US5683828A
Expired / Lapsed
US
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Metal platelet fuel cells production and operation methods
Assignee: H Power Corp
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Filing: 1995-10-31
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Granted: 1997-11-04
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Expires: 2015-10-31
Abstract
Abstract Fuel cell stacks comprising stacked separator/membrane electrode assembly cells in which the separators comprise a series of stacked thin sheet platelets having individually configured serpentine micro-channel reactant gas humidification, active area and cooling fields therein. The individual platelets are stacked with coordinate features precisely aligned in contact with adjacent platelets and bonded to form a monolithic separator. Post bonding processing includes passivation, such as nitriding. Preferred platelet material is 4-25 mil Ti in which the features, serpentine channels, tabs, lands, vias, manifolds and holes, are formed by chemical or laser etching, cutting, pressing or embossing, with combinations of depth and through-etching being preferred. The platelet manufacturing process is continuous and fast. By employing CAD based platelet design and photolithography, rapid change in feature design to accommodate a wide range of thermal management and humidification techniques. 100 cell H 2 -O 2 /Air PEM fuel cell stacks of this IFMT platelet design will exhibit outputs on the order of 0.75 kW/kg, some 3-6 times greater than current graphite plate PEM stacks.
Inventors
- 👤 Reginald G. Spear
- 👤 H. Harry Mueggenburg
- 👤 Rex Hodge
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 04:33
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/02; H01M8/0202; H01M8/0204; H01M8/0223; H01M8/0228; F; F28; F28D; F28D9/00; F28D9/0062; F28D9/0075; F28F; F28F3/00; F28F3/02; F28F3/04; H01M8/0206; H01M8/023; H01M8/0241; H01M8/0245; H01M8/0247; H01M8/0258; H01M8/026; H01M8/0263; H01M8/0267; H01M8/24; H01M8/2465; H01M8/2483; F28F2250/00; F28F2250/10; F28F2250/102; F28F2260/00; F28F2260/02; H01M2300/00; H01M2300/0017; H01M2300/0065; H01M2300/0082; H01M8/0208; H01M8/021; H01M8/04; H01M8/04007; H01M8/04029; H01M8/04067; H01M8/04074; H01M8/04082; H01M8/04089; H01M8/04119; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50; Y02P; Y02P70/00; Y02P70/50; Y02P80/00; Y02P80/10; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49108; Y10T29/49115
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
103 words
A method for producing fuel cell separator assemblies comprising the steps of: a) forming in thin sheet stock a plurality of different individual platelets with coordinate features selected from micro-channels, vias and manifolds, said features together forming at least one active area field for oxidant or fuel consumption in contact with a membrane electrode assembly; b) stacking said platelets with said individual platelet features in precise alignment with corresponding features of a matingly adjacent platelet to provide continuous circulation paths for said oxidant or fuel; and c) bonding said aligned platelets to form a monolithic separator having internal microchannels and access manifolds thereto.
Claim 2
Independent Claim
103 words
A method for producing fuel cell separator assemblies comprising the steps of: a) forming in thin sheet stock a plurality of different individual platelets with coordinate features selected from micro-channels, vias and manifolds, said features together forming at least one active area field for oxidant or fuel consumption in contact with a membrane electrode assembly; b) stacking said platelets with said individual platelet features in precise alignment with corresponding features of a matingly adjacent platelet to provide continuous circulation paths for said oxidant or fuel; and c) bonding said aligned platelets to form a monolithic separator having internal microchannels and access manifolds thereto.
Claim 3
Dependent Claim
33 words
A method as in claim 1 wherein said sheet stock is metal and said forming step includes the step of etch forming said features by a combination of depth etching and through etching.
Claim 4
Dependent Claim
31 words
A method as in claim 2 wherein said through etching comprises depth etching selected areas from both sides of said sheet stock to depths greater than 50% of the sheet thickness.
Claim 5
Dependent Claim
26 words
A method as in claim 3 wherein said metal is selected from Ti, Al, Cu, W, Niobium, stainless steel, and alloys, laminates, platings and composites thereof.
Claim 6
Dependent Claim
21 words
A method as in claim 2 wherein said forming step includes resist coating said sheet metal platelets to define features thereon.
Claim 7
Dependent Claim
16 words
A method as in claim 2 which includes the step of passivating said separator after bonding.
Claim 8
Dependent Claim
31 words
A method as in claim 6 wherein said bonding includes diffusion bonding under heat and pressure, said metal is Ti, and said passivating includes exposure to Nitrogen at an elevated temperature.
Claim 9
Dependent Claim
22 words
A method as in claim 5 wherein said resist coating is applied by at least one of direct transfer or photolithographic processing.
Claim 10
Independent Claim
94 words
A method of designing fuel cell separator assemblies comprising the steps of: a) developing a plurality of individual platelet drawings as plan views of platelet faces having features selected from at least one of metering orifices, channels, vias and manifolds to provide integrated fluid management of fuel, oxidant, humidification and temperature; and b) generating photo-tooling masks artwork for said platelets faces from said platelet drawings so that said features are coordinated from platelet to platelet to form a functional separator upon properly aligned stacking of said platelets in proper sequence and bonding them together.
Claim 11
Independent Claim
94 words
A method of designing fuel cell separator assemblies comprising the steps of: a) developing a plurality of individual platelet drawings as plan views of platelet faces having features selected from at least one of metering orifices, channels, vias and manifolds to provide integrated fluid management of fuel, oxidant, humidification and temperature; and b) generating photo-tooling masks artwork for said platelets faces from said platelet drawings so that said features are coordinated from platelet to platelet to form a functional separator upon properly aligned stacking of said platelets in proper sequence and bonding them together.
Claim 12
Dependent Claim
44 words
A method of fuel cell separator design as in claim 9 which includes the added step of: a) applying an etch factor to compensate for undercutting to at least one selected feature on selected ones of said platelet drawings in generating said photo-tooling masks.
Claim 13
Dependent Claim
33 words
A method of fuel cell separator design as in claim 10 which includes the added step of: a) generating an inspection database of critical dimensions for verification during mask creation and platelet manufacturing.
Claim 14
Dependent Claim
45 words
A method of fuel cell separator design as in claim 10 wherein: a) said etch factor includes a value for at least one of the type of metal, type of chemical milling equipment, etch speed, type of etchant, strength of etchant or temperature of etchant.
Claim 15
Dependent Claim
24 words
A method of fuel cell separator design as in claim 9 which includes the added step of: a) photoplotting platelet mask artwork on film.
Claim 16
Dependent Claim
26 words
A method of fuel cell separator design as in claim 13 wherein: a) said plotting is at 1:1 with respect to the size of the platelet.
Claim 17
Dependent Claim
45 words
A method of fuel cell separator design as in claim 10 wherein: a) said etch factor includes a value for at least one of the type of metal, type of chemical milling equipment, etch speed, type of etchant, strength of etchant or temperature of etchant.
Claim 18
Dependent Claim
24 words
A method of fuel cell separator design as in claim 15 which includes the added step of: a) photoplotting platelet mask artwork on film.
Claim 19
Dependent Claim
91 words
Method of integrated fluid management (IFM) operation of a fuel cell comprising: a) providing a fuel cell stack comprising plurality of aligned fuel cell separators as in claim 1 having disposed between each separator an electrode membrane assembly having at least one catalytically active zone where fuel and oxidant electrochemical reaction occur; b) providing fuel and oxidant to said stack; c) controlling the flow of fuel, oxidant and the removal of heat at rates integrated to substantially eliminate thermal hot spots while maintaining a substantially uniform preselected temperature throughout said stack.
Claim 20
Dependent Claim
28 words
An IFM fuel cell operation method as in claim 17 wherein: a) said step of removal of the heat includes introduction of a coolant for cooling said stack.
Claim 21
Dependent Claim
16 words
An IFM fuel cell operation method as in claim 18 wherein: a) said coolant includes water.
Claim 22
Dependent Claim
31 words
An IFM fuel cell operation method as in claim 19 wherein: a) at least some of said water is routed to humidify at least one of said fuel or said oxidant.
Claim 23
Dependent Claim
128 words
An IFM fuel cell operation method as in claim 20 wherein: a) at least some of said water is routed through microchannels in a first water zone of said stack on a first side of a water vapor permeable membrane, and at least one of said fuel or said oxidant is routed through microchannels in at least one humidification zone of said stack on the opposite side of said membrane corresponding to said first water zone; b) osmotically pumping water vapor through said membranes to humidify at least one of said fuel or said oxidant in said humidification zone; and c) controlling the humidity of said fuel or said oxidant to assist in maintaining the integrity of said electrode membrane assembly in the catalytically active electrochemical reaction zone.
Claim 24
Dependent Claim
39 words
An IFM fuel cell operation method as in claim 21 wherein: a) at least some of said water is routed adjacent said catalytically active electrochemical reaction zone to control the temperature thereof before being muted to said humidification zone.
Claim 25
Dependent Claim
51 words
An IFM fuel cell operation method as in claim 22 wherein: a) said water muted adjacent said catalytically active zone withdraws heat during electrochemical activity of said cell and exits therefrom at a temperature elevated above its inlet temperature; and b) said elevated temperature water is muted to said humidification zone.
Claim 26
Dependent Claim
31 words
An IFM fuel cell operation method as in claim 23 wherein both said fuel and said oxidant are humidified by water of elevated temperature exiting from adjacent said catalytically active zone.
Claim 27
Dependent Claim
18 words
An IFM fuel cell operation method as in claim 24 wherein: a) said fuel and oxidant are gases.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2000-11-03 | 2001-05-05 | 2001-11-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2004-11-03 | 2005-05-05 | 2005-11-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2008-11-03 | 2009-05-05 | 2009-11-04 | $7700.00 | Window Closed / Lapsed |