US5715677A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Diesel NOx reduction by plasma-regenerated absorbend beds
Assignee: University of California
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Filing: 1996-11-13
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Granted: 1998-02-10
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Expires: 2016-11-13
Abstract
Abstract Reduction of NO x from diesel engine exhaust by use of plasma-regenerated absorbent beds. This involves a process for the reduction of NO x and particulates from diesel engines by first absorbing NO x onto a solid absorbent bed that simultaneously acts as a physical trap for the particulate matter, and second regenerating said solid absorbent by pulsed plasma decomposition of absorbed NO x followed by air oxidation of trapped particulate matter. The absorbent bed may utilize all metal oxides, but the capacity and the kinetics of absorption and desorption vary between different materials, and thus the composition of the absorbent bed is preferably a material which enables the combination of NO x absorption capability with catalytic activity for oxidation of hydrocarbons. Thus, naturally occurring or synthetically prepared materials may be utilized, particularly those having NO x absorption properties up to temperatures around 400° C. which is in the area of diesel engine exhaust temperatures.
Inventors
- 👤 P. Henrik Wallman
- 👤 George E. Vogtlin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 14:30
CPC Classifications
F; F01; F01N; F01N3/00; F01N3/02; F01N3/021; F01N3/023; F01N3/0233; B; B01; B01D; B01D53/00; B01D53/34; B01D53/96; B01D53/965; F01N13/00; F01N13/011; F01N3/022; F01N3/0224; F01N3/027; F01N3/031; F01N3/032; F01N3/08; F01N3/0807; F01N3/0821; F01N3/0828; F01N3/0842; F01N3/0871; F01N3/0878; F01N9/00; F01N9/002; F01N2250/00; F01N2250/14; F01N2410/00; F01N2410/12; F01N2570/00; F01N2570/14; Y; Y02; Y02A; Y02A50/00; Y02A50/20; Y02T; Y02T10/00; Y02T10/10; Y02T10/12; Y02T10/40
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
124 words
A process for removing NO x and particulates from an engine exhaust, comprising: providing a plurality of beds containing absorbent/catalyst material; providing means for connecting the beds with engine exhaust, and providing a valve mechanism connected to the beds; providing means for producing a pulsed plasma in the beds; providing means for supplying air to the beds; providing means for activating the valve mechanism for directing engine exhaust through one of the plurality of beds; providing means for activating and controlling the pulsed plasma in another of the plurality of beds; and providing means for activating and controlling the air supplying means; whereby the other of the plurality of beds is regenerated while engine exhaust passes through the one of the plurality of beds.
Claim 2
Dependent Claim
124 words
A process for removing NO x and particulates from an engine exhaust, comprising: providing a plurality of beds containing absorbent/catalyst material; providing means for connecting the beds with engine exhaust, and providing a valve mechanism connected to the beds; providing means for producing a pulsed plasma in the beds; providing means for supplying air to the beds; providing means for activating the valve mechanism for directing engine exhaust through one of the plurality of beds; providing means for activating and controlling the pulsed plasma in another of the plurality of beds; and providing means for activating and controlling the air supplying means; whereby the other of the plurality of beds is regenerated while engine exhaust passes through the one of the plurality of beds.
Claim 3
Dependent Claim
37 words
The process of claim 1, wherein forming of the plurality of beds includes selecting the absorbent/catalyst material from the group consisting of vanadia, titania, alumina, silica, and silica base containing a transition metal oxide or noble metal.
Claim 4
Dependent Claim
23 words
The process of claim 1, wherein the absorbent/catalyst material is granular having a bead size in the range of 5 to 10 mm.
Claim 5
Dependent Claim
23 words
The process of claim 1, wherein the pulsed plasma heats the bed to a temperature in the range of 300° to 900° C.
Claim 6
Dependent Claim
28 words
The process of claim 1, wherein the air is supplied at a pressure of 0.1 to 0.5 bar and at a flow rate of 10 to 100 liter/second.
Claim 7
Dependent Claim
41 words
The process of claim 1, wherein providing means for producing a pulsed plasma in the beds is carried out by providing spaced electrodes adjacent the absorbent/catalyst material and providing a controlled power supply for producing an electrical discharge between the electrodes.
Claim 8
Dependent Claim
43 words
The process of claim 1, wherein the valve mechanism is formed to comprise a valve assembly having a plurality of positions and an exhaust, each position being adapted to connect the exhaust of the valve assembly with one of the plurality of beds.
Claim 9
Dependent Claim
34 words
The process of claim 1, wherein activating the valve mechanism, activating and controlling the pulsed plasma, and activating and controlling the air supplying means is carried out by a system including a switching logic.
Claim 10
Dependent Claim
36 words
The process of claim 8, wherein the switching logic is provided with signals representing at least one of the group consisting of temperature of the beds, on-stream time, NO x concentration, and particulates in the bed.
Claim 11
Dependent Claim
59 words
A process for the reduction of NO x and particulates from exhaust of a diesel or lean-burn gasoline engine, comprising: absorbing NO x onto a solid absorbent bed; simultaneously trapping particulate matter in the bed; regenerating the solid absorbent bed by pulsed plasma decomposition of absorbed NO x ; and burn-off of remaining trapped particulate matter by air oxidation.
Claim 12
Dependent Claim
59 words
A process for the reduction of NO x and particulates from exhaust of a diesel or lean-burn gasoline engine, comprising: absorbing NO x onto a solid absorbent bed; simultaneously trapping particulate matter in the bed; regenerating the solid absorbent bed by pulsed plasma decomposition of absorbed NO x ; and burn-off of remaining trapped particulate matter by air oxidation.
Claim 13
Dependent Claim
27 words
The process of claim 10, additionally including forming the solid absorbent bed from absorbent/catalyst material selected from the group consisting of iron oxide, ilmenite, perovskite, and calcite.
Claim 14
Dependent Claim
24 words
The process of claim 10, additionally including providing the bed with spaced electrodes for producing the pulsed plasma by electrical discharge between the electrodes.
Claim 15
Dependent Claim
31 words
The process of claim 10, wherein the air oxidation of the particulate matter is carried out by supplying air to the bed following heating of the bed by the pulsed plasma.
Claim 16
Independent Claim
145 words
An apparatus for reducing NO x and particulates in an engine exhaust, comprising: a plurality of solid absorbent/catalyst material beds, each bed having an inlet and an outlet; a valve assembly connected to said bed outlets and to an exhaust; said bed inlets being adapted to being connected to an engine exhaust system; a plurality of electrodes located in each of said beds; means for supplying electrical power to said electrodes for producing an electrical discharge therebetween; means for supplying air to said valve assembly,; and means for controlling said power supplying means; said air supplying means, and said valve assembly; whereby engine exhaust through said plurality of beds is controlled by said valve assembly, such that at least one of said plurality of beds is absorbing NO x and trapping particulate matter, while at least another of said plurality of beds is being regenerated.
Claim 17
Independent Claim
145 words
An apparatus for reducing NO x and particulates in an engine exhaust, comprising: a plurality of solid absorbent/catalyst material beds, each bed having an inlet and an outlet; a valve assembly connected to said bed outlets and to an exhaust; said bed inlets being adapted to being connected to an engine exhaust system; a plurality of electrodes located in each of said beds; means for supplying electrical power to said electrodes for producing an electrical discharge therebetween; means for supplying air to said valve assembly,; and means for controlling said power supplying means; said air supplying means, and said valve assembly; whereby engine exhaust through said plurality of beds is controlled by said valve assembly, such that at least one of said plurality of beds is absorbing NO x and trapping particulate matter, while at least another of said plurality of beds is being regenerated.
Claim 18
Dependent Claim
43 words
The apparatus of claim 14, wherein the absorbent/catalyst material beds are composed of an absorbent selected from the group consisting of oxides of iron, cobalt, nickel, copper and zink and a catalyst selected from the group consisting of vanadia, titania, alumina and silica.
Claim 19
Dependent Claim
32 words
The apparatus of claim 14, wherein said means for supplying electrical power to said electrodes includes a power supply capable of heating a bed to a temperature of 300° to 900° C.
Claim 20
Dependent Claim
64 words
The apparatus of claim 14, wherein said valve assembly is composed of a multi-position valve, one position of said valve being connected to one of said plurality of beds, whereby activation of said valve may connect one of said plurality of beds with the exhaust of said valve and block connection of another of said plurality of beds from the exhaust of said valve.
Claim 21
Dependent Claim
17 words
The apparatus of claim 14, wherein said means for controlling includes a system having a switching logic.
Claim 22
Dependent Claim
54 words
The apparatus of claim 14, whereby said plurality of beds consist of two beds, and wherein said valve assembly comprises a three-way valve, whereby activation of said three-way valve positions one of said two beds in an on-line mode to receive engine exhaust, and positions the other said two beds in a regeneration mode.
References Cited (Backward Citations)
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 2001-02-09 | 2001-08-11 | 2002-02-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2005-02-09 | 2005-08-11 | 2006-02-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2009-02-09 | 2009-08-11 | 2010-02-10 | $7700.00 | Window Closed / Lapsed |