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US5602269A Expired / Lapsed US ⏱️ 0.0 years remaining

Organometallic derivatives of group IIIA and process for their preparation

Assignee: Enichem Elastomeri SpA
•
Filing: 1995-07-18
•
Granted: 1997-02-11
•
Expires: 2015-07-18
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Abstract

Abstract New organometallic derivatives of group IIIA are described having general formula M(C 6 F 5 ) 3 wherein M is a metal of group IIIA selected from aluminium, gallium and indium. The above derivatives are prepared by exchange reaction between a metal alkyl MR 3 with an organometallic derivative of boron having the formula B(C 6 F 5 ) 3 .

Inventors

  • 👤 Paolo Biagini
  • 👤 Gabriele Lugli
  • 👤 Luigi Abis
  • 👤 Piero Andreussi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 10:09
CPC Classifications
C; C07; C07F; C07F5/00; C07F5/06; C07F5/061; C07F5/062

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 17 words
A compound of the formula (I): M(C 6 F 5 ) 3 , wherein M is aluminum.
Claim 2
Dependent Claim 17 words
A compound of the formula (I): M(C 6 F 5 ) 3 , wherein M is aluminum.
Claim 3
Dependent Claim 75 words
A process for the preparation of a compound having formula (I): M(C 6 F 5 ) 3 , which comprises: reacting B(C 6 F 5 ) 3 with a compound having the formula: M(H) n R m , wherein M is aluminum and R is a member selected from the group consisting of aliphatic, cycloaliphatic, benzylic, linear or branched, monofunctional radicals containing from 1 to 20 carbon atoms; n+m=3 and n is 0 or 1.
Claim 4
Dependent Claim 75 words
A process for the preparation of a compound having formula (I): M(C 6 F 5 ) 3 , which comprises: reacting B(C 6 F 5 ) 3 with a compound having the formula: M(H) n R m , wherein M is aluminum and R is a member selected from the group consisting of aliphatic, cycloaliphatic, benzylic, linear or branched, monofunctional radicals containing from 1 to 20 carbon atoms; n+m=3 and n is 0 or 1.
Claim 5
Dependent Claim 12 words
The process of claim 2, wherein R is methyl, ethyl or isobutyl.
Claim 6
Dependent Claim 24 words
The process of claim 3, wherein the molar ratio of B(C 6 F 5 ) 3 to M(H) n R m is about 1:1.
Claim 7
Dependent Claim 13 words
The process of claim 2, wherein the reaction occurs in a hydrocarbon solvent.
Claim 8
Dependent Claim 20 words
The process of claim 2, wherein the reaction is conducted at a temperature ranging from -20° C. to 100° C.
Claim 9
Dependent Claim 16 words
The process of claim 6, wherein the reaction temperature ranges from 0° C. to 30° C.
Claim 10
Dependent Claim 17 words
The process of claim 2, wherein M is aluminum, m=3 and R is methyl, ethyl or isobutyl.

References Cited (Backward Citations)

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2000-02-11 2000-08-12 2001-02-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-02-11 2004-08-12 2005-02-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2008-02-11 2008-08-12 2009-02-11 $7700.00 Window Closed / Lapsed

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