Process for making fullerene fibers

Claim 2

A process for making a carbon fiber comprising one or more fullerene tubes, comprising: (a) establishing an electric field between a needle tip and an opposing electrode; (b) providing vaporized carbon to the space around the electric field to form a growing carbon-containing precursor for fullerene which precursor contains carbon-carbon bonds that have a fullerene structure on the needle tip; (c) focusing a laser beam between the growing precursor and the opposing electrode; and (d) withdrawing the needle tip from the opposing electrode while maintaining the electric field between the growing precursor and the opposing electrode and while providing vaporized carbon to the space around the electric field to form said carbon fiber.

Claim 3

A process in accordance with claim 1 wherein the needle tip and the growing precursor are electrically biased to ground.

Claim 4

A process in accordance with claim 2 wherein the electric field is maintained at a pressure of less than 0.001 Torr.

Claim 5

A process in accordance with claim 3 wherein the vaporized carbon is provided to the space around the electric field by introducing a carbon feedstock comprising paraffins, olefins, aromatics, alcohols, ethers, esters, aldehydes, ketones, alkynes or mixtures thereof to the space around the electric field.

Claim 6

A process in accordance with claim 4 wherein the carbon feedstock is anthracene.

Claim 7

A process in accordance with claim 3 wherein the vaporized carbon is provided to the space around the electric field by introducing a carbon feedstock comprising graphite to the space around the electric field.

Claim 8

A process in accordance with claim 3 wherein the vaporized carbon is provided to the space around the electric field by introducing a carbon feedstock comprising fullerenes to the space around the electric field.

Claim 9

A process in accordance with claim 7 wherein the carbon feedstock consists essentially of fullerenes.

Claim 10

A process in accordance with claim 8 wherein the fullerenes are selected from the group of (La@C 60 ), (La@C 82 ), (La 2 @C 66 ), (La 2 @C 88 ), (La 3 @C 94 ), (@C 60 ), (@C 70 ) and mixtures thereof.

Claim 11

A process in accordance with claim 3 wherein the carbon feedstock comprises boron or nitrogen.

Claim 12

A process for making carbon fibers comprising one or more fullerene tubes, which comprises: (a) introducing carbon to a fiber growth site comprising an electric field and a laser beam for heating the growth site; (b) guiding the carbon with the electric field to said growth site; (c) reacting at least a portion of the carbon guided to the growth site into a carbon-containing precursor for fullerene which precursor contains carbon-carbon bonds that have a fullerene structure to form said carbon fiber; and (d) maintaining the growth site positioned in the laser beam.

Claim 13

A process for making carbon fibers comprising one or more fullerene tubes, which comprises: (a) introducing carbon to a fiber growth site comprising an electric field and a laser beam for heating the growth site; (b) guiding the carbon with the electric field to said growth site; (c) reacting at least a portion of the carbon guided to the growth site into a carbon-containing precursor for fullerene which precursor contains carbon-carbon bonds that have a fullerene structure to form said carbon fiber; and (d) maintaining the growth site positioned in the laser beam.

Claim 14

A process in accordance with claim 11, wherein the growth site is maintained positioned in the means for heating a growth site by manipulating the relative position of the fiber.

Claim 15

A process for making fullerene tubes comprising: (a) providing a fullerene tube nucleation zone maintained in an electric field, (b) providing a needle tip and a laser beam within the fullerene tube nucleation zone, c) providing carbon to the fullerene tube nucleation zone under conditions sufficient to form a carbon-containing precursor for fullerene which precursor contains carbon-carbon bonds that have a fullerene structure, having a first end anchored to the needle tip and a second end open for bonding to additional carbon, and (d) withdrawing the needle tip from the fullerene tube nucleation zone to maintain the second end within the laser beam in the fullerene tube nucleation zone.

Claim 16

A process for making fullerene tubes comprising: (a) providing a fullerene tube nucleation zone maintained in an electric field, (b) providing a needle tip and a laser beam within the fullerene tube nucleation zone, c) providing carbon to the fullerene tube nucleation zone under conditions sufficient to form a carbon-containing precursor for fullerene which precursor contains carbon-carbon bonds that have a fullerene structure, having a first end anchored to the needle tip and a second end open for bonding to additional carbon, and (d) withdrawing the needle tip from the fullerene tube nucleation zone to maintain the second end within the laser beam in the fullerene tube nucleation zone.

Claim 17

A process for making a carbon fiber comprising one or more fullerene tubes, comprising: (a) establishing an electric field between an initial fullerene growth site and an opposing electrode; (b) focusing a laser beam between said initial fullerene growth site and the opposing electrode; (c) providing vaporized carbon to a space around the electric field to form a growing carbon-containing precursor for fullerene which precursor contains carbon-carbon bonds that have a fullerene structure on said initial fullerene growth site; and (d) withdrawing said initial fullerene growth site from the opposing electrode while maintaining the electric field between the growing precursor and the opposing electrode and while providing vaporized carbon to the space around the electric field to form said carbon fiber connected to said initial fullerene growth site.

Claim 18

A process for making a carbon fiber comprising one or more fullerene tubes, comprising: (a) establishing an electric field between an initial fullerene growth site and an opposing electrode; (b) focusing a laser beam between said initial fullerene growth site and the opposing electrode; (c) providing vaporized carbon to a space around the electric field to form a growing carbon-containing precursor for fullerene which precursor contains carbon-carbon bonds that have a fullerene structure on said initial fullerene growth site; and (d) withdrawing said initial fullerene growth site from the opposing electrode while maintaining the electric field between the growing precursor and the opposing electrode and while providing vaporized carbon to the space around the electric field to form said carbon fiber connected to said initial fullerene growth site.

Claim 19

A process in accordance with claim 14 wherein said initial fullerene growth site is a needle tip.

Claim 20

A process in accordance with claim 14 wherein said initial fullerene growth site is a carbon fiber.

Claim 21

A process in accordance with claim 14 wherein said laser beam is initially focused to heat said initial fullerene growth site and is maintained focused on the growing precursor as said initial fullerene growth site is withdrawn from the opposing electrode.

Claim 22

A process for making a carbon fiber comprising one or more fullerene tubes, comprising: (a) establishing a high electric field having strength of 1 to 20 volts per Angstrom between a needle tip and an opposing electrode in the absence of an electrical discharge; (b) providing vaporized carbon to the space around the high electric field to form a growing carbon-containing precursor for fullerene which precursor contains carbon-carbon bonds that have a fullerene structure on the needle tip; and (c) withdrawing the needle tip from the opposing electrode while maintaining the high electric field between said growing precursor and the opposing electrode and while providing vaporized carbon to the space around the high electric field to form said carbon fiber.

Claim 23

A process for making a carbon fiber comprising one or more fullerene tubes, comprising: (a) establishing a high electric field having strength of 1 to 20 volts per Angstrom between a needle tip and an opposing electrode in the absence of an electrical discharge; (b) providing vaporized carbon to the space around the high electric field to form a growing carbon-containing precursor for fullerene which precursor contains carbon-carbon bonds that have a fullerene structure on the needle tip; and (c) withdrawing the needle tip from the opposing electrode while maintaining the high electric field between said growing precursor and the opposing electrode and while providing vaporized carbon to the space around the high electric field to form said carbon fiber.

Claim 24

A process in accordance with claim 18 wherein the needle tip and the growing precursor are electrically biased to ground.

Claim 25

A process in accordance with claim 19 wherein the high electric field is maintained at a pressure of less than 0.001 Torr.

Claim 26

A process in accordance with claim 20 wherein the vaporized carbon is provided to the space around the high electric field by introducing a carbon feedstock comprising paraffins, olefins, aromatics, alcohols, ethers, esters, aldehydes, ketones, alkynes or mixtures thereof to the space around the high electric field.

Claim 27

A process in accordance with claim 21 wherein the carbon feedstock is anthracene.

Claim 28

A process in accordance with claim 20 wherein the vaporized carbon is provided to the space around the high electric field by introducing a carbon feedstock comprising graphite to the space around the high electric field.

Claim 29

A process in accordance with claim 20 wherein the vaporized carbon is provided to the space around the high electric field by introducing a carbon feedstock comprising fullerenes to the space around the high electric field.

Claim 30

A process in accordance with claim 24 wherein the carbon feedstock consists essentially of fullerenes.

Claim 31

A process in accordance with claim 25 wherein the fullerenes are selected from the group of (La@C 60 ), (La@C 82 ), (La 2 @C 66 ), (La 2 @C 88 ), (La 3 @C 94 ), (@C 60 ), (@C 70 ) and mixtures thereof.

Claim 32

A process in accordance with claim 20 wherein the carbon feedstock comprises boron, nitrogen or mixtures thereof.

Claim 33

A process in accordance with claim 18 wherein a laser beam is focused between the growing precursor and the opposing electrode.

Claim 34

A process for making carbon fibers comprising one or more fullerene tubes, which comprises: (a) introducing carbon to a carbon fiber growth site comprising an electric field having a field strength of 1 to 20 volts per Angstrom and a means for heating the growth site comprising a laser beam or light as the heat source; (b) maintaining the electric field to prevent electrical discharges therein; (c) guiding the carbon with the electric field to said growth site; (d) reacting at least a portion of the carbon guided to the growth site into a carbon-containing precursor for fullerene which precursor contains carbon-carbon bonds that have a fullerene structure to form said carbon fiber; and e) maintaining the growth site positioned in the means for heating said growth site.

Claim 35

A process for making carbon fibers comprising one or more fullerene tubes, which comprises: (a) introducing carbon to a carbon fiber growth site comprising an electric field having a field strength of 1 to 20 volts per Angstrom and a means for heating the growth site comprising a laser beam or light as the heat source; (b) maintaining the electric field to prevent electrical discharges therein; (c) guiding the carbon with the electric field to said growth site; (d) reacting at least a portion of the carbon guided to the growth site into a carbon-containing precursor for fullerene which precursor contains carbon-carbon bonds that have a fullerene structure to form said carbon fiber; and e) maintaining the growth site positioned in the means for heating said growth site.

Claim 36

A process in accordance with claim 29 wherein the growth site is maintained positioned in the means for heating a growth site by manipulating the relative position of the fiber.

Claim 37

A process in accordance with claim 29 wherein the means for heating a growth site is a laser beam.