← Back to Patent Explorer
US5835340A Expired / Lapsed US ⏱️ 0.0 years remaining

Monolithic ceramic capacitor

Assignee: Murata Manufacturing Co Ltd
•
Filing: 1997-07-18
•
Granted: 1998-11-10
•
Expires: 2017-07-18
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A monolithic ceramic capacitor having a plurality of dielectric ceramic layers, internal electrodes, and external electrodes electrically connected to the internal electrode, wherein the dielectric ceramic layers comprise (a) barium titanate having an alkali metal oxide impurity content of not more than about 0.02% by weight, (b) scandium oxide and/or yttrium oxide, (c) gadolinium oxide, terbium oxide and/or dysprosium oxide, (d) manganese oxide, (e) cobalt oxide, and (f) nickel oxide, and is a material containing (1) 100 mols represented by the compositional formula: (1-α-β){BaO}.sub.m •TiO.sub.2 +α{(1-x)M.sub.2 O 3 +xRe 2 O 3 }+β(Mn 1-y-z Ni y Co z )O wherein M 2 O 3 represents the above-mentioned (b); Re 2 O 3 represents the above-mentioned (c); 0.0025≦β≦0.05; β/α≦4; 0<x≦0.50; 0≦1.0; 0≦z1.0; 0≦y+z<1.0; and 1.000<m≦1.035, (2) about 0.5 to 5.0 mol, in terms of MgO, of magnesium oxide and (3) about 0.2 to 3.0 parts by weight, per 100 pph of components (1) and (2), of SiO 2 -TiO 2 -MO-based oxide glass (wherein MO represents at least one member selected from the group consisting of BaO, CaO, SrO, MgO, ZnO, and MnO). The internal electrodes can be nickel or a nickel alloy.

Inventors

  • 👤 Hiroyuki Wada
  • 👤 Harunobu Sano
  • 👤 Norihiko Sakamoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 01:36
CPC Classifications
H; H01; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/06; H01G4/08; H01G4/12; H01G4/1209; H01G4/1218; H01G4/1227; C; C04; C04B; C04B35/00; C04B35/01; C04B35/46; C04B35/462; C04B35/465; C04B35/468

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 288 words
A monolithic ceramic capacitor comprising a laminate of a plurality of dielectric ceramic layers, at least internal electrodes between adjacent dielectric ceramic layers in such a manner that one end of each internal electrode is exposed at different ends of the dielectric ceramic layer alternately, and a pair of external electrodes each electrically connected to different exposed internal electrodes, in which said dielectric ceramic layers comprise (a) barium titanate having an alkali metal oxide impurity content of not more than about 0.02% by weight, (b) at least one member selected from the group consisting of scandium oxide and yttrium oxide, (c) at least one member selected from the group consisting of gadolinium oxide, terbium oxide and dysprosium oxide, (d) manganese oxide, (e) cobalt oxide and (f) nickel oxide, and is a material containing (1) 100 mol of a main component represented by the compositional formula: (1-α-β){BaO}.sub.m •TiO.sub.2 +α{(1-x)M.sub.2 O.sub.3 +xRe.sub.2 O.sub.3 }+β(Mn.sub.1-y-z Ni.sub.y Co.sub.z)O wherein M 2 O 3 represents at least one member selected from the group consisting of Sc 2 O 3 and Y 2 O 3 ; Re 2 O 3 represents at least one member selected from the group consisting of Gd 2 O 3 , Tb 2 O 3 and Dy 2 O 3 ; 0.0025≦α≦0.025; 0.0025≦β≦0.05; β/α≦4; 0<x≦0.50; 0≦y≦1.0; 0≦z≦1.0; 0≦y+z<1.0; and 1.000<m≦1.035, (2) about 0.5 to 5.0 mol, in terms of MgO, of magnesium oxide and (3) about 0.2 to 3.0 parts by weight, per 100 parts by weight of the total weight of said main component (1) and said magnesium oxide (2), of SiO 2 -TiO 2 -MO-based oxide glass, wherein MO represents at least one member selected from the group consisting of BaO, CaO, SrO, MgO, ZnO and MnO.
Claim 2
Dependent Claim 288 words
A monolithic ceramic capacitor comprising a laminate of a plurality of dielectric ceramic layers, at least internal electrodes between adjacent dielectric ceramic layers in such a manner that one end of each internal electrode is exposed at different ends of the dielectric ceramic layer alternately, and a pair of external electrodes each electrically connected to different exposed internal electrodes, in which said dielectric ceramic layers comprise (a) barium titanate having an alkali metal oxide impurity content of not more than about 0.02% by weight, (b) at least one member selected from the group consisting of scandium oxide and yttrium oxide, (c) at least one member selected from the group consisting of gadolinium oxide, terbium oxide and dysprosium oxide, (d) manganese oxide, (e) cobalt oxide and (f) nickel oxide, and is a material containing (1) 100 mol of a main component represented by the compositional formula: (1-α-β){BaO}.sub.m •TiO.sub.2 +α{(1-x)M.sub.2 O.sub.3 +xRe.sub.2 O.sub.3 }+β(Mn.sub.1-y-z Ni.sub.y Co.sub.z)O wherein M 2 O 3 represents at least one member selected from the group consisting of Sc 2 O 3 and Y 2 O 3 ; Re 2 O 3 represents at least one member selected from the group consisting of Gd 2 O 3 , Tb 2 O 3 and Dy 2 O 3 ; 0.0025≦α≦0.025; 0.0025≦β≦0.05; β/α≦4; 0<x≦0.50; 0≦y≦1.0; 0≦z≦1.0; 0≦y+z<1.0; and 1.000<m≦1.035, (2) about 0.5 to 5.0 mol, in terms of MgO, of magnesium oxide and (3) about 0.2 to 3.0 parts by weight, per 100 parts by weight of the total weight of said main component (1) and said magnesium oxide (2), of SiO 2 -TiO 2 -MO-based oxide glass, wherein MO represents at least one member selected from the group consisting of BaO, CaO, SrO, MgO, ZnO and MnO.
Claim 3
Dependent Claim 19 words
A monolithic ceramic capacitor according to claim 1, wherein the internal electrodes are of nickel or a nickel alloy.
Claim 4
Dependent Claim 72 words
A monolithic ceramic capacitor according to claim 2, wherein the alkali metal oxide impurity content of not more than about 0.012% by weight; M 2 O 3 represents Y 2 O 3 ; Re 2 O 3 comprises Dy 2 O 3 ; 0.006≦α≦0.015; 0.005≦β≦0.03; β/α≦3; 0.1≦x≦0.3; 0.1≦y≦0.2; 0.1≦z≦0.5; 0.1≦y+z<0.5; and 1.005≦m≦1.02; the amount of MgO is about 0.8-1.5 mol; the amount of glass is about 1-1.5 parts; and MO comprises CaO.
Claim 5
Dependent Claim 114 words
A monolithic ceramic capacitor according to claim 3, wherein the composition of said SiO 2 -TiO 2 -MO-based oxide glass is, when plotted on a triangular mol % diagram of (SiO 2 , TiO 2 , MO) in the area surrounded by, or on, four straight lines connecting four points: A (85,1,14), B (35,51,14), C (30,20,50), and D (39,1,60) and contains at least one of Al 2 O 3 and ZrO 2 in a total amount of not more than 15 parts by weight per 100 parts by weight of the (SiO 2 , TiO 2 , MO) component, provided that the amount of ZrO 2 is not more than 5 parts by weight.
Claim 6
Dependent Claim 31 words
A monolithic ceramic capacitor according to claim 4, wherein said external electrodes comprise a sintered layer of an electrically conductive metal powder or an electrically conductive metal powder containing glass frit.
Claim 7
Dependent Claim 46 words
A monolithic ceramic capacitor according to claim 4, wherein said external electrodes comprise a first layer made of a sintered layer of an electrically conductive metal powder or an electrically conductive metal layer containing glass frit and a second layer of plating on said first layer.
Claim 8
Dependent Claim 72 words
A monolithic ceramic capacitor according to claim 1, wherein the alkali metal oxide impurity content of not more than about 0.012% by weight; M 2 O 3 represents Y 2 O 3 ; Re 2 O 3 comprises Dy 2 O 3 ; 0.006≦α0.015; 0.005≦β≦0.03; β/α≦3; 0.1≦x≦0.3; 0.1≦y≦0.2; 0.1≦z≦0.5; 0.1≦y+z<0.5; and 1.005≦m≦1.02; the amount of MgO is about 0.8-1.5 mol; the amount of glass is about 1-1.5 parts; and MO comprises CaO.
Claim 9
Dependent Claim 114 words
A monolithic ceramic capacitor according to claim 7, wherein the composition of said SiO 2 -TiO 2 -MO-based oxide glass is, when plotted on a triangular mol % diagram of (SiO 2 , TiO 2 , MO) in the area surrounded by, or on, four straight lines connecting four points: A (85,1,14), B (35,51,14), C (30,20,50), and D (39,1,60) and contains at least one of Al 2 O 3 and ZrO 2 in a total amount of not more than 15 parts by weight per 100 parts by weight of the (SiO 2 , TiO 2 , MO) component, provided that the amount of ZrO 2 is not more than 5 parts by weight.
Claim 10
Dependent Claim 31 words
A monolithic ceramic capacitor according to claim 8, wherein said external electrodes comprise a sintered layer of an electrically conductive metal powder or an electrically conductive metal powder containing glass frit.
Claim 11
Dependent Claim 46 words
A monolithic ceramic capacitor according to claim 8, wherein said external electrodes comprise a first layer made of a sintered layer of an electrically conductive metal powder or an electrically conductive metal layer containing glass frit and a second layer of plating on said first layer.
Claim 12
Dependent Claim 114 words
A monolithic ceramic capacitor according to claim 1, wherein the composition of said SiO 2 -TiO 2 -MO-based oxide glass is, when plotted on a triangular mol % diagram of (SiO 2 , TiO 2 , MO) in the area surrounded by, or on, four straight lines connecting four points: A (85,1,14), B (35,51,14), C (30,20,50), and D (39,1,60) and contains at least one of Al 2 O 3 and ZrO 2 in a total amount of not more than 15 parts by weight per 100 parts by weight of the (SiO 2 , TiO 2 , MO) component, provided that the amount of ZrO 2 is not more than 5 parts by weight.
Claim 13
Dependent Claim 31 words
A monolithic ceramic capacitor according to claim 11, wherein said external electrodes comprise a sintered layer of an electrically conductive metal powder or an electrically conductive metal powder containing glass frit.
Claim 14
Dependent Claim 46 words
A monolithic ceramic capacitor according to claim 11, wherein said external electrodes comprise a first layer made of a sintered layer of an electrically conductive metal powder or an electrically conductive metal layer containing glass frit and a second layer of plating on said first layer.
Claim 15
Dependent Claim 31 words
A monolithic ceramic capacitor according to claim 1, wherein said external electrodes comprise a sintered layer of an electrically conductive metal powder or an electrically conductive metal powder containing glass frit.
Claim 16
Dependent Claim 46 words
A monolithic ceramic capacitor according to claim 1, wherein said external electrodes comprise a first layer made of a sintered layer of an electrically conductive metal powder or an electrically conductive metal layer containing glass frit and a second layer of plating on said first layer.

References Cited (Backward Citations)

US5225960A Cited
US5659456A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2001-11-09 2002-05-11 2002-11-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2005-11-09 2006-05-11 2006-11-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2009-11-09 2010-05-11 2010-11-10 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag