US5780209A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Processing of photographic silver halide photosensitive material
Assignee: Fujifilm Holdings Corp
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Filing: 1997-07-02
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Granted: 1998-07-14
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Expires: 2017-07-02
Abstract
Abstract A photographic silver halide photosensitive material comprising a silver halide emulsion of silver halide grains containing at least 20 mol % of AgCl, tabular grains having an aspect ratio of at least 2 accounting for at least 50% of the projected area of all silver halide grains, and having a Ag coverage of 0.5-1.5 g/m 2 and a gelatin coverage of 0.7-2.1 g/m 2 per one surface and a swelling factor of less than 180% is processed through an automatic processor by replenishing a developer containing an ascorbic acid type compound as a developing agent in an amount of 25-150 ml/m 2 and a fixer in an amount of 13-300 ml/m 2 . The invention is successful in producing images of quality while reducing the amounts of replenishment and spent solutions, increasing processing stability, and eliminating silver sludging.
Inventors
- 👤 Seiji Yamashita
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 06:22
CPC Classifications
G; G03; G03C; G03C5/00; G03C5/16; G03C1/00; G03C1/005; G03C1/0051; G03C5/26; G03C5/29; G03C5/30; G03C1/0053; G03C1/04; G03C1/047; G03C2001/0476; G03C2005/3007; G03C2200/00; G03C2200/21; G03C2200/36; G03C2200/44; G03C2200/57; G03C5/17; G03C7/00; G03C7/30; G03C7/42; Y; Y10; Y10S; Y10S430/00; Y10S430/164
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
179 words
A method for processing a photographic silver halide photosensitive material for medical radiographic imaging after imagewise exposure in an automatic processor with processing solutions including a developer, a fixer, and washing water and/or stabilizer while replenishing the respective processing solutions, said photosensitive material comprising a silver halide emulsion of silver halide grains containing at least 20 mol % of silver chloride, at least 50% of the projected area of all silver halide grains being tabular grains having an aspect ratio of at least 2, said photosensitive material having a silver coverage of less than 1.5 grams and a gelatin coverage of less than 2.1 grams per square meter of one surface thereof and a swelling factor of less than 180%, said developer containing an ascorbic acid type compound as a developing agent and being substantially free of a dihydroxybenzene, and said developer being replenished in an amount of less than 150 ml per square meter of said photosensitive material and said fixer being replenished in an amount of less than 300 ml per square meter of said photosensitive material.
Claim 2
Independent Claim
179 words
A method for processing a photographic silver halide photosensitive material for medical radiographic imaging after imagewise exposure in an automatic processor with processing solutions including a developer, a fixer, and washing water and/or stabilizer while replenishing the respective processing solutions, said photosensitive material comprising a silver halide emulsion of silver halide grains containing at least 20 mol % of silver chloride, at least 50% of the projected area of all silver halide grains being tabular grains having an aspect ratio of at least 2, said photosensitive material having a silver coverage of less than 1.5 grams and a gelatin coverage of less than 2.1 grams per square meter of one surface thereof and a swelling factor of less than 180%, said developer containing an ascorbic acid type compound as a developing agent and being substantially free of a dihydroxybenzene, and said developer being replenished in an amount of less than 150 ml per square meter of said photosensitive material and said fixer being replenished in an amount of less than 300 ml per square meter of said photosensitive material.
Claim 3
Dependent Claim
169 words
The method of claim 1 wherein an overall dry-to-dry processing time is less than 80 seconds, an hourly processing throughput is substantially more than 300 sheets of the quarter-size, a developing tank containing the developer and a fixing tank containing the fixer each have a liquid volume of less than 8.0 liters, a tank for washing water and/or stabilizer includes at least two stages, each stage having a liquid volume of less than 8.0 liters, the overall volume of spent solutions of the developer, the fixer and the washing water and/or stabilizer is less than 450 ml per square meter of said photosensitive material, after processing with the processing solutions, said photosensitive material is dried by means of a heat roller, said photosensitive material is capable of forming an image by combining it with a fluorescent screen having a maximum emission wavelength of longer then 500 nm or shorter than 350 nm, with crossover light being less than 20%, and said fixer contains sodium thiosulfate as a fixing agent.
Claim 4
Dependent Claim
43 words
The method of claim 1 wherein continuous processing is possible in the substantial absence of pipes for the spent solutions of the developer and the fixer, pipes for replenishment and waste discharge of the washing water and/or stabilizer, and a stenchful vapor duct.
Claim 5
Dependent Claim
15 words
The method of claim 2 wherein the overall processing time is less than 50 seconds.
Claim 6
Dependent Claim
41 words
The method of claim 1 wherein in the silver halide emulsion, tabular grains having {100} faces as major faces and an aspect ratio of at least 2 account for at least 50% of the projected area of all silver halide grains.
Claim 7
Dependent Claim
24 words
The method of claim 1 wherein in the silver halide emulsion, the silver halide grains contain 50 to 100 mol % of silver chloride.
Claim 8
Dependent Claim
102 words
The method of claim 1 wherein said photosensitive material further comprises a solid dispersion of a dye of the following general formula (I): ##STR73## wherein R 1 is selected from the class consisting of a hydrogen atom, alkyl, aryl, and heterocyclic group; R 2 is selected from the class consisting of a hydrogen atom, alkyl, aryl, heterocyclic, alkoxycarbonyl, aryloxycarbonyl, carbamoyl, acylamino, ureido, amino, acyl, alkoxy, aryloxy, hydroxy, carboxy, cyano, sulfamoyl, and sulfonamide group; B is a 5- or 6-membered oxygen-containing heterocyclic group or 6-membered nitrogen-containing heterocyclic group; L 1 to L 3 are methine groups; and letter n is 0 to 2.
Claim 9
Dependent Claim
45 words
The method of claim 1 wherein said photosensitive material further comprises a polymer latex produced by polymerizing a difficultly soluble monomer and the polymer latex is added in an amount of 5 to 70% by weight of the weight of a binder in photographic layers.
Claim 10
Dependent Claim
24 words
The method of claim 1 wherein in said photosensitive material, the silver coverage is 0.5 to 1.5 grams per square meter of one surface.
Claim 11
Dependent Claim
24 words
The method of claim 1 wherein in said photosensitive material, the gelatin coverage is 0.7 to 2.0 grams per square meter of one surface.
Claim 12
Dependent Claim
27 words
The method of claim 1 wherein said silver halide emulsion contains 1.0×10 -3 to 5.0×10 -1 mol of a polyhydric alcohol per mol of the silver halide.
Claim 13
Dependent Claim
17 words
The method of claim 1 wherein said photosensitive material has a swelling factor of 30 to 180%.
Claim 14
Dependent Claim
45 words
The method of claim 1 wherein said developer is replenished in an amount of 25 to 150 ml per square meter of said photosensitive material and said fixer is replenished in an amount of 13 to 300 ml per square meter of said photosensitive material.
Claim 15
Dependent Claim
52 words
The method of claim 1 wherein the ascorbic acid type compound in said developer is of the following general formula (II): ##STR74## wherein each of R 1 and R 2 are independently selected from the class consisting of a hydroxyl, substituted or unsubstituted amino, acylamino, alkylsulfonylamino, arylsulfonylamino, alkoxycarbonylamino, mercapto, and alkylthio group.
Claim 16
Dependent Claim
19 words
The method of claim 14 wherein said developer contains 0.01 to 0.8 mol/liter of the ascorbic acid type compound.
Claim 17
Dependent Claim
19 words
The method of claim 14 wherein said developer contains 0.1 to 0.4 mol/liter of the ascorbic acid type compound.
Claim 18
Dependent Claim
14 words
The method of claim 1 wherein said developer is at pH 8.5 to 10.5.
Claim 19
Dependent Claim
16 words
The method of claim 1 wherein said fixer contains 0.1 to 5 mol/liter of a thiosulfate.
Claim 20
Dependent Claim
27 words
The method of claim 1 further comprising the step of drying the photosensitive material using a heat roller at a surface temperature of 60 to 120° C.
Claim 21
Dependent Claim
15 words
The method of claim 4 wherein the overall processing time is 20 to 50 seconds.
Claim 22
Dependent Claim
34 words
The method of claim 2 wherein the hourly processing throughput is 300 to 800 sheets of the quarter-size, and the developing and fixing tanks each have a liquid volume of 4.0 to 8.0 liters.
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JPH0784343A
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US5498511A
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 2001-07-13 | 2002-01-12 | 2002-07-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2005-07-13 | 2006-01-12 | 2006-07-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2009-07-13 | 2010-01-12 | 2010-07-14 | $7700.00 | Window Closed / Lapsed |