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US5472630A Expired / Lapsed US ⏱️ 0.0 years remaining

Low phosphorous, low etch cleaner and method

Assignee: Veolia WTS USA Inc
•
Filing: 1994-03-24
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Granted: 1995-12-05
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Expires: 2014-03-24
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Abstract

Abstract Compositions and methods for cleaning and etching an aluminum surface with a low etch, low phosphate alkaline cleaner solution are disclosed. The preferred composition employs a stable combination of an alkali metal hydroxide, gluconic acid, a detergent source, an aluminum sequestrant, an oil emulsifier, a defoamer, and a hydrotrope.

Inventors

  • 👤 Jiangbo Ouyang
  • 👤 Edward A. Rodzewich
  • 👤 William L. Harpel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 03:16
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/66; C11D1/83; C11D3/00; C11D3/16; C11D3/20; C11D3/2075; C11D3/2086; C11D3/37; C11D3/3746; C11D3/3757; C11D3/3765; C11D7/00; C11D7/02; C11D7/04; C11D7/06; C23; C23G; C23G1/00; C23G1/14; C23G1/22; C11D1/02; C11D1/34; C11D1/345; C11D1/72

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 121 words
A method for cleaning and etching an aluminum surface, said method comprising applying to an aluminum surface a low aluminum etch, low phosphate-containing alkaline cleaning solution comprising, by volume percent, 5 to 50% alkali metal hydroxide and 0.5 to 10% gluconic acid, the improvement further comprising a stable combination of 0.2 to 5% of a detergent selected from the group consisting of trimethylnonanol polyethyleneglycol ether with 6 moles ethylene oxide, 0.5 to 10% of an aluminum sequestrant selected from the group consisting of poly(acrylic) acid, 0.5 to 10% of an oil emulsifier selected from the group consisting of potassium C 5 to C 18 alkoxy phenoxy carboxy phosphate, 0.05 to 5% of a defoamer, and 0.4 to 20% of a hydrotrope.
Claim 2
Independent Claim 121 words
A method for cleaning and etching an aluminum surface, said method comprising applying to an aluminum surface a low aluminum etch, low phosphate-containing alkaline cleaning solution comprising, by volume percent, 5 to 50% alkali metal hydroxide and 0.5 to 10% gluconic acid, the improvement further comprising a stable combination of 0.2 to 5% of a detergent selected from the group consisting of trimethylnonanol polyethyleneglycol ether with 6 moles ethylene oxide, 0.5 to 10% of an aluminum sequestrant selected from the group consisting of poly(acrylic) acid, 0.5 to 10% of an oil emulsifier selected from the group consisting of potassium C 5 to C 18 alkoxy phenoxy carboxy phosphate, 0.05 to 5% of a defoamer, and 0.4 to 20% of a hydrotrope.
Claim 3
Dependent Claim 15 words
The method as claimed in claim 1 wherein said alkali metal hydroxide is potassium hydroxide.
Claim 4
Dependent Claim 41 words
The method as claimed in claim 1 wherein said defoamer is a reverse ethyleneoxide-propylene oxide block copolymer of the general structure (R'O)--(RO) n --(R'O) where R is an ethylene group, R' is a propylene group and n is 5 or greater.
Claim 5
Dependent Claim 13 words
The method as claimed in claim 1 wherein said hydrotrope is sodium alkanoate.
Claim 6
Dependent Claim 16 words
The method as claimed in claim 1 wherein said solution is sprayed onto the aluminum surface.
Claim 7
Dependent Claim 27 words
The method as claimed in claim 1 wherein said solution is sprayed onto the aluminum surfaces at a temperature of about 100° F. to about 150° F.
Claim 8
Dependent Claim 19 words
The method as claimed in claim 1 wherein said solution is diluted to about 1 to 6% in water.

References Cited (Backward Citations)

GB1226314A Cited
BE745424A Cited
US4085060A Cited
JPS5345309A Cited
US4477290A Cited
JPS60260698A Cited
US4762638A Cited
US5342450A Cited
US5114607A Cited
US5110494A Cited
US5200114A Cited
JPH05320962A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-12-04 1999-06-05 1999-12-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-12-04 2003-06-05 2003-12-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-12-04 2007-06-05 2007-12-05 $7700.00 Window Closed / Lapsed

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