Patent US4592681A successfully refreshed from Google Patents.
US5773078A
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Method for depositing zirconium oxide on a substrate
Assignee: General Electric Co
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Filing: 1996-06-24
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Granted: 1998-06-30
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Expires: 2016-06-24
Abstract
Abstract An improved method for depositing zirconium oxide from a zirconium oxide source onto a substrate by means of physical vapor deposition is described. The method includes the step of adding zirconium metal to the zirconium oxide source, which is usually in the form of a cylindrical ingot. The zirconium metal is present in an amount sufficient to chemically bond with a substantial portion of oxygen which would otherwise be freed from the oxide source, as both the zirconium metal and the zirconium oxide source are evaporated during physical vapor deposition. The invention is especially suited for EB-PVD techniques, in which an electron beam is used to evaporate the zirconium metal and the zirconium oxide source during physical vapor deposition. In one embodiment, the zirconium metal comprises a tube which surrounds and contacts at least a portion of the outer surface of the ingot. In another embodiment, the zirconium metal is in the form of a rod inserted in a cavity within the ingot.
Inventors
- 👤 David William Skelly
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 01:09
CPC Classifications
C; C23; C23C; C23C14/00; C23C14/22; C23C14/24; C23C14/06; C23C14/08; C23C14/083; Y; Y02; Y02T; Y02T50/00; Y02T50/60
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
49 words
An improved method for depositing zirconium oxide from a zirconium oxide source onto a substrate by means of physical vapor deposition, comprising the step of adding zirconium metal to the zirconium oxide source by further using the zirconium metal as an evaporation source adjacent to the zirconium oxide source.
Claim 2
Dependent Claim
49 words
An improved method for depositing zirconium oxide from a zirconium oxide source onto a substrate by means of physical vapor deposition, comprising the step of adding zirconium metal to the zirconium oxide source by further using the zirconium metal as an evaporation source adjacent to the zirconium oxide source.
Claim 3
Dependent Claim
39 words
The method of claim 1, wherein the zirconium oxide source is in the form of an ingot, and the zirconium metal comprises a tube which surrounds and contacts at least a portion of the outer surface of the ingot.
Claim 4
Dependent Claim
49 words
The method of claim 1, wherein the zirconium metal is present in an amount sufficient to chemically bond with a substantial portion of oxygen which would otherwise be freed from the oxide source, as both the zirconium metal and the zirconium oxide source are evaporated during physical vapor deposition.
Claim 5
Dependent Claim
25 words
The method of claim 1, wherein an electron beam is used to evaporate the zirconium metal and the zirconium oxide source during physical vapor deposition.
Claim 6
Dependent Claim
31 words
The method of claim 1, wherein the zirconium oxide source is in the form of an ingot, and the zirconium metal comprises a rod inserted in a cavity within the ingot.
Claim 7
Dependent Claim
25 words
The method of claim 1, wherein the zirconium oxide source is in a form selected from the group consisting of beads, powder, grains, and flakes.
Claim 8
Dependent Claim
17 words
The method of claim 6, wherein the zirconium metal is in the form of grains or beads.
Claim 9
Dependent Claim
40 words
The method of claim 1, wherein the physical vapor deposition is carried out in a vacuum chamber operating at a vacuum of about 0.005 millibar, and oxygen is added to the chamber during deposition to substantially maintain the pressure value.
Claim 10
Dependent Claim
16 words
The method of claim 1, wherein the substrate is made of a material comprising a superalloy.
Claim 11
Dependent Claim
10 words
The method of claim 9, wherein the superalloy is nickel-based.
Claim 12
Dependent Claim
15 words
The method of claim 1, wherein the substrate is a component of a turbine engine.
Claim 13
Dependent Claim
29 words
The method of claim 1 where the substrate has a bond coat layer first applied to the substrate to improve adhesion of subsequently applied zirconium oxide on the substrate.
Claim 14
Dependent Claim
39 words
The method of claim 12 where the bond coat is an aluminide or a nickel-base alloy different from the substrate or a MCrAlY coating, where M is selected from the group consisting of Fe, Ni, Co, and mixtures thereof.
Claim 15
Dependent Claim
33 words
The method of claim 1 where the zirconium oxide source is chemically stabilized by a material selected from the group consisting of yttrium oxide, calcium oxide, magnesium oxide, scandium oxide, and mixtures thereof.
Claim 16
Independent Claim
148 words
A method for depositing evaporated zirconium oxide coatings onto a substrate, using a physical vapor deposition apparatus, comprising the steps of: (a.) adding zirconium metal to an ingot of a zirconium oxide source material by using the zirconium metal as an evaporation source adjacent to the zirconium oxide source so that proportionate amounts of the metal and the oxide is exposed to an intense heat source which constitutes part of the apparatus; (b.) evaporating a portion of the zirconium oxide source and zirconium metal by melting the surface of the ingot with the heat source, thereby forming a molten pool surrounding the ingot; and (c.) depositing the evaporated material onto the substrate as a coating, wherein the ratio of zirconium metal to zirconium oxide source material is substantially maintained in a pre-selected proportion sufficient to substantially reduce or prevent the formation of gas bubbles in the molten pool.
Claim 17
Independent Claim
148 words
A method for depositing evaporated zirconium oxide coatings onto a substrate, using a physical vapor deposition apparatus, comprising the steps of: (a.) adding zirconium metal to an ingot of a zirconium oxide source material by using the zirconium metal as an evaporation source adjacent to the zirconium oxide source so that proportionate amounts of the metal and the oxide is exposed to an intense heat source which constitutes part of the apparatus; (b.) evaporating a portion of the zirconium oxide source and zirconium metal by melting the surface of the ingot with the heat source, thereby forming a molten pool surrounding the ingot; and (c.) depositing the evaporated material onto the substrate as a coating, wherein the ratio of zirconium metal to zirconium oxide source material is substantially maintained in a pre-selected proportion sufficient to substantially reduce or prevent the formation of gas bubbles in the molten pool.
Claim 18
Dependent Claim
14 words
The method of claim 15, wherein the intense heat source is an electron beam.
Claim 19
Dependent Claim
40 words
The method of claim 15, wherein the physical vapor deposition is carried out in a vacuum chamber operating at a vacuum of about 0.005 millibar, and oxygen is added to the chamber during deposition to substantially maintain the pressure value.
Claim 20
Dependent Claim
41 words
The method of claim 15, wherein the zirconium oxide source is in the form of a substantially cylindrical ingot, and the zirconium metal comprises a tube which surrounds and contacts at least a portion of the outer surface of the ingot.
Claim 21
Dependent Claim
33 words
The method of claim 15, wherein the zirconium oxide source is in the form of a substantially cylindrical ingot, and the zirconium metal comprises a rod inserted in a cavity within the ingot.
Claim 22
Dependent Claim
16 words
The method of claim 15, wherein the substrate is made of a material comprising a superalloy.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2001-06-29 | 2001-12-29 | 2002-06-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2005-06-29 | 2005-12-29 | 2006-06-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2009-06-29 | 2009-12-29 | 2010-06-30 | $7700.00 | Window Closed / Lapsed |