← Back to Patent Explorer
US5494488A Expired / Lapsed US ⏱️ 0.0 years remaining

Detergent composition and method of use with surfactant, silicate, and polycarboxylate

Assignee: Evonik Operations GmbH
•
Filing: 1994-02-04
•
Granted: 1996-02-27
•
Expires: 2014-02-04
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A detergent composition with improved dirt-suspending power, method for its production and use of a suitable polycarboxylate for this purpose. The novel detergent contains, in addition to the customary components such as surfactant, calcium-binding silicate, etc., at least 1% by weight of a polycarboxylate with the schematic structure (X, Y, Z) in which X stands for ##STR1## Y for ##STR2## and Z for --(F).sub.q --. These carboxylates can be produced from acrolein and optionally one or several comonomers by means of oxidizing radical donors without saponifying conditions and/or without subsequent Cannizzaro reaction. The novel detergents exhibits improvements over traditionally used co-builders in all essential detergent qualities. The carboxylates may be used in detergents, fine-fabric detergents, color detergents, liquid detergents and compact detergents.

Inventors

  • 👤 Detlef Arnoldi
  • 👤 Wolfgang Leonhardt
  • 👤 Beata-Maria Lortz
  • 👤 Maurizio Ragnetti

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 09:05
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/37; C11D3/3746; C11D3/3757; C11D3/3761; C11D3/02; C11D3/12; C11D3/124; C11D3/1246; C11D3/128

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 211 words
A detergent composition containing: ______________________________________ Surfactant 5-40% by weight Calcium-binding silicate 5-50% by weight Polycarboxylate 1-20% by weight Other silicate 0-30% by weight Carbonate 0-30% by weight Organic complexing agent 0-10% by weight Phosphate 0-30% by weight Hydroxycarboxylic acid 0-20% by weight Bleaching agent 0-30% by weight Bleaching-agent activator 0-10% by weight Optical brightener 0-5% by weight Enzyme 0-30% by weight Greying inhibiter 0-5% by weight Defoamer 0-8% by weight Fillers 0-40% by weight ______________________________________ with at least 1% by weight of the composition being a polycarboxylate having an average molecular weight of between 500 and 500,000 with the structure (X, Y, Z) in which X stands for ##STR5## Y stands for ##STR6## and Z for --(F).sub.q --, in which A=H, OH, C 1-6 alkyl, CH 2 CO(DECO) r-1 OM; B=H, OH, C 1-6 alkyl, COOM D=O, NH E=C 1-6 alkyl F=a copolymerizable monomer; M=H, alkali metal or alkaline-earth metal, ammonium, substituted ammonium or --(CH 2 --CH 2 --O) 2-4 M 1 wherein M 1 is allowed to have the meaning of M except (CH 2 --CH 2 --O) 2-4 M 1 ; r=1-5; and m=0"99.5 molar % n=0.5-100 molar % q=0-99.5 molar % where m+n+q=100 molar % and said Y is at least about 1% by weight of said polycarboxylate.
Claim 2
Dependent Claim 211 words
A detergent composition containing: ______________________________________ Surfactant 5-40% by weight Calcium-binding silicate 5-50% by weight Polycarboxylate 1-20% by weight Other silicate 0-30% by weight Carbonate 0-30% by weight Organic complexing agent 0-10% by weight Phosphate 0-30% by weight Hydroxycarboxylic acid 0-20% by weight Bleaching agent 0-30% by weight Bleaching-agent activator 0-10% by weight Optical brightener 0-5% by weight Enzyme 0-30% by weight Greying inhibiter 0-5% by weight Defoamer 0-8% by weight Fillers 0-40% by weight ______________________________________ with at least 1% by weight of the composition being a polycarboxylate having an average molecular weight of between 500 and 500,000 with the structure (X, Y, Z) in which X stands for ##STR5## Y stands for ##STR6## and Z for --(F).sub.q --, in which A=H, OH, C 1-6 alkyl, CH 2 CO(DECO) r-1 OM; B=H, OH, C 1-6 alkyl, COOM D=O, NH E=C 1-6 alkyl F=a copolymerizable monomer; M=H, alkali metal or alkaline-earth metal, ammonium, substituted ammonium or --(CH 2 --CH 2 --O) 2-4 M 1 wherein M 1 is allowed to have the meaning of M except (CH 2 --CH 2 --O) 2-4 M 1 ; r=1-5; and m=0"99.5 molar % n=0.5-100 molar % q=0-99.5 molar % where m+n+q=100 molar % and said Y is at least about 1% by weight of said polycarboxylate.
Claim 3
Dependent Claim 24 words
The detergent composition according to claim 1, formulated as a compact detergent, and containing: Polycarboxylate 2-8% by weight Bleaching agent activator 2-8% by weight.
Claim 4
Dependent Claim 56 words
The detergent composition according to claim 1 formulated as a liquid detergent containing: ______________________________________ Anionic surfactant 5-15% by weight Non-ionic surfactant 10-20% by weight Calcium-binding silicate 10-25% by weight Polycarboxylate 1-5% by weight Bleaching agent 0% by weight Bleaching-agent activator 0% by weight Co-builder 0-8% by weight Solubilizer 0-30% by weight Water 0-50% by weight. ______________________________________
Claim 5
Dependent Claim 48 words
The detergent composition according to claim 1 formulated as a fine-fabric detergent containing: ______________________________________ Anionic surfactants 5-15% by weight Non-ionic surfactants 1-10% by weight Calcium-binding silicate 10-50% by weight Polycarboxylate 1-5% by weight Bleaching agent 0% by weight Bleaching-agent activator 0% by weight Carbonate 0-20% by weight. ______________________________________
Claim 6
Dependent Claim 22 words
A method of laundering textile materials which comprises washing the textile materials with a detergent composition as set forth in claim 1.
Claim 7
Dependent Claim 18 words
The detergent composition according to claim 1 in which the polycarboxylate is mixed with all of the components.
Claim 8
Dependent Claim 30 words
The detergent composition according to claim 1 in which the polycarboxylate is mixed with at least several of the components in the presence of water and the composition is dried.
Claim 9
Dependent Claim 86 words
The detergent composition according to claim 1 which contains at least one of the following components: ______________________________________ Surfactant 7-30% by weight Polycarboxylate 2-10% by weight Further silicate 3-15% by weight Carbonate 3-15% by weight Organic complexing agent 0.5-5% by weight Phosphonate 0.1-1% by weight Phosphate 0-5% by weight Hydroxycarboxylic acid 2-10% by weight Bleaching agent 10-25% by weight Bleaching-agent activator 2-8% by weight Optical brightener 0.1-0.3% by weight Enzyme 0.3-1% by weight Greying inhibitor 0.5-1.5% by weight Defoamer 0-3.5% by weight Fillers 0-20% by weight. ______________________________________
Claim 10
Dependent Claim 25 words
The detergent composition of claim 8 in which the amount of surfactant is 10-20% by weight and the amount of phosphate is 0-1% by weight.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-02-26 1999-08-28 2000-02-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-02-26 2003-08-28 2004-02-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-02-26 2007-08-28 2008-02-27 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag