US5866090A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for separation of carbon dioxide gas
Assignee: Toshiba Corp
•
Filing: 1996-07-31
•
Granted: 1999-02-02
•
Expires: 2016-07-31
Abstract
Abstract A method is disclosed for selectively separating carbon dioxide gas by contacting the carbon dioxide containing gas with a composition containing lithium zirconia at a temperature of 450 DEG C. or more so that carbon dioxide reacts with the lithium zirconia to produce lithium carbonate and zirconia. Subjecting the lithium carbonate and zirconia to a temperature of 600 DEG C. or more so as to produce lithium zirconia and carbon dioxide.
Inventors
- 👤 Kazuaki Nakagawa
- 👤 Hideyuki Ohzu
- 👤 Yoshihiro Akasaka
- 👤 Norihiro Tomimatsu
- 👤 Akiko Watanabe
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 16:46
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/06; H01M8/0662; H01M8/14; H01M2008/147; H01M2300/00; H01M2300/0017; H01M2300/0048; H01M2300/0051; H01M8/0606; H01M8/0612; Y; Y02; Y02C; Y02C20/00; Y02C20/40; Y02E; Y02E60/00; Y02E60/30; Y02E60/50
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
175 words
A method for selectively separating CO 2 gas from a high temperature gas containing a first amount of CO 2 , comprising: subjecting the high temperature gas containing the first amount of CO 2 gas to a first temperature zone having a first temperature of 450° C. or more; providing a functional material comprising lithium zirconia to the first temperature zone; selectively reacting the CO 2 gas with the lithium zirconia thereby decreasing the first amount of CO 2 gas to a second amount of CO 2 gas and forming a first forming system comprising lithium carbonate and zirconia; subjecting the first forming system to a second temperature zone having a second temperature of 600° C. or more with a carrier gas, wherein the second temperature is higher than the first temperature, thereby forming a second forming system comprising lithium zirconia as the functional material and a second high temperature gas containing a third amount of CO 2 gas and the carrier gas; and separating the second high temperature gas from the second forming system.
Claim 2
Independent Claim
175 words
A method for selectively separating CO 2 gas from a high temperature gas containing a first amount of CO 2 , comprising: subjecting the high temperature gas containing the first amount of CO 2 gas to a first temperature zone having a first temperature of 450° C. or more; providing a functional material comprising lithium zirconia to the first temperature zone; selectively reacting the CO 2 gas with the lithium zirconia thereby decreasing the first amount of CO 2 gas to a second amount of CO 2 gas and forming a first forming system comprising lithium carbonate and zirconia; subjecting the first forming system to a second temperature zone having a second temperature of 600° C. or more with a carrier gas, wherein the second temperature is higher than the first temperature, thereby forming a second forming system comprising lithium zirconia as the functional material and a second high temperature gas containing a third amount of CO 2 gas and the carrier gas; and separating the second high temperature gas from the second forming system.
Claim 3
Dependent Claim
32 words
The method according to claim 1, wherein the first temperature is in the range of 450° to 580° C. and the second temperature is in the range of 600° to 800° C.
Claim 4
Dependent Claim
29 words
The method according to claim 1, wherein the functional material further comprises a carbonate of alkali metal so as to lower a melting point of the first forming system.
Claim 5
Dependent Claim
29 words
The method according to claim 3, wherein the amount of the carbonate of alkali metal is in the range of 3 to 20 mol % of the functional material.
Claim 6
Dependent Claim
30 words
The method according to claim 1, wherein the functional material further comprises at least one compound selected from lithium aluminate and lithium tantalate to preclude the functional material from agglomeration.
Claim 7
Dependent Claim
19 words
The method according to claim 5, wherein the compound is 20 to 30% by weight of the functional material.
Claim 8
Dependent Claim
26 words
The method according to claim 1, wherein the difference between the second temperature and the first temperature is in the range of 80° to 250° C.
Claim 9
Dependent Claim
33 words
The method according to claim 1, wherein the method further comprises the step of reversibly changing the first temperature zone to the second temperature zone, while keeping the functional material in its place.
Claim 10
Dependent Claim
23 words
The method according to claim 1, wherein the first step, the second step, and the separating step are repeatedly performed in this order.
Claim 11
Independent Claim
160 words
A method for continuously separating a carbon dioxide gas at a high temperature from a high temperature gas containing the carbon dioxide gas, comprising: supplying the high temperature gas in a first temperature zone having a first temperature of 450° C. or more; providing a functional material comprising lithium zirconia to the first temperature zone; selectively reacting the carbon dioxide gas in the high temperature gas with the functional material so as to form a first forming product comprising lithium carbonate and zirconium oxide, thereby substantially separating the carbon dioxide gas as the carbonate, disposing the first forming product in a second temperature zone having a second temperature of 600° C. or more and containing a carrier gas, and reacting the lithium carbonate and zirconium oxide so as to form a second forming product comprising a second lithium zirconia as the functional material to be used in the first temperature zone and a second carbon dioxide gas to be exhausted.
Claim 12
Independent Claim
160 words
A method for continuously separating a carbon dioxide gas at a high temperature from a high temperature gas containing the carbon dioxide gas, comprising: supplying the high temperature gas in a first temperature zone having a first temperature of 450° C. or more; providing a functional material comprising lithium zirconia to the first temperature zone; selectively reacting the carbon dioxide gas in the high temperature gas with the functional material so as to form a first forming product comprising lithium carbonate and zirconium oxide, thereby substantially separating the carbon dioxide gas as the carbonate, disposing the first forming product in a second temperature zone having a second temperature of 600° C. or more and containing a carrier gas, and reacting the lithium carbonate and zirconium oxide so as to form a second forming product comprising a second lithium zirconia as the functional material to be used in the first temperature zone and a second carbon dioxide gas to be exhausted.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2002-02-01 | 2002-08-03 | 2003-02-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2006-02-01 | 2006-08-03 | 2007-02-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2010-02-01 | 2010-08-03 | 2011-02-02 | $7700.00 | Window Closed / Lapsed |