US5657404A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Robust spectroscopic optical probe
Assignee: Rosemount Inc
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Filing: 1995-05-25
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Granted: 1997-08-12
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Expires: 2015-05-25
Abstract
Abstract Disclosed is a spectroscopic probe apparatus useful for Raman, near infrared, luminescence, ultraviolet or visible spectroscopies that is formed with a robust method of construction using a molten metal soldering technique. The disclosed method and apparatus provides an optical probe that is easy to manufacture yet able to withstand drastic environmental conditions without damage and produce useful spectroscopic results under such conditions.
Inventors
- 👤 Norma Lindsey Buchanan
- 👤 Daniel Charles Alsmeyer
- 👤 Gregory Wayne Nelson
- 👤 Roger Dale Edwards
- 👤 Vincent Alvin Nicely
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 05:46
CPC Classifications
G; G02; G02B; G02B6/00; G02B6/24; G02B6/42; G02B6/36; G02B6/38; G02B6/3807; G02B6/3833; G02B6/3855; G01; G01N; G01N21/00; G01N21/84; G01N21/85; G01N21/8507; G02B6/241
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
151 words
A fluid-tight spectroscopic optical probe comprising: (a) a fluid-tight housing; (b) a probe tip having a terminal surface, said probe tip sealably closing one end of said housing; (c) at least one fiber optic excitation channel terminating at said terminal surface of said probe tip and extending within the length of said housing, said excitation channel transmitting radiation from a radiation source to a chemical composition to be irradiated for spectroscopic analysis; and (d) at least one fiber optic collection channel terminating at said terminal surface of said probe tip and extending within the length of said housing, said collection channel transmitting radiation from an irradiated chemical composition to detector means remotely situated from said chemical composition; wherein said fiber optic excitation channel and said fiber optic collection channel are each separated from one another and securely held and sealed within said probe tip by solder means encompassing each said channel.
Claim 2
Dependent Claim
151 words
A fluid-tight spectroscopic optical probe comprising: (a) a fluid-tight housing; (b) a probe tip having a terminal surface, said probe tip sealably closing one end of said housing; (c) at least one fiber optic excitation channel terminating at said terminal surface of said probe tip and extending within the length of said housing, said excitation channel transmitting radiation from a radiation source to a chemical composition to be irradiated for spectroscopic analysis; and (d) at least one fiber optic collection channel terminating at said terminal surface of said probe tip and extending within the length of said housing, said collection channel transmitting radiation from an irradiated chemical composition to detector means remotely situated from said chemical composition; wherein said fiber optic excitation channel and said fiber optic collection channel are each separated from one another and securely held and sealed within said probe tip by solder means encompassing each said channel.
Claim 3
Dependent Claim
13 words
The probe of claim 1 comprising two to six fiber optic collection channels.
Claim 4
Dependent Claim
13 words
The probe of claim 1 comprising two to six fiber optical excitation channels.
Claim 5
Dependent Claim
15 words
The probe of claim 1 wherein said housing and tip are formed from solder-adherable metal.
Claim 6
Dependent Claim
11 words
The probe of claim 4 wherein said metal is stainless steel.
Claim 7
Dependent Claim
33 words
The probe of claim 1 wherein said excitation channel and said collection channel each comprises an optical fiber having a circular cross-section, said fibers having a diameter of 1 μm to 1000 μm.
Claim 8
Dependent Claim
14 words
The probe of claim 6 wherein said diameter is 200 μm to 400 μm.
Claim 9
Dependent Claim
21 words
The probe of claim 6 wherein each said optical fiber further comprises a peripheral surface bearing a thin solder-adherable metallic layer.
Claim 10
Dependent Claim
11 words
The probe of claim 8 wherein said metallic layer comprises gold.
Claim 11
Dependent Claim
16 words
The probe of claim 6 wherein each said optical fiber comprises a step-indexed multimode optical fiber.
Claim 12
Dependent Claim
24 words
The probe of claim 1 wherein said solder means comprises a solder plug, said plug being situated at said terminal surface of said tip.
Claim 13
Dependent Claim
19 words
The probe of claim 11 wherein said solder plug is formed of a silver solder or a gold solder.
Claim 14
Dependent Claim
38 words
The probe of claim 1 further comprising a reflector cap that includes a concave mirror, said cap being situated in close proximity to said tip and capable of reflecting radiation from said excitation channel to said collection channel.
Claim 15
Dependent Claim
12 words
The probe of claim 1 wherein said detector means comprises a spectrometer.
Claim 16
Dependent Claim
25 words
The probe of claim 14 wherein said spectrometer is an ultraviolet-visible (UV/VIS) spectrometer, a near infrared (NIR) spectrometer, a Raman spectrometer, or a luminescence spectrometer.
Claim 17
Dependent Claim
19 words
The probe of claim 15 wherein said spectrometer is a Raman spectrometer and said radiation source is a laser.
Claim 18
Dependent Claim
12 words
The probe of claim 16 wherein said laser is a diode laser.
Claim 19
Dependent Claim
23 words
The probe of claim 15 wherein said spectrometer is a near infrared (NIR) spectrometer and said radiation source is a halogen-modified tungsten lamp.
Claim 20
Dependent Claim
21 words
The probe of claim 15 wherein said spectrometer is an ultraviolet-visible (UV-VIS) spectrometer and said radiation source is a tungsten lamp.
Claim 21
Dependent Claim
12 words
The probe of claim 1 comprising a single fiber optic excitation channel.
Claim 22
Dependent Claim
12 words
The probe of claim 1 comprising a single fiber optic collection channel.
Claim 23
Independent Claim
305 words
A method for forming a fluid-tight spectroscopic optical probe provided with a fluid-tight housing and a probe tip having a terminal surface and sealably closing one end of said housing, said housing and said probe tip each being formed of solder-adherable metal; at least one excitation channel that transmits radiation from a radiation source to a chemical composition to be irradiated; and at least one collection channel that transmits radiation from an irradiated chemical composition to detector means remotely situated from said chemical composition, each said channel comprising an optical fiber having a circular cross-section, one end of each said fiber terminating at said terminal surface of said probe tip and extending within the length of said housing; said method comprising: forming a cavity at said terminal surface of said probe tip; filling said cavity with molten metal solder, then allowing said solder to cool and solidify to a plug; forming at least two closely spaced holes of circular cross-section penetrating through said plug, said holes having a cross-section very slightly larger than the cross-section of said optical fibers; inserting one end of each of said optical fibers through said probe tip and into each of said holes in said plug, thereby substantially filling said holes in said probe tip and plug, said ends of said fibers being separated from one another and together with said plug forming a substantially continuous surface with said terminal surface of said probe tip; heating said solder plug to a temperature sufficient to cause the solder to flow around and encompassing each said optical fiber end; cooling said plug to ambient temperature, thereby securing and sealing said separated optical fiber ends at said terminal surface of said probe tip; and grinding and polishing said substantially continuous terminal surface of said probe tip, thereby forming an optically smooth terminal surface.
Claim 24
Independent Claim
305 words
A method for forming a fluid-tight spectroscopic optical probe provided with a fluid-tight housing and a probe tip having a terminal surface and sealably closing one end of said housing, said housing and said probe tip each being formed of solder-adherable metal; at least one excitation channel that transmits radiation from a radiation source to a chemical composition to be irradiated; and at least one collection channel that transmits radiation from an irradiated chemical composition to detector means remotely situated from said chemical composition, each said channel comprising an optical fiber having a circular cross-section, one end of each said fiber terminating at said terminal surface of said probe tip and extending within the length of said housing; said method comprising: forming a cavity at said terminal surface of said probe tip; filling said cavity with molten metal solder, then allowing said solder to cool and solidify to a plug; forming at least two closely spaced holes of circular cross-section penetrating through said plug, said holes having a cross-section very slightly larger than the cross-section of said optical fibers; inserting one end of each of said optical fibers through said probe tip and into each of said holes in said plug, thereby substantially filling said holes in said probe tip and plug, said ends of said fibers being separated from one another and together with said plug forming a substantially continuous surface with said terminal surface of said probe tip; heating said solder plug to a temperature sufficient to cause the solder to flow around and encompassing each said optical fiber end; cooling said plug to ambient temperature, thereby securing and sealing said separated optical fiber ends at said terminal surface of said probe tip; and grinding and polishing said substantially continuous terminal surface of said probe tip, thereby forming an optically smooth terminal surface.
Claim 25
Dependent Claim
19 words
The method of claim 22 wherein said solder plug is formed of a silver solder or a gold solder.
Claim 26
Dependent Claim
17 words
The method of claim 22 further comprising: sealably connecting said housing with said probe tip by soldering.
Claim 27
Dependent Claim
22 words
The method of claim 22 wherein each said optical fiber further comprises a peripheral surface bearing a thin solder-adherable layer of gold.
Claim 28
Dependent Claim
20 words
The method of claim 22 wherein each said optical fiber has a diameter of about 200 μm to 400 μm.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2000-08-11 | 2001-02-10 | 2001-08-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2004-08-11 | 2005-02-10 | 2005-08-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2008-08-11 | 2009-02-10 | 2009-08-12 | $7700.00 | Window Closed / Lapsed |