US5543124A
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Process for reducing nitrogen oxides
Assignee: Toyota Central R&D Labs Inc
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Filing: 1994-10-20
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Granted: 1996-08-06
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Expires: 2014-10-20
Abstract
Abstract A process for efficiently reducing nitrogen oxides in exhaust gases including excess oxygen. The process includes intermittently introducing a reducing agent, such as hydrogen and carbon monoxide, for reducing nitrogen oxides to a reducing catalyst, such as platinum, disposed in an exhaust gas passage while maintaining an oxygen excess condition. The reducing agent is intermittently introduced in a manner to satisfy the following equation: [NOx]<[H2]+[CO], wherein [H2], [CO] and [NOx] are molar concentrations of hydrogen, carbon monoxide and nitrogen oxides, respectively. The reducing catalyst may include a transition metal, an alkaline metal and/or an alkaline earth metal.
Inventors
- 👤 Koji Yokota
- 👤 Masayuki Fukui
- 👤 Toshiyuki Tanaka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 15:55
CPC Classifications
F; F01; F01N; F01N3/00; F01N3/08; F01N3/10; F01N3/24; F01N3/28; F01N3/2882; B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9404; B01D53/9409; B01D53/9413; B01D53/9418; F01N3/18; F01N3/20; F01N3/206; B01D2251/00; B01D2251/20; B01D2251/202; B01D2251/204; B01D2255/00; B01D2255/10; B01D2255/102; B01D2255/1021; B01D2255/1023; B01D2255/20; B01D2255/202; B01D2255/204; B01D2255/2042; B01D2255/2047; B01D2255/209; B01D2255/2092; F01N2610/00; F01N2610/04
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
160 words
A process for reducing nitrogen oxides in exhaust gases including excess oxygen, the amount of which is larger than a stoichiometric amount of oxygen required to oxidize components to be oxidized in said exhaust gases, comprising the steps of: i) bringing said exhaust gases into contact with a catalyst for reducing nitrogen oxides; and ii) reducing said nitrogen oxides by intermittently introducing a reducing agent for reducing nitrogen oxides to said reducing catalyst, wherein said reducing catalyst comprises a porous carrier of at least one material selected from the group consisting of silica, zeolite and alumina, and platinum loaded thereon, said reducing agent is selected from the group consisting of hydrogen (H 2 ) and carbon monoxide (CO), and said reducing agent is intermittently introduced in a manner to satisfy the following equation: [NO.sub.x ]<[H.sub.2 ]+[CO], wherein [H 2 ], [CO] and [NO x ] are molar concentrations in said exhaust gases of hydrogen, carbon monoxide and nitrogen oxides, respectively.
Claim 2
Dependent Claim
160 words
A process for reducing nitrogen oxides in exhaust gases including excess oxygen, the amount of which is larger than a stoichiometric amount of oxygen required to oxidize components to be oxidized in said exhaust gases, comprising the steps of: i) bringing said exhaust gases into contact with a catalyst for reducing nitrogen oxides; and ii) reducing said nitrogen oxides by intermittently introducing a reducing agent for reducing nitrogen oxides to said reducing catalyst, wherein said reducing catalyst comprises a porous carrier of at least one material selected from the group consisting of silica, zeolite and alumina, and platinum loaded thereon, said reducing agent is selected from the group consisting of hydrogen (H 2 ) and carbon monoxide (CO), and said reducing agent is intermittently introduced in a manner to satisfy the following equation: [NO.sub.x ]<[H.sub.2 ]+[CO], wherein [H 2 ], [CO] and [NO x ] are molar concentrations in said exhaust gases of hydrogen, carbon monoxide and nitrogen oxides, respectively.
Claim 3
Dependent Claim
32 words
A process for reducing nitrogen oxides according to claim 1, wherein said reducing catalyst further comprises at least one metal selected from the group consisting of alkali metals and alkaline earth metals.
Claim 4
Dependent Claim
34 words
A process for reducing nitrogen oxides according to claim 2, wherein said at least one metal is included in the range of from 0.001 to 15 by molar ratio with respect to said platinum.
Claim 5
Dependent Claim
51 words
A process for reducing nitrogen oxides according to claim 2, wherein said alkali metal is at least one metal selected from the group consisting of lithium, sodium, potassium, and rubidium, and said alkaline earth metal is at least one metal selected from the group consisting of magnesium, calcium, strontium and barium.
Claim 6
Dependent Claim
26 words
The process for reducing nitrogen oxides according to claim 1, wherein said reducing catalyst further comprises an oxidation inhibitor for suppressing the oxidation of said platinum.
Claim 7
Dependent Claim
31 words
A process for reducing nitrogen oxides according claim 5, wherein said reducing catalyst further comprises at least one metal selected from the group consisting of alkali metals and alkaline earth metals.
Claim 8
Dependent Claim
51 words
A process for reducing nitrogen oxides according to claim 6, wherein said alkali metal is at least one metal selected from the group consisting of lithium, sodium, rubidium, and potassium and said alkaline earth metal is at least one metal selected from the group consisting of magnesium, calcium, strontium and barium.
Claim 9
Dependent Claim
34 words
A process for reducing nitrogen oxides according to claim 6, wherein said at least one metal is included in the range of from 0.001 to 15 by molar ratio with respect to said platinum.
Claim 10
Dependent Claim
22 words
A process for reducing nitrogen oxides according to claim 5, wherein said oxidation inhibitor comprises an alkali metal and a transition metal.
Claim 11
Dependent Claim
16 words
A process for reducing nitrogen oxides according to claim 9, wherein said transition metal is molybdenum.
Claim 12
Dependent Claim
32 words
A process for reducing nitrogen oxides according to claim 9, wherein said alkali metal is included in the range of from 0.001 to 15 by molar ratio with respect to said platinum.
Claim 13
Dependent Claim
32 words
A process for reducing nitrogen oxides according to claim 9, wherein said transition metal is included in the range of not less than 3 by molar ratio with respect to said platinum.
Claim 14
Dependent Claim
30 words
A process for reducing nitrogen oxides according to claim 9, wherein said alkali metal is at least one element selected from the group consisting of lithium, sodium, rubidium and potassium.
References Cited (Backward Citations)
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