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US5693444A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrostatic-image developer and image forming process

Assignee: Fujifilm Business Innovation Corp
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Filing: 1996-12-12
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Granted: 1997-12-02
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Expires: 2016-12-12
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Abstract

Abstract An electrostatic-image developer which comprises a toner and a carrier comprising core particles coated with a coating resin, wherein the toner comprises toner particles having a volume-average particle diameter of from 3 to 9 μm and having a specific particle diameter distribution, at least 20% of the total surface area of the toner particles is covered with (a) an external additive having an average particle diameter of from 20 nm to 100 nm, and at least 40% of the total surface area of the toner particles is covered with (b) an external additive having an average particle diameter of from 7 nm to 20 nm, and wherein the core particles of the carrier are magnetic particles formed from a composition comprising 100 parts by weight of a ferrite component represented by the following formula (3): (M.sub.y O).sub.100-x (Fe.sub.2 O.sub.3).sub.x (3) (wherein M is a metal atom selected from the group consisting of Li, Mg, Ca and Mn; x is from 45 to 95 mol %; and y is 1 or 2) and from 0.01 to 10 parts by weight of an oxide of at least one element selected from the group consisting of Groups IA, IIA, IIIA, IVA, VA, IIIB, IVB, and VB of the periodic table by granulating the composition and sintering the granules, and the magnetic particles have a silicon content of from 500 to 5,000 ppm. An image forming process using the developer is also disclosed.

Inventors

  • 👤 Masahiro Takagi
  • 👤 Akihiro Iizuka
  • 👤 Satoru Ishigaki
  • 👤 Masanori Ichimura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 17:28
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/0819; G03G9/097; G03G9/10; G03G9/107; G03G9/1075; G03G9/108; G03G9/1085

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 356 words
An electrostatic-image developer which comprises a toner and a carrier comprising core particles coated with a coating resin, wherein the toner comprises toner particles having a volume-average particle diameter of from 3 to 9 μm and having a particle diameter distribution satisfying the following expressions (1) and (2): D16v/D50v≦1.475-0.036·D50v (1) D50p/D84p≦1.45 (2) (wherein D16v and D50v represent, in terms of absolute value, a cumulative 16% diameter (μm) and a cumulative 50% diameter (μm), respectively, of a cumulative volume particle diameter distribution of the toner particles depicted from the maximum particle diameter and D50p and D84p represent, in terms of absolute value, a cumulative 50% diameter (μm) and a cumulative 84% diameter (μm), respectively, of a cumulative population particle diameter distribution of the toner particles depicted from the maximum particle diameter), and at least 20% of the total surface area of the toner particles is covered with (a) an external additive having an average particle diameter of from 20 nm to 100 nm, excluding 100 nm, and at least 40% of the total surface area of the toner particles is covered with (b) an external additive having an average particle diameter of from 7 nm to 20 nm, excluding 20 nm, the total percentage of the coverage with the two external additives is from 60% to 120%, excluding 120%, based on the total surface area of the toner particles, and wherein the core particles of the carrier are magnetic particles formed from a composition comprising 100 parts by weight of a ferrite component represented by the following formula (3): (M.sub.y O).sub.100-x (Fe.sub.2 O.sub.3).sub.x ( 3) (wherein M represents at least one metal atom selected from the group consisting of Li, Mg, Ca and Mn; x represents a mole percentage of 45 to 95%; and y represents 1 or 2) and from 0.01 to 10 parts by weight of an oxide of at least one element selected from the group consisting of Groups IA, IIA, IIIA, IVA, VA, IIIB, IVB, and VB of the periodic table by granulating the composition and sintering the granules, and the magnetic particles have a silicon content of from 500 to 5,000 ppm.
Claim 2
Dependent Claim 356 words
An electrostatic-image developer which comprises a toner and a carrier comprising core particles coated with a coating resin, wherein the toner comprises toner particles having a volume-average particle diameter of from 3 to 9 μm and having a particle diameter distribution satisfying the following expressions (1) and (2): D16v/D50v≦1.475-0.036·D50v (1) D50p/D84p≦1.45 (2) (wherein D16v and D50v represent, in terms of absolute value, a cumulative 16% diameter (μm) and a cumulative 50% diameter (μm), respectively, of a cumulative volume particle diameter distribution of the toner particles depicted from the maximum particle diameter and D50p and D84p represent, in terms of absolute value, a cumulative 50% diameter (μm) and a cumulative 84% diameter (μm), respectively, of a cumulative population particle diameter distribution of the toner particles depicted from the maximum particle diameter), and at least 20% of the total surface area of the toner particles is covered with (a) an external additive having an average particle diameter of from 20 nm to 100 nm, excluding 100 nm, and at least 40% of the total surface area of the toner particles is covered with (b) an external additive having an average particle diameter of from 7 nm to 20 nm, excluding 20 nm, the total percentage of the coverage with the two external additives is from 60% to 120%, excluding 120%, based on the total surface area of the toner particles, and wherein the core particles of the carrier are magnetic particles formed from a composition comprising 100 parts by weight of a ferrite component represented by the following formula (3): (M.sub.y O).sub.100-x (Fe.sub.2 O.sub.3).sub.x ( 3) (wherein M represents at least one metal atom selected from the group consisting of Li, Mg, Ca and Mn; x represents a mole percentage of 45 to 95%; and y represents 1 or 2) and from 0.01 to 10 parts by weight of an oxide of at least one element selected from the group consisting of Groups IA, IIA, IIIA, IVA, VA, IIIB, IVB, and VB of the periodic table by granulating the composition and sintering the granules, and the magnetic particles have a silicon content of from 500 to 5,000 ppm.
Claim 3
Dependent Claim 44 words
The electrostatic-image developer according to claim 1, wherein the oxide is a metal oxide selected from the group consisting of Li 2 O, BaO, SrO, Al 2 O 3 , TiO 2 , SiO 2 , SnO 2 and Bi 2 O 5 .
Claim 4
Dependent Claim 37 words
The electrostatic-image developer according to claim 1, wherein the oxide is a metal oxide selected from the group consisting of Li 2 O, SrO, Al 2 O 3 , SiO 2 and Bi 2 O 5 .
Claim 5
Dependent Claim 20 words
The electrostatic-image developer according to claim 1, wherein the magnetic particle has a silicon content of 1000 to 3000 ppm.
Claim 6
Dependent Claim 32 words
The electrostatic-image developer according to claim 1, wherein the carrier is coated with the coating resin in an amount of 0.1 to 5% by weight based on the weight of the carrier.
Claim 7
Dependent Claim 32 words
The electrostatic-image developer according to claim 1, wherein the carrier is coated with the coating resin in an amount of 0.3 to 3% by weight based on the weight of the carrier.
Claim 8
Dependent Claim 54 words
The electrostatic-image developer according to claim 1, wherein the coating resin is a homopolymer or a copolymer comprising a monomer selected from the group consisting of a fluorinated vinyl monomer, styrene, a derivative of styrene, an aliphatic α-methylene monocarboxylic acid and an alkyl ester of an aliphatic α-methylene monocarboxylic acid, or a silicone resin.
Claim 9
Dependent Claim 14 words
The electrostatic-image developer according to claim 1, wherein the developer comprises a color toner.
Claim 10
Dependent Claim 16 words
The electrostatic-image developer according to claim 1, wherein the toner comprises a binder resin comprising polyester.
Claim 11
Dependent Claim 46 words
An image forming method comprising: forming a latent image on a latent-image holding member; developing the latent image using a developer to form a toner image; and transferring the toner image to a transferring member, wherein the developer is the developer as claimed in claim 1.
Claim 12
Dependent Claim 45 words
The image forming method according to claim 10, wherein the oxide is a metal oxide selected from the group consisting of Li 2 O, BaO, SrO, Al 2 O 3 , TiO 2 , SiO 2 , SnO 2 and Bi 2 O 5 .
Claim 13
Dependent Claim 38 words
The image forming method according to claim 10, wherein the oxide is a metal oxide selected from the group consisting of Li 2 O SrO, Al 2 O 3 , SiO 2 and Bi 2 O 5 .
Claim 14
Dependent Claim 21 words
The image forming method according to claim 10, wherein the magnetic particle has a silicon content of 1000 to 3000 ppm.
Claim 15
Dependent Claim 33 words
The image forming method according to claim 10, wherein the carrier is coated with the coating resin in an amount of 0.1 to 5% by weight based on the weight of the carrier.
Claim 16
Dependent Claim 33 words
The image forming method according to claim 10, wherein the carrier is coated with the coating resin in an amount of 0.3 to 3% by weight based on the weight of the carrier.
Claim 17
Dependent Claim 55 words
The image forming method according to claim 10, wherein the coating resin is a homopolymer or a copolymer comprising a monomer selected from the group consisting of a fluorinated vinyl monomer, styrene, a derivative of styrene, an aliphatic α-methylene monocarboxylic acid and an alkyl ester of an aliphatic s-methylene monocarboxylic acid, or a silicone resin.
Claim 18
Dependent Claim 15 words
The image forming method according to claim 10, wherein the developer comprises a color toner.
Claim 19
Dependent Claim 17 words
The image forming method according to claim 10, wherein the toner comprises a binder resin comprising polyester.

References Cited (Backward Citations)

US4485162A Cited
JPS58215664A Cited
US5164774A Cited
JPH01163758A Cited
US5120631A Cited
US5296324A Cited
US5342721A Cited
JPH06110253A Cited
JPH07225497A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2000-12-01 2001-06-02 2001-12-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-12-01 2005-06-02 2005-12-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2008-12-01 2009-06-02 2009-12-02 $7700.00 Window Closed / Lapsed

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