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US5476912A Expired / Lapsed US ⏱️ 0.0 years remaining

Silicone-modified acrylic copolymer and adhesive thereof

Assignee: Tokuyama Corp
•
Filing: 1994-06-30
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Granted: 1995-12-19
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Expires: 2014-06-30
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Abstract

Abstract An adhesive which exhibits excellent adhesiveness and is capable of firmly adhering an acrylic resin and a silicone rubber together at a temperature of as low as about 20 DEG to 30 DEG C. requiring a time of as short as several minutes. The adhesive is obtained by dissolving in a solvent a novel silicone-modified acrylic copolymer having a polyorganosiloxane with an SiH reaction point on the side chain.

Inventors

  • 👤 Yasuhiro Hosoi
  • 👤 Osamu Iwamoto
  • 👤 Masataka Himeno

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-10 00:58
CPC Classifications
C; C08; C08G; C08G81/00; C08G81/02; C08G81/024; A; A61; A61K; A61K6/00; A61K6/30; A61K6/35; C08F; C08F8/00; C08F8/42

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 286 words
A silicone-modified acrylic copolymer comprising: I. a structural unit of the formula ##STR57## wherein R 1 is a hydrogen atom, a methyl group or an ethyl group, and R 3 is an alkyl group with 1 to 13 carbon atoms or an aryl group with 6 to 14 carbon atoms, II. a structural unit of the formula ##STR58## or of the formula ##STR59## wherein R 2 is a hydrogen atom, a methyl group or an ethyl group, each of R 4 is an alkyl group with 1 to 6 carbon atoms or an aryl group with 6 to 14 carbon atoms which may be the same or different, each of R 5 is a hydrogen atom, an alkyl group with 1 to 6 carbon atoms or an aryl group with 6 to 14 carbon atoms which may be the same or different, A is a divalent organic group with 2 to 20 carbon atoms which may have an ether bond or an ester bond in the main chain, and c and d are average recurring unit numbers, c being a number of 1 to 100 and d being a number of 0 to 100, and III. a structural unit of the formula ##STR60## wherein R 6 is a hydrogen atom, a methyl group or an ethyl group, and R 7 is an ethylenically unsaturated hydrocarbon group with 2 to 20 carbon atoms which may have an ether bond or an ester bond in the main chain, wherein the unit (I), the unit (II) and the unit (III) are contained at ratios in mole % of (I)=10 to 99.9, (II)=90 to 0.1, and (III)=0 to 89.9, and have weight average molecular weights of from 5,000 to 1,000,000.
Claim 2
Dependent Claim 286 words
A silicone-modified acrylic copolymer comprising: I. a structural unit of the formula ##STR57## wherein R 1 is a hydrogen atom, a methyl group or an ethyl group, and R 3 is an alkyl group with 1 to 13 carbon atoms or an aryl group with 6 to 14 carbon atoms, II. a structural unit of the formula ##STR58## or of the formula ##STR59## wherein R 2 is a hydrogen atom, a methyl group or an ethyl group, each of R 4 is an alkyl group with 1 to 6 carbon atoms or an aryl group with 6 to 14 carbon atoms which may be the same or different, each of R 5 is a hydrogen atom, an alkyl group with 1 to 6 carbon atoms or an aryl group with 6 to 14 carbon atoms which may be the same or different, A is a divalent organic group with 2 to 20 carbon atoms which may have an ether bond or an ester bond in the main chain, and c and d are average recurring unit numbers, c being a number of 1 to 100 and d being a number of 0 to 100, and III. a structural unit of the formula ##STR60## wherein R 6 is a hydrogen atom, a methyl group or an ethyl group, and R 7 is an ethylenically unsaturated hydrocarbon group with 2 to 20 carbon atoms which may have an ether bond or an ester bond in the main chain, wherein the unit (I), the unit (II) and the unit (III) are contained at ratios in mole % of (I)=10 to 99.9, (II)=90 to 0.1, and (III)=0 to 89.9, and have weight average molecular weights of from 5,000 to 1,000,000.
Claim 3
Dependent Claim 30 words
A silicone-modified acrylic copolymer according to claim 1, wherein R 1 , R 2 and R 6 in the structural units (1) to (3) are hydrogen atoms or methyl groups.
Claim 4
Dependent Claim 26 words
A silicone-modified acrylic copolymer according to claim 1, wherein R 3 in the structural unit (1) is an alkyl group with 1 to 3 carbon atoms.
Claim 5
Dependent Claim 26 words
A silicone-modified acrylic copolymer according to claim 1, wherein R 4 in the structural unit (2a) or (2b) is a methyl group or a phenyl group.
Claim 6
Dependent Claim 29 words
A silicone-modified acrylic copolymer according to claim 1, wherein R 5 in the structural unit (2a) or (2b) is a hydrogen atom, a methyl group or a phenyl group.
Claim 7
Dependent Claim 28 words
A silicone-modified acrylic copolymer according to claim 1, wherein R 7 in the structural unit (3) is an ethylenically unsaturated hydrocarbon group with 3 to 10 carbon atoms.
Claim 8
Dependent Claim 31 words
A silicone-modified acrylic copolymer according to claim 1, wherein the group A in the structural unit (2a) or (2b) is a divalent saturated hydrocarbon group with 3 to 10 carbon atoms.
Claim 9
Dependent Claim 31 words
A silicone-modified acrylic copolymer according to claim 1, wherein said silicone-modified acrylic copolymer has three or more SiH groups per a unit of a polyorganosiloxane group in the silicone-modified acrylic copolymer.
Claim 10
Dependent Claim 21 words
An adhesive obtained by dissolving the silicone-modified acrylic copolymer of claim 1 in a solvent in which said copolymer is soluble.
Claim 11
Dependent Claim 15 words
An adhesive according to claim 9, wherein said soluble solvent is methylene chloride or toluene.
Claim 12
Dependent Claim 24 words
An adhesive according to claim 9, wherein the adhesive contains the silicone-modified acrylic copolymer in an amount of from 0.1 to 20% by weight.
Claim 13
Dependent Claim 42 words
The silicone-modified acrylic copolymer of claim 1 wherein the unit (I), the unit (II) and the unit (III) are present at ratios of (I) 50 to 99.9 mole %, (II) 50 to 0.1 mole %, and (III) 0 to 49.9 mole %.
Claim 14
Dependent Claim 15 words
The silicone-modified acrylic copolymer of claim 12 wherein structural units of formula (3) are present.
Claim 15
Dependent Claim 15 words
The silicone-modified acrylic copolymer of claim 12 wherein structural units of formula (3) are absent.
Claim 16
Dependent Claim 23 words
The silicone-modified acrylic copolymer of claim 1 wherein in the formula (2a) and (2b) c and d satisfy the relationships 10≦c+d≦100 and 0≦d/c≦10.
Claim 17
Dependent Claim 100 words
A silicone-modified acrylic copolymer according to claim 2, wherein R 3 in the structural unit (1) is an alkyl group with 1 to 3 carbon atoms, R 4 in the structural units (2a) and (2b) is a methyl or phenyl group, R 5 in the structural units (2a) and (2b) is a hydrogen atom, a methyl group or a phenyl group, R 7 in the structural unit (3) is an ethylenically unsaturated hydrocarbon group with 3 to 10 carbon atoms, and A in structural units (2a) and (2b) is a divalent saturated hydrocarbon group with 3 to 10 carbon atoms.
Claim 18
Dependent Claim 22 words
The silicone-modified acrylic copolymer of claim 16 which has at least 3 SiH groups per unit of polyorganosiloxane group in the copolymer.
Claim 19
Dependent Claim 15 words
The silicone-modified acrylic copolymer of claim 16 wherein structural units of formula (3) are present.
Claim 20
Dependent Claim 23 words
The adhesive according to claim 10, wherein the silicone-modified acrylic copolymer is present in an amount of from 0.1 to 20% by weight.

References Cited (Backward Citations)

EP0049155A2 Cited
EP0205327A1 Cited
US4831080A Cited
US5229435A Cited
DE4131089A1 Cited
WO1992007916A1 Cited
US5288827A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-12-18 1999-06-19 1999-12-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-12-18 2003-06-19 2003-12-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-12-18 2007-06-19 2007-12-19 $7700.00 Window Closed / Lapsed

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