US5466736A
Expired / Lapsed
US
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Electrostatic spray paint
Assignee: Morgan Advanced Materials PLC
•
Filing: 1992-10-09
•
Granted: 1995-11-14
•
Expires: 2012-10-09
Abstract
Abstract PCT No. PCT/GB92/01839 Sec. 371 Date Jun. 16, 1994 Sec. 102(e) Date Jun. 16, 1994 PCT Filed Oct. 9, 1992 PCT Pub. No. WO93/07226 PCT Pub. Date Apr. 15, 1993.Electrostatic spray paint formulations of alkyds, acrylics, nitrocellulose or polyurethanes having defined viscosity values and film forming solids content.
Inventors
- 👤 Mark J. Spowage
- 👤 Julia P. Grayson
- 👤 Alan C. Outhwaite
- 👤 Nighat Ahmed
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 02:27
CPC Classifications
C; C09; C09D; C09D167/00; C09D167/08; C09D175/00; C09D175/04
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
97 words
A paint formulation of pigment, resin and solvent, for electrostatic spraying, based on one of the following resins and having a film-forming solids content, according to the base resin, as follows: ______________________________________
Formulation Solids
Resin (by weight)
______________________________________
alkyd 55% to 90%
acrylic 20% to 40%
nitrocellulose
17.5% to 25%
polyurethane 50% to 70%
______________________________________ together with viscosity/resistivity values which in a rectangular plot of resistivity (ohm cm×10 6 ) and viscosity (P) fall within the rectilinear-sided operating envelope defined by the points x/y 0.25×10 6 /0.1, 2×10 6 /8, 32×10 6 /4 and 35×10 6 /0.1.
Claim 2
Dependent Claim
97 words
A paint formulation of pigment, resin and solvent, for electrostatic spraying, based on one of the following resins and having a film-forming solids content, according to the base resin, as follows: ______________________________________
Formulation Solids
Resin (by weight)
______________________________________
alkyd 55% to 90%
acrylic 20% to 40%
nitrocellulose
17.5% to 25%
polyurethane 50% to 70%
______________________________________ together with viscosity/resistivity values which in a rectangular plot of resistivity (ohm cm×10 6 ) and viscosity (P) fall within the rectilinear-sided operating envelope defined by the points x/y 0.25×10 6 /0.1, 2×10 6 /8, 32×10 6 /4 and 35×10 6 /0.1.
Claim 3
Dependent Claim
34 words
The formulation of claim 1 with the following relation of the resins and the solids content: ______________________________________
alkyd 55 to 75%
acrylic 25 to 35%
nitrocellulose 17.5 to 22.5%
polyurethane 50 to 60%
______________________________________
Claim 4
Dependent Claim
29 words
The formulation of claim 1 when for use in electrostatic spraying, at from 1 to 15 ml/min, and with resulting gloss of over 70, as defined by ASTM D523,60°.
Claim 5
Dependent Claim
22 words
The formulation as claimed in claim 3 wherein the application rate is 1.5 to 10 g/s/cm 2 ×10 -5 dry paint film.
Claim 6
Dependent Claim
22 words
A method of spray painting wherein electrostatic spraying is employed and a paint formulation as set out in claim 1 is used.
Claim 7
Dependent Claim
33 words
The formulation of claim 1 wherein the viscosity/resistivity values fall within a rectilinear-sided operating envelope defined by the points x/y 0.25×10 6 /0.25, 2×10 6 /8, 32×10 6 /0.25 and 35×10 6 /0.25.
Claim 8
Dependent Claim
22 words
A formulation as claimed in claim 4 wherein the application rate is 1.7 to 8.4 g/s/cm 2 ×10 -5 dry paint film.
Claim 9
Independent Claim
138 words
A method of spray painting comprising the steps of forming a spray cloud by the application of a high electric potential to a liquid paint formulation at a paint-supply head thereby breaking said paint up into charged droplets by electrostatic forces, and spraying the charged droplets whereby the droplets are attracted to a work to be painted to form a film, the liquid paint formulation having a film-forming solids content by weight, according to the resin system, selected from: ______________________________________
alkyd 55% to 90%
acrylic 20% to 40%
nitrocellulose
17.5% to 25%
polyurethane 50% to 70%
______________________________________ and viscosity/resistivity values which in a rectangular plot of resistivity (ohm cm×10 6 ) and viscosity (P) fall within the rectilinear-sided operating envelope defined by the points x/y 0.25×10 6 /0.1, 2×10 6 /8, 32×10 6 /4 and 35×10 6 /0.1.
Claim 10
Independent Claim
138 words
A method of spray painting comprising the steps of forming a spray cloud by the application of a high electric potential to a liquid paint formulation at a paint-supply head thereby breaking said paint up into charged droplets by electrostatic forces, and spraying the charged droplets whereby the droplets are attracted to a work to be painted to form a film, the liquid paint formulation having a film-forming solids content by weight, according to the resin system, selected from: ______________________________________
alkyd 55% to 90%
acrylic 20% to 40%
nitrocellulose
17.5% to 25%
polyurethane 50% to 70%
______________________________________ and viscosity/resistivity values which in a rectangular plot of resistivity (ohm cm×10 6 ) and viscosity (P) fall within the rectilinear-sided operating envelope defined by the points x/y 0.25×10 6 /0.1, 2×10 6 /8, 32×10 6 /4 and 35×10 6 /0.1.
Claim 11
Dependent Claim
29 words
The method of claim 8 wherein the film-forming solid contents are: ______________________________________
alkyd 55% to 75%
acrylic 20% to 35%
nitrocellulose
17.5% to 22.5%
polyurethane 50% to 60%.
______________________________________
Claim 12
Dependent Claim
28 words
The method of claim 8 wherein the liquid paint formulation has x/y viscosity/resistivity values of 0.25×10 6 /0.25, 2×10 6 /8, 32×10 6 /4 and 35×10 6 /0.25.
Claim 13
Dependent Claim
33 words
The method of claim 8 wherein the spraying step is carried out at from 1 to 15 ml/min, resulting in a dry paint film gloss of over 70 as defined by ASTM D523,60.
Claim 14
Dependent Claim
30 words
The method of claim 11 wherein the spraying step is carried out at from 1 to 6 ml/min and the gloss of the resultant dry paint film is over 80.
Claim 15
Dependent Claim
20 words
The method of claim 8 wherein the application rate is 1.5 to 10 g/s/cm 2 ×10 -5 dry paint film.
Claim 16
Dependent Claim
20 words
The method of claim 13 wherein the application rate is 1.7 to 8.4 g/s/cm 2 ×10 -5 dry paint film.
Claim 17
Dependent Claim
96 words
An electrostatically sprayable paint formulation of pigment, resin and solvent based on one of the following resins and having a film-forming solids content, according to the base resin, as follows: ______________________________________
Formulation Solids
Resin (by weight)
______________________________________
alkyd 55% to 90%
acrylic 20% to 40%
nitrocellulose
17.5% ot 25%
polyurethane 50% to 70%
______________________________________ together with viscosity/resistivity values which in a rectangular plot of resistivity (ohm cm×10 6 ) and viscosity (P) fall within the rectilinear-sided operating envelope defined by the points x/y 0.25×10 6 /0.1, 2×10 6 /8, 32×10 6 /4 and 35×10 6 /0.1.
Claim 18
Dependent Claim
96 words
An electrostatically sprayable paint formulation of pigment, resin and solvent based on one of the following resins and having a film-forming solids content, according to the base resin, as follows: ______________________________________
Formulation Solids
Resin (by weight)
______________________________________
alkyd 55% to 90%
acrylic 20% to 40%
nitrocellulose
17.5% ot 25%
polyurethane 50% to 70%
______________________________________ together with viscosity/resistivity values which in a rectangular plot of resistivity (ohm cm×10 6 ) and viscosity (P) fall within the rectilinear-sided operating envelope defined by the points x/y 0.25×10 6 /0.1, 2×10 6 /8, 32×10 6 /4 and 35×10 6 /0.1.
Claim 19
Dependent Claim
36 words
The electrically sprayable formulation of claim 15 with the following relation of the resins and the solids content: ______________________________________
alkyd 55% to 75%
acrylic 20% to 35%
nitrocellulose 17.5% to 22.5%
polyurethane 50% to 60%.
______________________________________
Claim 20
Dependent Claim
30 words
The electrically sprayable formulation of claim 15 for use in electrostatic spraying, at from 1 to 15 ml/min, and with resulting gloss of over 70 as defined by ASTM D523,60°.
Claim 21
Dependent Claim
24 words
The electrically sprayable formulation as claimed in claim 11 wherein the application rate is 1.5 to 10 g/s/cm 2 ×10 -5 dry paint film.
Claim 22
Dependent Claim
40 words
The electrically sprayable formulation as claimed in claim 15 wherein the viscosity/resistivity values fall within a rectilinear-sided operated envelope defined by the points x/y viscosity/resistivity values of 0.25×10 6 /0.25, 2×10 6 /8, 32×10 6 /4 and 35×10 6 /0.25.
Claim 23
Dependent Claim
22 words
A formulation as claimed in claim 18 wherein the application rate is 1.7 to 8.4 g/s/cm 2 ×10 -5 dry paint film.
References Cited (Backward Citations)
US3267057A
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DE1519258A1
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1998-11-13 | 1999-05-15 | 1999-11-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2002-11-13 | 2003-05-15 | 2003-11-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2006-11-13 | 2007-05-15 | 2007-11-14 | $7700.00 | Window Closed / Lapsed |