Fabric softener compositions with improved environmental impact

Claim 2

A rinse-added liquid fabric softening composition comprising: (A) from about 0.5% to about 80% of biodegradable cationic fabric softening compound; (B) from about 0.01% to about 10% of an enduring perfume which has at least about 70% of components with a ClogP≧3.0 and a boiling point of≧250° C., ClogP being the calculated octanol/water partitioning coefficient (P) expressed as the logarithm to the base 10, logP; (C) optionally, from about 0% to about 30% of dispersibility modifier; and (D) the balance comprising a liquid carrier selected from the group consisting of: water, C 1-4 monohydric alcohol; C 2-6 polyhydric alcohol; propylene carbonate; liquid polyethylene glycols; and mixtures thereof; and wherein the dispersibility modifier affects the viscosity of said liquid fabric softening composition.

Claim 3

The composition of claim 1 wherein the quaternary ammonium fabric softening compound has the formula: (R).sub.4-m --.sup.+ N--[(CH.sub.2).sub.n --Y--R.sup.2 ].sub.m X.sup.- wherein: each Y is --O--(O)C--, or --C(O)--O--; m is 2 or 3; n is 1 to 4; each R is a C 1 -C 6 alkyl group, hydroxyalkyl group, benzyl group, or mixtures thereof, each R 2 is a C 12 -C 22 hydrocarbyl or substituted hydrocarbyl substituent; and X - is any softener-compatible anion.

Claim 4

The composition of claim 2 wherein the quaternary ammonium compound is derived from C 12 -C 22 fatty acyl groups having an Iodine Value of from greater than about 5 to less than about 100, a cis/trans isomer weight ratio of greater than about 30/70 when the Iodine Value is less than about 25, the level of unsaturation of the fatty acyl groups being less than about 65% by weight.

Claim 5

The composition of claim 2 wherein the enduring perfume has at least about 75% of the total weight of components with a ClogP≧3.0 and a boiling point of≧250° C.

Claim 6

The composition of claim 2 wherein the enduring perfume has at least about 80% of the total weight of components with a ClogP≧3.0 and a boiling point of≧250° C.

Claim 7

The composition of claim 2 wherein the enduring perfume has at least about 85% of the total weight of components with a ClogP≧3.0 and a boiling point of≧250° C.

Claim 8

The composition of claim 1 wherein the the enduring perfume has a least about 75% of the total weight of components with a ClogP≧3.0 and a boiling point of≧250° C.

Claim 9

The composition of claim 1 wherein the enduring perfume has at least about 80% of the total weight of components with a ClogP≧3.0 and a boiling point of≧250° C.

Claim 10

The composition of claim 1 wherein the enduring perfume has at least about 85% of the total weight of components with a ClogP≧3.0 and a boiling point of≧250° C.

Claim 11

The composition of claim 1 wherein said enduring perfume composition is present at a level of from about 0.05% to about 8%.

Claim 12

The composition of claim 10 wherein said enduring perfume composition is present at a level of from about 0.1% to about 6%.

Claim 13

The composition of claim 11 wherein said enduring perfume composition is present at a level of from about 0.15% to about 4%.

Claim 14

The composition of claim 11 wherein the enduring perfume has a least about 85% of the total weight of components with a ClogP≧3.0 and a boiling point of≧250° C.

Claim 15

The composition of claim 10 wherein the enduring perfume has a least about 75% of the total weight of components with a ClogP≧3.0 and a boiling point of≧250° C.

Claim 16

The composition of claim 1 wherein said dispersibility modifier is selected from the group consisting of: single-long-chain-C 10 -C 22 alkyl, cationic surfactant; nonionic surfactant with at least 8 ethoxy moieties; amine oxide surfactant; and mixtures thereof.

Claim 17

The composition according to claim 15 wherein the dispersibility modifier is a single-long-chain-alkyl cationic surfactant which is present in an effective amount to affect the viscosity of up to about 15% of the composition.

Claim 18

The composition according to claim 16 wherein the dispersibility modifier is a quaternary ammonium salt of the general formula: [R.sup.2 N.sup.+ R.sub.3 ] X.sup.- wherein the R 2 group is a C 10 -C 22 hydrocarbon group, or the corresponding ester linkage interrupted group with a short alkylene (C 1 -C 4 ) group between the ester linkage and the N, and having a similar hydrocarbon group, each R is a C 1 -C 4 alkyl or substituted alkyl, or hydrogen; and the counterion X - is a softener compatible anion.

Claim 19

The composition according to claim 17 wherein the dispersibility modifier is C 12 -C 14 choline ester.

Claim 20

The composition according to claim 15 wherein the dispersibility modifier is a nonionic surfactant which is present in an effective amount to affect the viscosity of up to about 15% of the composition.

Claim 21

The composition according to claim 19 wherein the dispersibility modifier is C 10-14 alcohol with poly(10-18)ethoxylate.

Claim 22

The composition according to claim 15 wherein the dispersibility modifier is amine oxide with one alkyl, or hydroxyalkyl, moiety of about 8 to about 22 carbon atoms and two alkyl moieties selected from the group consisting of alkyl groups and hydroxyalkyl groups containing from one to about three carbon atoms.

Claim 23

The composition of claim 1 wherein the composition comprises: (A) from about 1% to about 35% of biodegradable quaternary ammonium fabric softening compound; (B) from about 0.05% to about 6% of an enduring perfume composition; (C) from about 0.5% to about 10% of dispersibility modifier wherein the dispersibility modifier affects the composition's viscosity, dispersibility in a laundry process rinse cycle, or both; and (D) the balance comprising a liquid carrier selected from the group consisting of water; C 1 -C 4 monohydric alcohols; C 2 -C 6 polyhydric alcohols; propylene carbonate; liquid polyalkylene glycols; and mixtures thereof.

Claim 24

The composition of claim 1 wherein the composition comprises: (A) from about 15% to about 50% of biodegradable quaternary, ammonium fabric softening compound; (B) from about 0.05% to about 6% of an enduring perfume composition; (C) from about 0.5% to about 5% of dispersibility modifier wherein the dispersibility modifier affects the composition's viscosity; the balance comprising a liquid carder selected from the group consisting of water; C 1 -C 4 monohydric alcohols; C 2 -C 6 polyhydric alcohols; propylene carbonate; liquid polyalkylene glycols; and mixtures thereof, and wherein said composition further comprises from 0% to about 1% of a stabilizer; and from about 0.01% to about 2% electrolyte.

Claim 25

The composition of claim 23 wherein the quaternary ammonium fabric softening compound has the formula: (R).sub.4-m --.sup.+ N--[(CH.sub.2).sub.n --Y--R.sup.2 ].sub.m X.sup.- wherein: each Y is --O--(O)C--, or --C(O)--O--; m is 2 or 3; n is 1 to 4; each R is a C 1 -C 6 alkyl group, hydroxyalkyl group, benzyl group, or mixtures thereof; each R 2 is a C 12 -C 22 hydrocarbyl or substituted hydrocarbyl substituent; and X - is any softener-compatible anion.

Claim 26

The composition of claim 24 wherein the quaternary ammonium compound is derived from C 12 -C 22 fatty acyl groups having an Iodine Value of from greater than about 5 to less than about 100, a cis/trans isomer weight ratio of greater than about 30/70 when the Iodine Value is less than about 25, the level of unsaturation of the fatty acyl groups being less than about 65% by weight.

Claim 27

The composition of claim 24 wherein the enduring perfume has at least about 75% of the total weight of components with a ClogP≧3.0 and a boiling point of≧250° C.

Claim 28

The composition of claim 24 wherein the enduring perfume has at least about 80% of the total weight of components with a ClogP≧3.0 and a boiling point of≧250° C.

Claim 29

The composition of claim 24 wherein the enduring perfume has at least about 85% of the total weight of components with a ClogP≧3.0 and a boiling point of≧250° C.

Claim 30

The composition of claim 24 wherein the level of said enduring perfume composition is from about 0.15% to about 4%.

Claim 31

The composition of claim 23 wherein the level of said enduring perfume composition is from about 0.15% to about 4%.

Claim 32

The composition of claim 1 wherein said enduring perfume composition contains at least 70% of materials selected from the group consisting of: Allyl cyclohexane propionate; Ambrettolide; Amyl benzoate; Amyl cinnamate; Amyl cinnamic aldehyde; Amyl cinnamic aldehyde dimethyl acetal; iso-Amyl salicylate; Hydroxycitronellal-methylanthranilate; Benzophenone; Benzyl salicylate; para-tert-Butyl cyclohexyl acetate; iso-Butyl quinoline; beta-Caryophyllene; Cadinene; Cedrol; Cedryl acetate; Cedryl formate; Cinnamyl cinnamate; Cyclohexyl salicylate; Cyclamen aldehyde; Dihydro isojasmonate; Diphenyl methane; Diphenyl oxide; Dodecalactone; 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)-ethanone; Ethylene brassylate; Ethylmethyl phenyl glycidate; Ethyl undecylenate; 15-Hydroxypentadecanoic acid, lactone; 1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethytcyclopenta-gamma-2-benzopyran; Geranyl anthranilate; Geranyl phenyl acetate; Hexadecanolide; Hexenyl salicylate; Hexyl cinnamic aldehyde; Hexyl salicylate; alpha-Irone; para-tertiary-Butyl-alpha-methyl hydrocinnamic aldehyde; Linalyl benzoate; 2-Methoxy naphthalene; Methyl dihydrojasmone; gamma-n-Methyl ionone; Musk indanone; Musk ketone; Musk tibetine; Myristicin; Oxahexadecanolide-10; Oxahexadecanolide-11; Patchouli alcohol; 5-Acetyl-1,1,2,3,3,6-hexamethyl indan; Phenyl ethyl benzoate; Phenylethylphenylacetate; Phenyl heptanol; Phenyl hexanol; alpha-Santalol; delta-Undecalactone; gamma-Undecalactone; Vetiveryl acetate; yara-yara; Ylangene; and mixtures thereof.

Claim 33

A solid particulate composition comprising: (A) from about 50% to about 95% of biodegradable cationic fabric softening compound; (B) from about 0.01% to about 15% of an enduring perfume composition which has at least about 70% of components with a ClogP≧3.0 and a boiling point of≧250° C.; ClogP being the calculated octanol/water partitioning coefficient (P) expressed as the logarithm to the base 10, logP; (C) optionally, from 0% to about 30% of dispersibility improver; and (D) optionally, from 0% to about 15% of pH modifier.

Claim 34

A solid particulate composition comprising: (A) from about 50% to about 95% of biodegradable cationic fabric softening compound; (B) from about 0.01% to about 15% of an enduring perfume composition which has at least about 70% of components with a ClogP≧3.0 and a boiling point of≧250° C.; ClogP being the calculated octanol/water partitioning coefficient (P) expressed as the logarithm to the base 10, logP; (C) optionally, from 0% to about 30% of dispersibility improver; and (D) optionally, from 0% to about 15% of pH modifier.

Claim 35

The composition of claim 32 wherein the composition comprises: (A) from about 60% to about 90% of biodegradable cationic, diester, quaternary ammonium fabric softening compound; (B) from about 0.05% to about 8% of an enduring perfume composition; (C) from 3% to about 15% of dispersibility modifier; and (D) optionally, from 0% to about 10% of pH modifier.

Claim 36

The composition of claim 32 wherein said enduring perfume composition contains at least 70% of materials selected from the group consisting of: Allyl cyclohexane propionate; Ambrettolide; Amyl benzoate; Amyl cinnamate; Amyl cinnamic aldehyde; Amyl cinnamic aldehyde dimethyl acetal; iso-Amyl salicylate; Hydroxycitronellal-methylanthranilate; Benzophenone; Benzyl salicylate; para-tert-Butyl cyclohexyl acetate; iso-Butyl quinoline; beta-Caryophyllene; Cadinene; Cedrol; Cedryl acetate; Cedryl formate; Cinnamyl cinnamate; Cyclohexyl salicylate; Cyclamen aldehyde; Dihydro isojasmonate; Diphenyl methane; Diphenyl oxide; Dodecalactone; 1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)-ethanone; Ethylene brassylate; Ethylmethyl phenyl glycidate; Ethyl undecylenate; 15-Hydroxypentadecanoic acid, lactone; 1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma-2-benzopyran; Geranyl anthranilate; Geranyl phenyl acetate; Hexadecanolide; Hexenyl salicylate; Hexyl cinnamic aldehyde; Hexyl salicylate; alpha-Irone; para-tertiary-Butyl-alpha-methyl hydrocinnamic aldehyde; Linalyl benzoate; 2-Methoxy naphthalene; Methyl dihydrojasmone; gamma-n-Methyl ionone; Musk indanone; Musk ketone; Musk tibetine; Myristicin; Oxahexadecanolide-10; Oxahexadecanolide-11; Patchouli alcohol; 5-Acetyl-1,1,2,3,3,6-hexamethyl indan; Phenyl ethyl benzoate; Phenylethylphenylacetate; Phenyl heptanol; Phenyl hexanol; alpha-Santalol; delta-Undecalactone; gamma-Undecalactone; Vetiveryl acetate; yara-yara; Ylangene; and mixtures thereof.