← Back to Patent Explorer
US5596102A Expired / Lapsed US ⏱️ 0.0 years remaining

Biocides

Assignee: Avecia Ltd
•
Filing: 1994-12-15
•
Granted: 1997-01-21
•
Expires: 2014-12-15
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Compounds having a 5 membered, nitrogen containing ring with a thione group adjacent to a nitrogen atom substituted with an OR group have antimicrobial properties. Metal complexes or salts of these compounds also have antimicrobial properties. The compounds, or the metal complexes or salts thereof, can be used as a cutting fluid preservative, a wood preservative, in cooling water applications or as an antimicrobial agent in a paint. Some of the compounds are new. The metal complexes or salts are new.

Inventors

  • 👤 Peter W. Austin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 23:57
CPC Classifications
C; C07; C07D; C07D277/00; C07D277/60; C07D277/62; C07D277/68; C07D277/70; C07D277/72; A; A01; A01N; A01N43/00; A01N43/48; A01N43/50; A01N43/52; A01N43/72; A01N43/74; A01N43/78; C07D233/00; C07D233/54; C07D233/66; C07D233/84; C07D233/88; C07D277/02; C07D277/20; C07D277/32; C07D277/36; C09; C09D; C09D5/00; C09D5/02; C09D5/024; C09D5/025; C14; C14C; C14C9/00

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 96 words
A metal complex of a compound of formula I ##STR10## wherein the metal is copper or a metal of Group VIII or IIB of the Periodic Table, A and B are independently selected from --C(R 2 ) 2 --, --CR 2 ═ or >C═NR 2 ; D is --NR 2 -- or sulphur R is hydrogen; and R 2 is hydrogen, C 1-6 hydrocarbyl, C 1-6 hydrocarbyl substituted by halogen or two groups R 2 together with the carbon atom or carbon atoms to which they are attached form a 5- or 6-membered hydrocarbon ring system.
Claim 2
Dependent Claim 96 words
A metal complex of a compound of formula I ##STR10## wherein the metal is copper or a metal of Group VIII or IIB of the Periodic Table, A and B are independently selected from --C(R 2 ) 2 --, --CR 2 ═ or >C═NR 2 ; D is --NR 2 -- or sulphur R is hydrogen; and R 2 is hydrogen, C 1-6 hydrocarbyl, C 1-6 hydrocarbyl substituted by halogen or two groups R 2 together with the carbon atom or carbon atoms to which they are attached form a 5- or 6-membered hydrocarbon ring system.
Claim 3
Dependent Claim 18 words
The metal complex of claim 1 wherein A and B are --CR 2 ═ and D is sulphur.
Claim 4
Dependent Claim 14 words
The metal complex of claim 1 wherein the metal is iron, copper or zinc.
Claim 5
Dependent Claim 20 words
The metal complex of claim 1 of: 3-hydroxy-4-methylthiazol-2(3H)-thione, 3-hydroxy-4-phenylthiazol-2(3H)-thione, 3-hydroxy-4,5,6,7-tetrahydrobenzothiazol-2(3H)-thione, 5,5-dimethyl-1-hydroxy-4-imimo-3-phenylimidazolidine-2-thione, 1-hydroxy-4-imino-3-phenyl-2-thiono-1,3-diazaspiro[4,5]decane, 4,5-dimethyl-3-hydroxythiazol-2(3H)-thione, 4-ethyl-3-hydroxy-5-methylthiazol-2(3H)-thione, 4-(4-chlorophenyl)-3-hydroxythiazol-2(3H)-thione, 3-hydroxy-5-methyl-4-phenylthiazol-2(3H)-thione, 1-hydroxy-5-methyl-4-phenyl imidazoline-2-thione, or 3-hydroxy-5-methyl-4-phenylthiazol-2(3H)-thione.
Claim 6
Dependent Claim 11 words
The zinc complexes of claim 1 of: 3-hydroxy-4-methylthiazole-2(3H)-thione, 4,5-dimethyl-3-hydroxythiazole-2(3H)-thione and 4-ethyl-3-hydroxy-5-methylthiazole-2(3H)-thione.
Claim 7
Dependent Claim 22 words
A metal complex as claimed in claim 1 wherein R 2 is selected from the group hydrogen, methyl, ethyl, phenyl or chlorophenyl.
Claim 8
Dependent Claim 20 words
A metal complex as claimed in claim 1 wherein the groups A and B are linked through a double bond.

References Cited (Backward Citations)

GB1113634A Cited
US3448116A Cited
GB1104893A Cited
US4278793A Cited
EP0064657A1 Cited
US4454216A Cited
DE3510178A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2000-01-21 2000-07-22 2001-01-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-01-21 2004-07-22 2005-01-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2008-01-21 2008-07-22 2009-01-21 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag