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US5489501A Expired / Lapsed US ⏱️ 0.0 years remaining

Recording composition

Assignee: Ricoh Co Ltd
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Filing: 1994-10-18
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Granted: 1996-02-06
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Expires: 2014-10-18
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Abstract

Abstract A recording material contains at least two coordination compounds which react to produce at least one newly produced coordination compound with the occurrence of visual changes in the recording material, which visual changes are utilized for recording.

Inventors

  • 👤 Masafumi Torii
  • 👤 Kunio Hayakawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 18:55
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/30; B41M5/32; Y; Y10; Y10S; Y10S430/00; Y10S430/165

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 299 words
A composition for use in a recording material having a visual appearance comprising a substrate and one or more recording layers, wherein said composition is contained in said one or more recording layers, said composition comprising at least two coordination compounds (A) and (B) which react to produce at least one newly produced coordination compound with the occurrence of visual changes in said recording material, which visual changes are utilized for recording, said composition also comprising at least one additional compound, and wherein said coordination compound (A) comprises (1) a fatty acid, an aromatic carboxylic acid, a heterocyclic carboxylic acid, an organic phosphoric acid, or an organic sulfur acid and (2) one metal capable of forming a colored coordination compound with said coordination compound (B), alone or with an additional metal, and wherein said coordination compound (B) has a (1) center metal and (2) a ligand selected from the group consisting of nitrogen ligands, oxygen ligands, oxygen-nitrogen ligands and sulfur ligands, and wherein said at least one additional compound is selected from the group consisting of (a) a sulfonic acid ester with a thermal decomposition temperature of 60° C. or more, (b) a water-releasing material which is a compound of the formula (I) or (II): M.sup.1 M.sup.3 (SO.sub.4).sub.2.12H.sub.2 O (I) M.sup.1.sub.2 SO.sub.4.M.sup.3.sub.2 (SO.sub.4).sub.3.24H.sub.2 O(II) wherein M 1 is a monovalent metal, ammonium, or alkyl ammonium, and M 1 is a trivalent metal, and (c) a compound comprising a metal which is capable of forming a coordination compound having a stability Kr which satisfies formula (III) when said at least two coordination compounds have stabilities K 1 to K n , and said at least one newly produced coordination compound has a stability Kz when said newly produced coordination compound is produced by complex formation: K.sub.1 to K.sub.n ≦Kr<Kz (III).
Claim 2
Dependent Claim 299 words
A composition for use in a recording material having a visual appearance comprising a substrate and one or more recording layers, wherein said composition is contained in said one or more recording layers, said composition comprising at least two coordination compounds (A) and (B) which react to produce at least one newly produced coordination compound with the occurrence of visual changes in said recording material, which visual changes are utilized for recording, said composition also comprising at least one additional compound, and wherein said coordination compound (A) comprises (1) a fatty acid, an aromatic carboxylic acid, a heterocyclic carboxylic acid, an organic phosphoric acid, or an organic sulfur acid and (2) one metal capable of forming a colored coordination compound with said coordination compound (B), alone or with an additional metal, and wherein said coordination compound (B) has a (1) center metal and (2) a ligand selected from the group consisting of nitrogen ligands, oxygen ligands, oxygen-nitrogen ligands and sulfur ligands, and wherein said at least one additional compound is selected from the group consisting of (a) a sulfonic acid ester with a thermal decomposition temperature of 60° C. or more, (b) a water-releasing material which is a compound of the formula (I) or (II): M.sup.1 M.sup.3 (SO.sub.4).sub.2.12H.sub.2 O (I) M.sup.1.sub.2 SO.sub.4.M.sup.3.sub.2 (SO.sub.4).sub.3.24H.sub.2 O(II) wherein M 1 is a monovalent metal, ammonium, or alkyl ammonium, and M 1 is a trivalent metal, and (c) a compound comprising a metal which is capable of forming a coordination compound having a stability Kr which satisfies formula (III) when said at least two coordination compounds have stabilities K 1 to K n , and said at least one newly produced coordination compound has a stability Kz when said newly produced coordination compound is produced by complex formation: K.sub.1 to K.sub.n ≦Kr<Kz (III).
Claim 3
Dependent Claim 27 words
The composition of claim 1 wherein said at least one additional compound is a sulfonic acid ester with a thermal decomposition temperature of 60° C. or more.
Claim 4
Dependent Claim 53 words
The composition of claim 1 wherein said at least one additional compound is a water-releasing material which is a compound of the formula (I) or (II): M.sup.1 M.sup.3 (SO.sub.4).sub.2.12H.sub.2 O (I) M.sup.1.sub.2 SO.sub.4.M.sup.3.sub.2 (SO.sub.4).sub.3.24H.sub.2 O(II) wherein M 1 is a monovalent metal, ammonium, or alkyl ammonium, and M 3 is a trivalent metal.
Claim 5
Dependent Claim 13 words
The composition of claim 3, further comprising pullulan, together with said water-releasing material.
Claim 6
Dependent Claim 78 words
The composition of claim 1 wherein said at least one additional compound is a compound comprising a metal which is capable of forming a coordination compound having a stability Kr which satisfies formula (III) when said at least two coordination compounds have stabilities K 1 to K n , and said at least one newly produced coordination compound has a stability Kz when said newly produced coordination compound is produced by complex formation: K.sub.1 to K.sub.n ≦Kr<Kz (III)
Claim 7
Dependent Claim 32 words
The composition of claim 1 wherein as said coordination compounds are contained a coordination compound with an 8-hydroxy-quinoline compound being contained as a ligand thereof, and a coordination compound comprising ferric ion.
Claim 8
Dependent Claim 37 words
The composition of claim 6, wherein said coordination compound with an 8-hydroxyquinoline, compound being contained as a ligand thereof is a coordination compound with a 8-hydroxyquinoline compound and an organic carboxylic acid being contained as ligands thereof.
Claim 9
Dependent Claim 22 words
The composition of claim 6, wherein said coordination compound with an 8-hydroxyquinoline compound being contained as a ligand thereof further comprises magnesium.
Claim 10
Dependent Claim 24 words
The composition of claim 7, wherein said coordination compound with at least an 8-hydroxyquinoline compound being contained as a ligand thereof further comprises magnesium.
Claim 11
Dependent Claim 21 words
The composition of claim 8, wherein said coordination compound having a stability Kr is an electrolyte compound comprising zinc or nickel.
Claim 12
Dependent Claim 20 words
The composition of 9, wherein said coordination compound having a stability Kr is an electrolyte compound comprising zinc or nickel.
Claim 13
Dependent Claim 20 words
The composition of 9, wherein said coordination compound having a stability Kr is an electrolyte compound comprising zinc or nickel.
Claim 14
Dependent Claim 20 words
The composition of claim 1, wherein one of said coordination compounds is an iron salt of an organic phosphoric acid.
Claim 15
Dependent Claim 19 words
The composition of claim 1, wherein one of said coordination compounds is an iron salt of a dicarboxylic acid.
Claim 16
Dependent Claim 10 words
The composition of claim 12, further comprising a dicarboxylic acid.

References Cited (Backward Citations)

US3157526A Cited
US3859111A Cited
US4602264A Cited
JPS63183875A Cited
US4829046A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-02-05 1999-08-07 2000-02-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-02-05 2003-08-07 2004-02-06 $3760.00 Window Closed / Lapsed
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