US5668094A
Expired / Lapsed
US
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Fabric softening bar compositions containing fabric softener and enduring perfume
Assignee: Procter and Gamble Co
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Filing: 1996-02-26
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Granted: 1997-09-16
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Expires: 2016-02-26
Abstract
Abstract The present invention relates to a fabric softening bar composition comprising: from about 40% to about 90% by weight of the composition of a hydrophobic fabric softening compound, from about 0.1% to about 10% of an enduring perfume composition comprising at least about 70% of enduring perfume ingredients, and optionally, but preferably, from about 5% to about 30% by weight of the composition of a nonionic surfactant, and from about 5% to about 10% by weight of the composition, water. These compositions are low sudsing, low lathering, non-detersive fabric softening compositions which provide long lasting perfume effects.
Inventors
- 👤 Dennis Ray Bacon
- 👤 Alex Haejoon Chung
- 👤 Toan Trinh
- 👤 Frederick Anthony Hartman
- 👤 Robert Mermelstein
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 09:57
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/0005; C11D3/0026; C11D17/00; C11D17/0047; C11D17/006; C11D3/16; C11D3/38; C11D3/386; C11D3/38645; C11D3/50
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
327 words
A low sudsing, fabric softening bar composition comprising: (A) from about 40% to about 90%, by weight of the composition, of a hydrophobic, fabric softening compound selected from the group consisting of quaternary ammonium compounds, carboxylic acid salts of tertiary amines, carboxylic acid salts of tertiary ester amines, sorbitan esters of fatty alcohols, glycerol and polyglycerol esters, fatty amines, fatty acids, alkyl or alkenyl succinic acids, and mixtures thereof; (B) from about 0.01% to about 10% of an enduring perfume comprising at least 70% of enduring perfume ingredients selected from the group consisting of: ingredients having a boiling point of at least about 250° C. and a ClogP of at least about 3, wherein ClogP is the calculated octanol/water partitioning coefficient as the logarithm to the base 10, logP, said ingredients having a boiling point of at least about 250° C. and a cogP of at least about 3 being less than 70% by weight of said enduring perfume so that a perfume with only ingredients having a boiling point of at least about 250° C. and a cogP of at least about 3 will not be an enduring perfume; cis-jasmone; dimethyl benzyl carbinyl acetate; ethyl vanillin; geranyl acetate; alpha-ionone; beta-ionone; gamma-ionone; koavone; lauric aldehyde; methyl dihydrojasmonate; methyl nonyl acetaldehyde; gamma-nonalactone; phenoxy ethyl iso-butyrate; phenyl ethyl dimethyl carbinol; phenyl ethyl dimethyl carbinyl acetate; alpha-methyl-4-(2-methylpropyl)-benzenepropanal; 6-acetyl-1,1,3,4,4,6-hexamethyl tetrahydronaphthalene; undecylenic aldehyde; vanillin; 2,5,5-trimethyl-2-pentyl-cyclopentanone; 2-tert-butylcyclohexanol; verdox; para-tert-butylcyclohexyl acetate; and mixtures thereof; (C) optionally, from about 5% to about 30%, by weight of the composition, of a nonionic surfactant; (D) optionally, from about 5% to about 30%, by weight of the composition, water; and; (E) optionally, cellulase, at a level equivalent to an activity from about 1 to about 100 Cellulase Equivalent Viscosity Units/gram of the composition; wherein when (A) is a sorbitan ester of a fatty alcohol, glycerol ester, or a polyglycerol ester, then (C) cannot also be a sorbitan ester of a fatty alcohol, glycerol ester, or a polyglycerol ester.
Claim 2
Dependent Claim
327 words
A low sudsing, fabric softening bar composition comprising: (A) from about 40% to about 90%, by weight of the composition, of a hydrophobic, fabric softening compound selected from the group consisting of quaternary ammonium compounds, carboxylic acid salts of tertiary amines, carboxylic acid salts of tertiary ester amines, sorbitan esters of fatty alcohols, glycerol and polyglycerol esters, fatty amines, fatty acids, alkyl or alkenyl succinic acids, and mixtures thereof; (B) from about 0.01% to about 10% of an enduring perfume comprising at least 70% of enduring perfume ingredients selected from the group consisting of: ingredients having a boiling point of at least about 250° C. and a ClogP of at least about 3, wherein ClogP is the calculated octanol/water partitioning coefficient as the logarithm to the base 10, logP, said ingredients having a boiling point of at least about 250° C. and a cogP of at least about 3 being less than 70% by weight of said enduring perfume so that a perfume with only ingredients having a boiling point of at least about 250° C. and a cogP of at least about 3 will not be an enduring perfume; cis-jasmone; dimethyl benzyl carbinyl acetate; ethyl vanillin; geranyl acetate; alpha-ionone; beta-ionone; gamma-ionone; koavone; lauric aldehyde; methyl dihydrojasmonate; methyl nonyl acetaldehyde; gamma-nonalactone; phenoxy ethyl iso-butyrate; phenyl ethyl dimethyl carbinol; phenyl ethyl dimethyl carbinyl acetate; alpha-methyl-4-(2-methylpropyl)-benzenepropanal; 6-acetyl-1,1,3,4,4,6-hexamethyl tetrahydronaphthalene; undecylenic aldehyde; vanillin; 2,5,5-trimethyl-2-pentyl-cyclopentanone; 2-tert-butylcyclohexanol; verdox; para-tert-butylcyclohexyl acetate; and mixtures thereof; (C) optionally, from about 5% to about 30%, by weight of the composition, of a nonionic surfactant; (D) optionally, from about 5% to about 30%, by weight of the composition, water; and; (E) optionally, cellulase, at a level equivalent to an activity from about 1 to about 100 Cellulase Equivalent Viscosity Units/gram of the composition; wherein when (A) is a sorbitan ester of a fatty alcohol, glycerol ester, or a polyglycerol ester, then (C) cannot also be a sorbitan ester of a fatty alcohol, glycerol ester, or a polyglycerol ester.
Claim 3
Dependent Claim
27 words
The composition of claim 1 wherein said fabric softening compound is biodegradable and said nonionic surfactant is a solid with a melting point above about 25° C.
Claim 4
Dependent Claim
20 words
The composition of claim 2 wherein the nonionic surfactant is a solid with a melting point above about 30° C.
Claim 5
Dependent Claim
30 words
The composition of claim 2 wherein the enduring perfume has less than about 65% of the total weight of ingredients with a ClogP≧3.0 and a boiling point of ≧250° C.
Claim 6
Dependent Claim
19 words
The composition of claim 4 wherein the enduring perfume has at least about 75% of said enduring perfume ingredients.
Claim 7
Dependent Claim
19 words
The composition of claim 5 wherein the enduring perfume has at least about 80% of said enduring perfume ingredients.
Claim 8
Dependent Claim
19 words
The composition of claim 6 wherein the enduring perfume has at least about 85% of said enduring perfume ingredients.
Claim 9
Dependent Claim
30 words
The composition of claim 1 wherein the enduring perfume has less than about 65% of the total weight of ingredients with a ClogP≧3.0 and a boiling point of ≧250° C.
Claim 10
Dependent Claim
19 words
The composition of claim 8 wherein the enduring perfume has at least about 75% of said enduring perfume ingredients.
Claim 11
Dependent Claim
19 words
The composition of claim 9 wherein the enduring perfume has at least about 80% of said enduring perfume ingredients.
Claim 12
Dependent Claim
19 words
The composition of claim 10 wherein the enduring perfume has at least about 85% of said enduring perfume ingredients.
Claim 13
Dependent Claim
19 words
The composition of claim 1 wherein said enduring perfume present in an amount from about 0.05% to about 5%.
Claim 14
Dependent Claim
21 words
The composition of claim 12 wherein said enduring perfume is present in an amount of from about 0.1% to about 4%.
Claim 15
Dependent Claim
21 words
The composition of claim 13 wherein said enduring perfume is present in the amount of from about 0.15% to about 3%.
Claim 16
Dependent Claim
19 words
The composition of claim 14 wherein the enduring perfume has a least about 75% of said enduring perfume ingredients.
Claim 17
Dependent Claim
19 words
The composition of claim 15 wherein the enduring perfume has a least about 85% of said enduring perfume ingredients.
Claim 18
Dependent Claim
19 words
The composition of claim 12 wherein the enduring perfume has a least about 75% of said enduring perfume ingredients.
Claim 19
Dependent Claim
50 words
The composition of claim 1 the nonionic surfactant is selected from the group consisting of ethoxylated amines, ethoxylated alcohols, alkyl phenol ethoxylates, sorbitan esters of fatty alcohols, glycerol and polyglycerol esters, polyoxyethylene/polyoxypropylene block polymers; polyoxyethylene/polyoxypropylene block polymers of ethylene diamine, polyhydroxy fatty acid amides, amine oxides, alkylpolysaccharides, and mixtures thereof.
Claim 20
Dependent Claim
236 words
The composition of claim 1 wherein the fabric softening compound is a carboxylic acid salt of a tertiary amine, a carboxylic acid salt of a tertiary ester amine, and mixtures thereof of the formula: ##STR10## wherein R 5 is a long chain aliphatic group containing from about 8 to about 30 carbon atoms; each R 4 and R 6 are selected from the group consisting of an aliphatic group containing from about 1 to about 30 carbon atoms, a hydroxyalkyl group of the formula: R 8 OH wherein R 8 is an alkylene group of from about 2 to about 30 carbon atoms, an alkyl ether group of the formula: R 9 O(C s H 2s O) r wherein R 9 is alkyl or alkenyl group having from about 1 to about 30 carbon atoms or a hydrogen atom, s is from 1 to 5, and r is from about 1 to about 30; wherein R 4 , R 5 , R 6 , R 8 , and R 9 can be ester interrupted groups; and wherein R 7 is selected from the group consisting of unsubstituted alkyl, alkenyl, aryl, alkaryl and aralkyl groups having from about 8 to about 30 carbon atoms and substituted alkyl, alkenyl, aryl, alkaryl, and aralkyl groups having from about 1 to about 30 carbon atoms, wherein the substituents are selected from the group consisting of halogen, carboxyl, and hydroxyl group.
Claim 21
Dependent Claim
56 words
The composition of claim 19 wherein the carboxylic acid salt of a tertiary amine and the carboxylic acid salt of a tertiary ester amine has a carboxylic acid salt forming anion moiety wherein the carboxylic acid salt forming anion moiety is selected from the group consisting of lauric, myristic, palmitic, stearic, oleic acid, and mixtures thereof.
Claim 22
Dependent Claim
55 words
The composition of claim 20 wherein the carboxylic acid salt of a tertiary amine and ester amine is selected from the group consisting of oleyldimethylamine stearate, dioleylmethylamine stearate, linoleyldimethylamine stearate, dilinoleylmethylamine stearate, stearyldimethylamine stearate, distearylmethylamine myristate, stearyldimethylamine palmitate, distearylmethylamine palmitate, distearylmethylamine myristate, distearylmethylamine palmitate, distearylmethylamine laurate, dioleyldistearylmethylamine oleate, distearylmethylamine oleate, tallowyldimethylamine stearate, and mixtures thereof.
Claim 23
Dependent Claim
142 words
The composition of claim 1 wherein the fabric softening compound is a quaternary ammonium compound selected from the group consisting of: (R).sub.4-m --N.sup.+ --[(CH.sub.2).sub.n --Y--R.sup.2 ]X.sup.-(I) (R).sub.4-m --N.sup.+ --[R.sup.2 ].sub.m X.sup.- (IV) and mixtures thereof and wherein: each Y is --O--(O)C--, --C(O)--O--; --NH--C(O)--; --(O)C--NH--; and mixtures thereof; m is 1 to 3; each n is 1 to 4; each R substituent is H, a branched or straight chained C 1 -C 6 alkyl group, (C y H 2y O) w H where y is from 1 to 5, and w is from 1 to 5; benzyl group, and mixtures thereof; each R 2 is a long chain, saturated or unsaturated, Iodine Value of from about 3 to about 60; C 8 -C 30 hydrocarbyl, or substituted hydrocarbyl substituent and mixtures thereof, and the counterion, X - , can be any softener-compatible anion.
Claim 24
Dependent Claim
45 words
The composition of claim 22 wherein: each Y is --O--(O)C--, --C(O)--O--; and mixtures thereof, m is 2; each n is 2; each R substituent is a C 1 -C 3 , alkyl group; each R 2 is a saturated C 12 -C 18 alkyl group.
Claim 25
Dependent Claim
67 words
The composition of claim 1 enduring perfume composition contains at least 5% of materials selected from the group consisting of: cis-jasmone; dimethyl benzyl carbinyl acetate; ethyl vanillin; geranyl acetate; alpha-ionone; beta-ionone; gamma-ionone; koavone; lauric aldehyde; methyl dihydrojasmonate; methyl nonyl acetaldehyde; gamma-nonalactone; phenoxy ethyl iso-butyrate; phenyl ethyl dimethyl carbinol; phenyl ethyl dimethyl carbinyl acetate; alpha-methyl-4-(2-methylpropyl)-benzenepropanal; 6-acetyl-1,1,3,4,4,6-hexamethyl tetrahydronaphthalene; undecylenic aldehyde; vanillin; 2,5,5-trimethyl-2-pentyl-cyclopentanone; 2-tert-butylcyclohexanol; verdox; para-tert-butylcyclohexyl acetate; and mixtures thereof.
Claim 26
Dependent Claim
34 words
A method of conditioning fabrics wherein an effective amount to provide softening and/or antistatic effects of the bar composition of claim 1 is contacted with fabrics after a wash cycle of a laundering process.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 2000-09-15 | 2001-03-17 | 2001-09-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2004-09-15 | 2005-03-17 | 2005-09-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2008-09-15 | 2009-03-17 | 2009-09-16 | $7700.00 | Window Closed / Lapsed |