US5467635A
Expired / Lapsed
US
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Gas chromatograph
Assignee: Shimadzu Corp
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Filing: 1994-12-12
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Granted: 1995-11-21
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Expires: 2014-12-12
Abstract
Abstract A target pressure is calculated by a fluid dynamic theory using a length of the column, an inner diameter of the column and the temperature of the column so that the linear velocity of the gas flowing through the column is at a preset pre-determined value at which the HETP (height equivalent to a theoretical plate) value, as calculated from chemical kinematic theory, is the minimum and the resolution of the column is the highest. Then the pressure of the gas at the entrance of the column of a chromatograph is maintained at the calculated target pressure while the temperature of the column is raised to reduce the analyzing time.
Inventors
- 👤 Kazuya Nakagawa
- 👤 Toyoaki Fukushima
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 03:54
CPC Classifications
G; G01; G01N; G01N30/00; G01N30/02; G01N30/26; G01N30/28; G01N30/32; G01N2030/022; G01N2030/025; G01N30/04; G01N30/06; G01N30/12; G01N2030/126; G01N2030/127; G01N30/30; G01N2030/3007; G01N2030/324
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
132 words
A gas chromatograph comprising: a pressure regulator under variable control via electrical input signals for regulating a pressure of a gas at an entrance of a column of the gas chromatograph; a pressure sensor for detecting a pressure of the gas at the entrance of the column; calculating means for calculating a target pressure of the gas at the entrance of the column from a length of the column, an inner diameter of the column and a temperature of the column, the target pressure being such a pressure that a linear velocity of the gas flowing, through the column is at a preset pre-determined value; and a controller with electrical output signals for controlling the pressure regulator so that the pressure detected by the pressure sensor is maintained at the target pressure.
Claim 2
Dependent Claim
132 words
A gas chromatograph comprising: a pressure regulator under variable control via electrical input signals for regulating a pressure of a gas at an entrance of a column of the gas chromatograph; a pressure sensor for detecting a pressure of the gas at the entrance of the column; calculating means for calculating a target pressure of the gas at the entrance of the column from a length of the column, an inner diameter of the column and a temperature of the column, the target pressure being such a pressure that a linear velocity of the gas flowing, through the column is at a preset pre-determined value; and a controller with electrical output signals for controlling the pressure regulator so that the pressure detected by the pressure sensor is maintained at the target pressure.
Claim 3
Dependent Claim
36 words
The gas chromatograph according to claim 1, wherein the gas chromatograph further comprises temperature controlling means for controlling the temperature of the column according to a preset temperature program that serves to reduce the analyzing time.
Claim 4
Dependent Claim
42 words
The gas chromatograph according to claim 2, wherein the preset pre-determined value of the linear velocity is a value at which a HETP (height equivalent to a theoretical plate) value is the minimum where said HETP value corresponds to maximum chromatographic resolution.
Claim 5
Dependent Claim
103 words
The gas chromatograph according to claim 3, wherein the target pressure P is calculated by the following formulae: P=(L/D.sup.2)·μ·{a·(L/D.sup.2)·μ.multidot.v.sub.m +b}·v.sub.m μ=α·{(T.sub.20 +β)/(T+β)}·(T/T.sub.20).sup.3/2 where L is the length of the column, D is the inner diameter of the column, T is the absolute temperature of the column, is the viscosity of gas flowing thru the column, a and b and α and β are constants to be determined for a particular column and gas, T 20 is 293 degrees Kelvin scale, and v m is the preset pre-determined value of the linear velocity of the gas at which the HETP value is the minimum.
Claim 6
Dependent Claim
50 words
The gas chromatograph according to claim 4, wherein the values of μ at a plurality of temperature values T of the column and for a plurality of gases are calculated and stored in a memory beforehand, and an appropriate value of μ is retrieved from the memory in an analysis.
Claim 7
Dependent Claim
96 words
The gas chromatograph according to claim 3, wherein the target pressure P is calculated by the following formulae: P=(L/D.sup.2)·μ·{a·(L/D.sup.2)·μ.multidot.v.sub.m +b}·v.sub.m μ=γ·T+δ where L is the length of the column, D is the inner diameter of the column, Tμ is the viscosity of gas flowing thru the column, a and b and γ and δ are constants to be determined for a particular column and gas, v 111 is the preset pre-determined value of the linear velocity of the gas at which the HETP value is the minimum, and T is the absolute temperature of the column.
Claim 8
Independent Claim
90 words
A method of performing an analysis using a chromatograph including a column, the method comprising the steps of: calculating a target pressure of a gas at an entrance of the column from a length of the column, an inner diameter of the column and a temperature of the column, the target pressure being such a pressure that a linear velocity of the gas flowing through the column is at a preset pre-determined value; and controlling the pressure at the entrance of the column to be maintained at the target pressure.
Claim 9
Independent Claim
90 words
A method of performing an analysis using a chromatograph including a column, the method comprising the steps of: calculating a target pressure of a gas at an entrance of the column from a length of the column, an inner diameter of the column and a temperature of the column, the target pressure being such a pressure that a linear velocity of the gas flowing through the column is at a preset pre-determined value; and controlling the pressure at the entrance of the column to be maintained at the target pressure.
Claim 10
Dependent Claim
30 words
The gas chromatographic analyzing method according to claim 7, wherein a temperature of the column is controlled according to a preset temperature program that serves to reduce the analyzing time.
Claim 11
Dependent Claim
44 words
The gas chromatographic analyzing method according to claim 8, wherein the preset pre-determined value of the linear velocity is a value at which a HETP (height equivalent to a theoretical plate) value is the minimum where said HETP value corresponds to maximum chromatographic resolution.
Claim 12
Dependent Claim
105 words
The gas chromatographic analyzing method according to claim 9, wherein the target pressure P is calculated by the following formulae: P=(L/D.sup.2)·μ·{a·(L/D.sup.2)·μ.multidot.v.sub.m +b}·v.sub.m μ=α·{(T.sub.20 +β)/(T+β)}·(T/T.sub.20).sup.3/2 where L is the length of the column, D is the inner diameter of the column, T is the absolute temperature of the column, μ is the viscosity of gas flowing thru the column, a and b and α and βare constants to be determined for a particular column and gas T 20 is 293 degrees Kelvin scale, and v m is the preset pre-determined value of the linear velocity of the gas at which the HETP value is the minimum.
Claim 13
Dependent Claim
52 words
The gas chromatographic analyzing method according to claim 10, wherein the values of μ at a plurality of temperature values T of the column and for a plurality of gases are calculated and stored in a memory beforehand, and an appropriate value of μ is retrieved from the memory in an analysis.
Claim 14
Dependent Claim
98 words
The gas chromatographic analyzing method according to claim 9, wherein the target pressure P is calculated by the following formulae: P=(L/D.sup.2)·μ·{a·(L/D.sup.2)·μ.multidot.v.sub.m +b}·v.sub.m μ=γ·T+δ where L is the length of the column, D is the inner diameter of the column, μ is the viscosity of gas flowing thru the column, a and b and γ and δ are constants to be determined for a particular column and gas, v 111 is the preset pre-determined value of the linear velocity of the gas at which the HETP value is the minimum, and T is the absolute temperature of the column.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1998-11-20 | 1999-05-22 | 1999-11-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2002-11-20 | 2003-05-22 | 2003-11-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2006-11-20 | 2007-05-22 | 2007-11-21 | $7700.00 | Window Closed / Lapsed |