereof at the resonant frequency. The resonant acoustic isolator is solidly mounted on a substrate but provides acoustic isolation between the thin film acoustic resonator and the substrate at a resonant frequency.
Inventors
- 👤 Paul H. Kobrin
- 👤 Charles W. Seabury
- 👤 Alan B. Harker
- 👤 Ronald P. O'Toole
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 20:57
CPC Classifications
G; G01; G01N; G01N29/00; G01N29/02; G01N29/022; G01N29/036; G01N5/00; G01N5/02; G01N2291/00; G01N2291/02; G01N2291/025; G01N2291/0255; G01N2291/0256; G01N2291/04; G01N2291/042; G01N2291/0426
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
112 words
A chemical sensor for sensing chemicals in an environment, comprising: a substrate; a chemically sensitive thin-film acoustic resonator, comprising: a piezoelectric resonator having an acoustic resonance quality, and an organic coating on a surface of said piezoelectric resonator and exposed to the environment, said coating and said piezoelectric resonator together having an acoustic resonance quality less than that of said piezoelectric resonator by itself; and a resonant acoustic isolator, interfacing between said chemically sensitive thin film acoustic resonator and said substrate and having a resonant frequency substantially matching that of said thin film acoustic resonator, thereby acoustically isolating said chemically sensitive thin film acoustic resonator from said substrate at said resonant frequency.
Claim 2
Dependent Claim
112 words
A chemical sensor for sensing chemicals in an environment, comprising: a substrate; a chemically sensitive thin-film acoustic resonator, comprising: a piezoelectric resonator having an acoustic resonance quality, and an organic coating on a surface of said piezoelectric resonator and exposed to the environment, said coating and said piezoelectric resonator together having an acoustic resonance quality less than that of said piezoelectric resonator by itself; and a resonant acoustic isolator, interfacing between said chemically sensitive thin film acoustic resonator and said substrate and having a resonant frequency substantially matching that of said thin film acoustic resonator, thereby acoustically isolating said chemically sensitive thin film acoustic resonator from said substrate at said resonant frequency.
Claim 3
Dependent Claim
62 words
The chemical sensor of claim 1, wherein said resonant acoustic isolator comprises alternating low acoustic impedance layers and high acoustic impedance layers, and wherein said piezoelectric resonator has a thin piezoelectric film with a thickness substantially equal to an integer multiple of a half wavelength of a bulk acoustic wave propagating normal to the surface of said film at said resonant frequency.
Claim 4
Dependent Claim
29 words
The chemical sensor of claim 2, wherein said integer multiple of a half wavelength equals one-half wavelength, and wherein said resonant frequency is in the range of 1-10 Gigahertz.
Claim 5
Dependent Claim
43 words
The chemical sensor of claim 3, wherein each of said low acoustic impedance layers and high acoustic impedance layers has a thickness substantially equal to an odd integer multiple of one-quarter acoustic wavelength at the resonant frequency of said thin film acoustic resonator.
Claim 6
Dependent Claim
20 words
The chemical sensor of claim 4, wherein said coating has a thickness in the range of 20 to 100 nanometers.
Claim 7
Dependent Claim
37 words
The chemical sensor of claim 3, further comprising a temperature compensating material on said electrodes with positive temperature coefficient of acoustic velocity that compensates for a a negative temperature coefficient of acoustic velocity of said piezoelectric material.
Claim 8
Dependent Claim
16 words
The chemical sensor of claim 6, wherein said compensating material comprises silicon dioxide (SiO 2 ).
Claim 9
Dependent Claim
18 words
The chemical sensor of claim 7, wherein said high acoustic impedance layers comprise hafnium oxide (HfO 2 ).
Claim 10
Dependent Claim
134 words
A chemical sensor array for sensing chemicals in an environment, comprising: a common substrate; a plurality of chemical sensors, fabricated on said common substrate, each chemical sensor comprising: a chemically sensitive thin-film acoustic resonator, comprising: (a) a piezoelectric resonator having an acoustic resonance quality, and (b) an organic coating on a surface of said piezoelectric resonator and exposed to the environment, said coating and said piezoelectric resonator together having an acoustic resonance quality less than that of said piezoelectric resonator by itself, and a resonant acoustic isolator, interfacing between said chemically sensitive thin film acoustic resonator and said common substrate and having a resonant frequency substantially matching that of said thin film acoustic resonator, said acoustic isolator acoustically isolating said chemically sensitive thin film acoustic resonator from said common substrate at said resonant frequency.
Claim 11
Dependent Claim
134 words
A chemical sensor array for sensing chemicals in an environment, comprising: a common substrate; a plurality of chemical sensors, fabricated on said common substrate, each chemical sensor comprising: a chemically sensitive thin-film acoustic resonator, comprising: (a) a piezoelectric resonator having an acoustic resonance quality, and (b) an organic coating on a surface of said piezoelectric resonator and exposed to the environment, said coating and said piezoelectric resonator together having an acoustic resonance quality less than that of said piezoelectric resonator by itself, and a resonant acoustic isolator, interfacing between said chemically sensitive thin film acoustic resonator and said common substrate and having a resonant frequency substantially matching that of said thin film acoustic resonator, said acoustic isolator acoustically isolating said chemically sensitive thin film acoustic resonator from said common substrate at said resonant frequency.
Claim 12
Dependent Claim
59 words
The sensor array of claim 9, wherein said resonant acoustic isolators comprise alternating low acoustic impedance layers and high acoustic impedance layers, and wherein said piezoelectric layer has a thickness substantially equal to an integer multiple of a half wavelength for a bulk acoustic wave propagating normal to the surface of said resonator's thin film at said resonant frequency.
Claim 13
Dependent Claim
16 words
The sensor array of claim 10, wherein said resonant frequency is in the 1-10 Gigahertz range.
Claim 14
Dependent Claim
15 words
The sensor array of claim 11, wherein said sensors share a common resonant acoustic isolator.
Claim 15
Dependent Claim
14 words
The sensor array of claim 12, wherein said sensors share a common bottom electrode.
Claim 16
Dependent Claim
14 words
The sensor array of claim 13, wherein said sensors share a common piezoelectric layer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2002-08-09 | 2003-02-08 | 2003-08-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2006-08-09 | 2007-02-08 | 2007-08-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2010-08-09 | 2011-02-08 | 2011-08-10 | $7700.00 | Window Closed / Lapsed |