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US5713992A Expired / Lapsed US ⏱️ 0.0 years remaining

Recording liquid

Assignee: Mitsubishi Chemical Corp
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Filing: 1995-03-02
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Granted: 1998-02-03
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Expires: 2015-03-02
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Abstract

Abstract PCT No. PCT/JP95/00336 Sec. 371 Date Jan. 13, 1997 Sec. 102(e) Date Jan. 13, 1997 PCT Filed Mar. 2, 1995 PCT Pub. No. WO96/26985 PCT Pub. Date Sep. 6, 1996The present invention relates to a recording liquid characterized by comprising an aqueous medium and at least one monoazo dye selected from dyes, the free acid forms of which are represented by general formula {I}: <IMAGE> {I} (wherein R1, R2, and R3 each independently represents a substituted or unsubstituted alkyl group having 1 to 9 carbon atoms, an alkoxy group having 1 to 9 carbon atoms, a halogen atom, a hydrogen atom, a hydroxyl group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted sulfamoyl group, a substituted or unsubstituted amino group, a nitro group, a sulfonic ester group, a sulfonyl group, a COOH group, or a carboxylic ester group; m represents a number of 0, 1, or 2; and R4, R5, R6, and R7 each independently represents a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 1 to 18 carbon atoms, an aryl group, an aralkyl group, an alicyclic group, or a heterocyclic group, and each may have a substituent when not representing a hydrogen atom, provided that at least one of R4, R5, R6, and R7 represents a group having a COOH group as a substituent).

Inventors

  • 👤 Nobuyoshi Satoh
  • 👤 Takashi Hirasa
  • 👤 Yukichi Murata

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 08:34
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/32; C09B; C09B29/00; C09B29/24; C09B29/28; C09B29/30; C09B43/00; C09B43/12; C09B43/136; C09B43/16; C09D11/16; C09D11/17; C09D11/328

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 213 words
An ink-jet recording liquid comprising an aqueous medium and at least one dye selected from the group consisting of dyes, the free acid forms of which are represented by general formula {I}: ##STR6## wherein R 1 , R 2 , and R 3 each independently represents a substituted or unsubstituted alkyl group having 1 to 9 carbon atoms, a halogen atom, a hydrogen atom, a hydroxyl group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted sulfamoyl group, a substituted or unsubstituted amino group, a nitro group, a sulfonic ester group, a sulfonyl group, a COOH group, or a carboxylic ester group; m represents a number of 0, 1, or 2; and R 4 , R 5 , R 6 , and R 7 each independently represents a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 1 to 18 carbon atoms, an aryl group, an aralkyl group, an alicyclic group, or a heterocyclic group, and each may have a substituent when not representing a hydrogen atom, provided that at least one of R 4 , R 5 , R 6 , and R 7 represents a group having a COOH group as a substituent; wherein the at least one dye is suitable for ink-let recording.
Claim 2
Dependent Claim 213 words
An ink-jet recording liquid comprising an aqueous medium and at least one dye selected from the group consisting of dyes, the free acid forms of which are represented by general formula {I}: ##STR6## wherein R 1 , R 2 , and R 3 each independently represents a substituted or unsubstituted alkyl group having 1 to 9 carbon atoms, a halogen atom, a hydrogen atom, a hydroxyl group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted sulfamoyl group, a substituted or unsubstituted amino group, a nitro group, a sulfonic ester group, a sulfonyl group, a COOH group, or a carboxylic ester group; m represents a number of 0, 1, or 2; and R 4 , R 5 , R 6 , and R 7 each independently represents a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 1 to 18 carbon atoms, an aryl group, an aralkyl group, an alicyclic group, or a heterocyclic group, and each may have a substituent when not representing a hydrogen atom, provided that at least one of R 4 , R 5 , R 6 , and R 7 represents a group having a COOH group as a substituent; wherein the at least one dye is suitable for ink-let recording.
Claim 3
Dependent Claim 55 words
An ink jet recording liquid as claimed in claim 1, wherein in general formula {I}, a group represented by general formula {II}: ##STR7## (wherein R 4 , R 5 , R 6 , and R 7 each has the same meaning as in general formula {I}) is bonded to the 8-position of the 1-naphthol ring.
Claim 4
Dependent Claim 35 words
An ink jet recording liquid as claimed in claim 1, wherein in general formula {I}, at least one of R 4 , R 5 , R 6 , and R 7 is a hydrogen atom.
Claim 5
Dependent Claim 33 words
An ink jet recording liquid as claimed in claim 1, wherein in general formula {I}, either of R 4 and R 5 and either of R 6 and R 7 are hydrogen atoms.
Claim 6
Dependent Claim 30 words
An ink jet recording liquid as claimed in claim 1, wherein in general formula {I}, either R 4 and R 5 or R 6 and R 7 are hydrogen atoms.
Claim 7
Dependent Claim 18 words
An ink jet recording liquid as claimed in claim 1, wherein in general formula {I}, m is 0.
Claim 8
Dependent Claim 18 words
An ink jet recording liquid as claimed in claim 1, wherein in general formula {I}, m is 1.
Claim 9
Dependent Claim 32 words
An ink jet recording liquid as claimed in claim 1, wherein in general formula {I}, at least one of R 1 , R 2 , and R 3 is a hydrogen atom.
Claim 10
Dependent Claim 32 words
An ink jet recording liquid as claimed in claim 1, wherein in general formula {I}, any one or two of R 1 , R 2 , and R 3 are COOH groups.
Claim 11
Dependent Claim 71 words
An ink jet recording liquid as claimed in claim 1, wherein in general formula {I}, at least one of R 4 , R 5 , R 6 and R 7 is an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 1 to 18 carbon atoms, an aryl group, an aralkyl group, or a cyclohexyl group, each of which is substituted with from 1 to 4 COOH groups.
Claim 12
Dependent Claim 39 words
An ink jet recording liquid as claimed in claim 1, wherein in general formula {I}, either of R 4 and R 5 and either of R 6 and R 7 are groups having a COOH group as a substituent.
Claim 13
Dependent Claim 42 words
An ink jet recording liquid as claimed in claim 1, wherein in general formula {I}, at least one of R 4 , R 5 , R 6 , and R 7 is a phenyl group having a COOH group as a substituent.
Claim 14
Dependent Claim 78 words
An ink-jet recording liquid comprising an aqueous medium and at least one dye selected from the group consisting of dyes, the free acid forms of which are represented by general formula {III}: ##STR8## wherein R 8 represents a hydrogen atom, an alkyl group having 1 to 9 carbon atoms and optionally substituted with a hydroxy group or a COOH group, a cycloalkyl group, or an aralkyl group; wherein the at least one dye is suitable for ink-jet recording.
Claim 15
Dependent Claim 78 words
An ink-jet recording liquid comprising an aqueous medium and at least one dye selected from the group consisting of dyes, the free acid forms of which are represented by general formula {III}: ##STR8## wherein R 8 represents a hydrogen atom, an alkyl group having 1 to 9 carbon atoms and optionally substituted with a hydroxy group or a COOH group, a cycloalkyl group, or an aralkyl group; wherein the at least one dye is suitable for ink-jet recording.
Claim 16
Dependent Claim 40 words
An ink jet recording liquid as claimed in claim 1 or 13, wherein the content of the dye of general formula {I} or {III} is from 0.5 to 5% by weight based on the total amount of the recording liquid.
Claim 17
Dependent Claim 75 words
An ink-jet recording liquid as claimed in claim 1 or 13, wherein said aqueous medium comprises water and at least one water-soluble organic solvent selected from the group consisting of ethylene glycol, propylene glycol, butylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol having a molecular weight of 190 to 400, glycerol, N-methylpyrrolidone, N-ethylpyrrolidone, 1,3-dimethylimidazolidinone, thiodiethanol, dimethyl sulfoxide, ethylene glycol monoallyl ether, ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, 2-pyrrolidone, sulfolane, ethyl alcohol, and isopropanol.
Claim 18
Dependent Claim 34 words
An ink jet recording liquid as claimed in claim 15, wherein the content of said water-soluble organic solvent is from 1 to 50% by weight based on the total amount of said recording liquid.
Claim 19
Dependent Claim 42 words
An ink-jet recording liquid as claimed in claim 1, wherein in general formula {I}, m=0 and at least one of R 4 , R 5 , R 6 and R 7 is a phenyl group having a COOH group as a substituent.

References Cited (Backward Citations)

DE2814802A1 Cited
US4631085A Cited
EP0239847A1 Cited
JPH04279671A Cited
WO1994016021A1 Cited

USPTO Annuity & Maintenance Windows

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