US5670019A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Removal process for tungsten etchback precipitates
Assignee: Taiwan Semiconductor Manufacturing Co TSMC Ltd
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Filing: 1996-02-26
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Granted: 1997-09-23
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Expires: 2016-02-26
Abstract
Abstract This invention provides a method of cleaning integrated circuit wafers which effectively removes precipitates formed as a result of the tungsten etchback process. When tungsten is used to fill via holes in an inter-metal dielectric layer an adhesion layer of titanium nitride, TiN, is required to provide good adhesion. As a result of the tungsten etchback, wherein fluorine based etchants are used, precipitates of TiF 3 can form which are extremely difficult to remove. Methods, such as in-situ bake after the tungsten etchback, are used to prevent the formation of the precipitates but do not remove them after they are formed. This invention teaches a method using a strong oxidizing agent, such as H 2 O 2 , to cause an oxidation-reduction reaction which converts the precipitates to a water soluble form. The water soluble form of the precipitates are then removed using a water rinse and spin dry process.
Inventors
- 👤 Yuan-Chang Huang
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 03:07
CPC Classifications
H; H10; H10P; H10P70/00; H10P70/20; H10P70/27; H10P70/273
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
201 words
A method of cleaning integrated circuit wafers, comprising the steps of: providing an integrated circuit wafer having devices formed therein and an inter-metal dielectric formed thereon; providing via holes formed in said inter metal dielectric wherein each said via hole has sidewalls and a bottom; forming a titanium nitride adhesion layer over said inter-metal dielectric layer, said sidewalls of each said via hole, and said bottom of each said via hole; forming a conduction metal layer over said titanium nitride adhesion layer thereby filling said via holes with said conduction metal; etching away that part of said conduction metal layer not filling said via holes and that part of said titanium nitride adhesion layer not on said sidewalls and bottom of each said via hole using dry etching with a fluorine based etchant; immersing said integrated circuit wafer in an oxidizing agent having a first temperature for a first time, after said metal etchback process has been completed; immersing said integrated circuit wafer in water having a second temperature for a second time after immersing said integrated circuit wafer in said oxidizing agent has been completed; and drying said wafer after said immersing said wafer in said water has been completed.
Claim 2
Independent Claim
201 words
A method of cleaning integrated circuit wafers, comprising the steps of: providing an integrated circuit wafer having devices formed therein and an inter-metal dielectric formed thereon; providing via holes formed in said inter metal dielectric wherein each said via hole has sidewalls and a bottom; forming a titanium nitride adhesion layer over said inter-metal dielectric layer, said sidewalls of each said via hole, and said bottom of each said via hole; forming a conduction metal layer over said titanium nitride adhesion layer thereby filling said via holes with said conduction metal; etching away that part of said conduction metal layer not filling said via holes and that part of said titanium nitride adhesion layer not on said sidewalls and bottom of each said via hole using dry etching with a fluorine based etchant; immersing said integrated circuit wafer in an oxidizing agent having a first temperature for a first time, after said metal etchback process has been completed; immersing said integrated circuit wafer in water having a second temperature for a second time after immersing said integrated circuit wafer in said oxidizing agent has been completed; and drying said wafer after said immersing said wafer in said water has been completed.
Claim 3
Dependent Claim
13 words
The method of claim 1 wherein said fluorine based etchant comprises sulfur hexafluoride.
Claim 4
Dependent Claim
14 words
The method of claim 1 wherein said fluorine based etchant comprises NF 3 .
Claim 5
Dependent Claim
11 words
The method of claim 1 wherein said conduction metal is tungsten.
Claim 6
Dependent Claim
17 words
The method of claim 1 wherein said oxidizing agent is a solution of hydrogen peroxide and water.
Claim 7
Dependent Claim
26 words
The method of claim 5 wherein the volume of said hydrogen peroxide in said solution of hydrogen peroxide and water is between about 25% and 37%.
Claim 8
Dependent Claim
16 words
The method of claim 1 wherein said first time is between about 48 and 72 seconds.
Claim 9
Dependent Claim
17 words
The method of claim 1 wherein said first temperature is between about 25° C. and 70° C.
Claim 10
Dependent Claim
16 words
The method of claim 1 wherein said second time is between about 300 and 400 seconds.
Claim 11
Dependent Claim
17 words
The method of claim 1 wherein said second temperature is between about 25° C. and 70° C.
Claim 12
Independent Claim
198 words
A method of cleaning integrated circuit wafers, comprising the steps of: providing an integrated circuit wafer having devices formed therein and an inter-metal dielectric formed thereon; providing via holes formed in said inter metal dielectric wherein each said via hole has sidewalls and a bottom; forming a titanium adhesion layer over said inter-metal dielectric layer, said sidewalls of each said via hole, and said bottom of each said via hole; forming a conduction metal layer over said titanium adhesion layer thereby filling said via holes with said conduction metal; etching away that part of said conduction metal layer not filling said via holes and that part of said titanium adhesion layer not on said sidewalls and bottom of each said via hole using dry etching with a fluorine based etchant; immersing said integrated circuit wafer in an oxidizing agent having a first temperature for a first time, after said metal etchback process has been completed; immersing said integrated circuit wafer in water having a second temperature for a second time after immersing said integrated circuit wafer in said oxidizing agent has been completed; and drying said wafer after said immersing said wafer in said water has been completed.
Claim 13
Independent Claim
198 words
A method of cleaning integrated circuit wafers, comprising the steps of: providing an integrated circuit wafer having devices formed therein and an inter-metal dielectric formed thereon; providing via holes formed in said inter metal dielectric wherein each said via hole has sidewalls and a bottom; forming a titanium adhesion layer over said inter-metal dielectric layer, said sidewalls of each said via hole, and said bottom of each said via hole; forming a conduction metal layer over said titanium adhesion layer thereby filling said via holes with said conduction metal; etching away that part of said conduction metal layer not filling said via holes and that part of said titanium adhesion layer not on said sidewalls and bottom of each said via hole using dry etching with a fluorine based etchant; immersing said integrated circuit wafer in an oxidizing agent having a first temperature for a first time, after said metal etchback process has been completed; immersing said integrated circuit wafer in water having a second temperature for a second time after immersing said integrated circuit wafer in said oxidizing agent has been completed; and drying said wafer after said immersing said wafer in said water has been completed.
Claim 14
Dependent Claim
13 words
The method of claim 11 wherein said fluorine based etchant comprises sulfur hexafluoride.
Claim 15
Dependent Claim
14 words
The method of claim 11 wherein said fluorine based etchant comprises NF 3 .
Claim 16
Dependent Claim
11 words
The method of claim 11 wherein said conduction metal is tungsten.
Claim 17
Dependent Claim
17 words
The method of claim 11 wherein said oxidizing agent is a solution of hydrogen peroxide and water.
Claim 18
Dependent Claim
26 words
The method of claim 15 wherein the volume of said hydrogen peroxide in said solution of hydrogen peroxide and water is between about 25% and 37%.
Claim 19
Dependent Claim
16 words
The method of claim 11 wherein said first time is between about 48 and 72 seconds.
Claim 20
Dependent Claim
17 words
The method of claim 11 wherein said first temperature is between about 25° C. and 70° C.
Claim 21
Dependent Claim
16 words
The method of claim 11 wherein said second time is between about 300 and 400 seconds.
Claim 22
Dependent Claim
17 words
The method of claim 11 wherein said second temperature is between about 25° C. and 70° C.
References Cited (Backward Citations)
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