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Ceramic capacitor and method for fabricating the same

Assignee: Taiyo Yuden Co Ltd
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Filing: 1992-06-05
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Granted: 1995-09-26
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Expires: 2012-06-05
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Abstract

Abstract A miniaturized ceramic capacitor having excellent electric characteristics and substantial capacity can be obtained by firing under a non-oxidative atmosphere at a temperature of up to 1200° C. A dielectric layer of this ceramic capacitor consists of a basic component of 100 parts by weight and an additional component of 0.2 to 5 parts by weight. The basic component consists essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}k(Ti.sub.1-y-z Zr.sub.y R z )O 2-z/2 The additional component consists essentially of Li 2 O--SiO 2 --MO, B 2 O 3 --SiO 2 --MO or B 2 O 3 --SiO 2 --Li 2 O.

Inventors

  • 👤 Hiroshi Kishi
  • 👤 Hisamitsu Shizuno
  • 👤 Shinya Kusumi
  • 👤 Hiroshi Saito

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 16:45
CPC Classifications
H; H01; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/06; H01G4/08; H01G4/12; C; C04; C04B; C04B35/00; C04B35/01; C04B35/48; C04B35/49; H01G4/1209; H01G4/1236; H01G4/1245

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 117 words
A ceramic capacitor, comprising: at least one dielectric ceramic layer consisting essentially of a dielectric ceramic composition and at least two internal electrodes sandwiching said dielectric ceramic composition; said dielectric ceramic composition consisting essentially of a fired mixture of a basic component of 100 parts by weight and an additional component in the range of 0.2 to 5 parts by weight; said basic component consisting essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}.sub.k (Ti.sub.1-y-z Zr.sub.y R.sub.z)O.sub.2-z/2 where, R is one or more elements selected from the group consisting of Sc, Y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu; and w, x, y, z and k are numerals fulfilling the following conditions:
Claim 2
Dependent Claim 117 words
A ceramic capacitor, comprising: at least one dielectric ceramic layer consisting essentially of a dielectric ceramic composition and at least two internal electrodes sandwiching said dielectric ceramic composition; said dielectric ceramic composition consisting essentially of a fired mixture of a basic component of 100 parts by weight and an additional component in the range of 0.2 to 5 parts by weight; said basic component consisting essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}.sub.k (Ti.sub.1-y-z Zr.sub.y R.sub.z)O.sub.2-z/2 where, R is one or more elements selected from the group consisting of Sc, Y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu; and w, x, y, z and k are numerals fulfilling the following conditions:
Claim 3
Dependent Claim 226 words
00≦w≦0.27 0.001≦x≦0.03 0.05≦y≦0.26 0.002≦z≦0.04 1.00≦k≦1.04 said additional component consisting essentially of Li 2 O, SiO 2 and MO wherein said MO is at least one oxide selected from the group consisting of BaO, SrO, CaO, MgO and ZnO; and a ratio among amounts of Li 2 O, SiO 2 and MO in said additional component is within an area in a ternary system of mol % having five vertexes of first to fifth vertexes wherein: said first vertex A represents a condition in which amounts of Li 2 O is 1 mol %, SiO 2 is 80 mol % and MO is 19 mol %; said second vertex B represents a condition in which amounts of Li 2 O is 1 mol %, SiO 2 is 39 mol % and MO is 60 mol %; said third vertex C represents a condition in which amounts of Li 2 O is 30 mol %, SiO 2 is 30 mol % and MO is 40 mol %; said fourth vertex D represents a condition in which amounts of Li 2 O is 50 mol %, SiO 2 is 50 mol % and MO is 0 mol %; and said fifth vertex E represents a condition in which amounts of Li 2 O is 20 mol %, SiO 2 is 80 mol % and MO is 0 mol %.
Claim 4
Dependent Claim 226 words
00≦w≦0.27 0.001≦x≦0.03 0.05≦y≦0.26 0.002≦z≦0.04 1.00≦k≦1.04 said additional component consisting essentially of Li 2 O, SiO 2 and MO wherein said MO is at least one oxide selected from the group consisting of BaO, SrO, CaO, MgO and ZnO; and a ratio among amounts of Li 2 O, SiO 2 and MO in said additional component is within an area in a ternary system of mol % having five vertexes of first to fifth vertexes wherein: said first vertex A represents a condition in which amounts of Li 2 O is 1 mol %, SiO 2 is 80 mol % and MO is 19 mol %; said second vertex B represents a condition in which amounts of Li 2 O is 1 mol %, SiO 2 is 39 mol % and MO is 60 mol %; said third vertex C represents a condition in which amounts of Li 2 O is 30 mol %, SiO 2 is 30 mol % and MO is 40 mol %; said fourth vertex D represents a condition in which amounts of Li 2 O is 50 mol %, SiO 2 is 50 mol % and MO is 0 mol %; and said fifth vertex E represents a condition in which amounts of Li 2 O is 20 mol %, SiO 2 is 80 mol % and MO is 0 mol %.
Claim 5
Dependent Claim 116 words
A ceramic capacitor, comprising: at least one,dielectric ceramic layer consisting essentially of a dielectric ceramic composition and at least two internal electrodes sandwiching said dielectric ceramic composition; said dielectric ceramic composition consisting essentially of a fired mixture of a basic component of 100 parts by weight and an additional component in the range of 0.2 to 5 parts by weight; said basic component consisting essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}.sub.k (Ti.sub.1-y-z Zr.sub.y R.sub.z)O.sub.2-z-2 where, R is one or more elements selected from the group consisting of Sc, Y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu; and w, x, y, z and k are numerals fulfilling the following conditions:
Claim 6
Dependent Claim 116 words
A ceramic capacitor, comprising: at least one,dielectric ceramic layer consisting essentially of a dielectric ceramic composition and at least two internal electrodes sandwiching said dielectric ceramic composition; said dielectric ceramic composition consisting essentially of a fired mixture of a basic component of 100 parts by weight and an additional component in the range of 0.2 to 5 parts by weight; said basic component consisting essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}.sub.k (Ti.sub.1-y-z Zr.sub.y R.sub.z)O.sub.2-z-2 where, R is one or more elements selected from the group consisting of Sc, Y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu; and w, x, y, z and k are numerals fulfilling the following conditions:
Claim 7
Dependent Claim 267 words
00≦w≦0.27 0.001≦x≦0.03 0.05≦y≦0.26 0.002≦z≦0.04 1.00≦k≦1.04 said additional component consisting essentially of B 2 O 3 , SiO 2 and MO wherein said MO is at least one oxide selected from the group consisting of BaO, SrO, CaO, MgO and ZnO; and a ratio among amounts of B 2 O 3 , SiO 2 and MO in said additional component is within an area in a ternary system diagram of mol % having six vertexes of first to sixth vertexes, wherein: said first vertex F represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 80 mol % and MO is 19 mol %; said second vertex G represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 39 mol % and MO is 60 mol %; said third vertex H represents a condition in which amounts of B 2 O 3 is 30 mol %, SiO 2 is 0 mol % and MO is 70 mol %; said fourth vertex I represents a condition in which amounts of B 2 O 3 is 90 mol %, SiO 2 is 0 mol % and MO is 10 mol %; said fifth vertex J represents a condition in which amounts of B 2 O 3 is 90 mol %, SiO 2 is 10 mol % and MO is 0 mol %; and said sixth vertex K represents a condition in which amounts of B 2 O 3 is 20 mol %, SiO 2 is 80 mol % and MO is 0 mol %.
Claim 8
Dependent Claim 267 words
00≦w≦0.27 0.001≦x≦0.03 0.05≦y≦0.26 0.002≦z≦0.04 1.00≦k≦1.04 said additional component consisting essentially of B 2 O 3 , SiO 2 and MO wherein said MO is at least one oxide selected from the group consisting of BaO, SrO, CaO, MgO and ZnO; and a ratio among amounts of B 2 O 3 , SiO 2 and MO in said additional component is within an area in a ternary system diagram of mol % having six vertexes of first to sixth vertexes, wherein: said first vertex F represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 80 mol % and MO is 19 mol %; said second vertex G represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 39 mol % and MO is 60 mol %; said third vertex H represents a condition in which amounts of B 2 O 3 is 30 mol %, SiO 2 is 0 mol % and MO is 70 mol %; said fourth vertex I represents a condition in which amounts of B 2 O 3 is 90 mol %, SiO 2 is 0 mol % and MO is 10 mol %; said fifth vertex J represents a condition in which amounts of B 2 O 3 is 90 mol %, SiO 2 is 10 mol % and MO is 0 mol %; and said sixth vertex K represents a condition in which amounts of B 2 O 3 is 20 mol %, SiO 2 is 80 mol % and MO is 0 mol %.
Claim 9
Dependent Claim 380 words
A ceramic capacitor, comprising: at lease one dielectric ceramic layer consisting essentially of a dielectric ceramic composition and at least two internal electrodes sandwiching said dielectric ceramic composition; said dielectric ceramic composition consisting essentially of a fired mixture of a basic component of 100 parts by weight and an additional component in the range of 0.2 to 5 parts by weight; said basic component consisting essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}.sub.k (Ti.sub.1-y-z Zr.sub.y R.sub.z)O.sub.2-z/2 where, R is one or more elements selected from the group consisting of Sc, Y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu; and w, x, y, z and k are numerals fulfilling the following conditions: 0.00≦w≦0.27 0.001≦x≦0.03 0.05≦y≦0.26 0.002≦z≦0.04 1.00≦k≦1.04 said additional component consisting essentially of B 2 O 3 , SiO 2 and Li 2 O; and a ratio among amounts of B 2 O 3 , SiO 2 and Li 2 O in said additional component is within an area in a ternary system diagram of mol % having six vertexes of first to sixth vertexes wherein: said first vertex L represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 50 mol % and Li 2 O is 49 mol %; said second vertex M represents a condition in which amounts of B 2 O 3 is 50 mol %, SiO 2 is 1 mol % and Li 2 O is 49 mol %; said third vertex N represents a condition in which amounts of B 2 O 3 is 80 mol %, SiO 2 is 1 mol % and Li 2 O is 19 mol %; said fourth vertex O represents a condition in which amounts of B 2 O 3 is 89 mol %, SiO 2 is 10 mol % and Li 2 O is 1 mol %; said fifth vertex P represents a condition in which amounts of B 2 O 3 is 19 mol %, SiO 2 is 80 mol % and Li 2 O is 1 mol %; and said sixth vertex Q represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 80 mol % and Li 2 O is 19 mol %.
Claim 10
Dependent Claim 380 words
A ceramic capacitor, comprising: at lease one dielectric ceramic layer consisting essentially of a dielectric ceramic composition and at least two internal electrodes sandwiching said dielectric ceramic composition; said dielectric ceramic composition consisting essentially of a fired mixture of a basic component of 100 parts by weight and an additional component in the range of 0.2 to 5 parts by weight; said basic component consisting essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}.sub.k (Ti.sub.1-y-z Zr.sub.y R.sub.z)O.sub.2-z/2 where, R is one or more elements selected from the group consisting of Sc, Y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu; and w, x, y, z and k are numerals fulfilling the following conditions: 0.00≦w≦0.27 0.001≦x≦0.03 0.05≦y≦0.26 0.002≦z≦0.04 1.00≦k≦1.04 said additional component consisting essentially of B 2 O 3 , SiO 2 and Li 2 O; and a ratio among amounts of B 2 O 3 , SiO 2 and Li 2 O in said additional component is within an area in a ternary system diagram of mol % having six vertexes of first to sixth vertexes wherein: said first vertex L represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 50 mol % and Li 2 O is 49 mol %; said second vertex M represents a condition in which amounts of B 2 O 3 is 50 mol %, SiO 2 is 1 mol % and Li 2 O is 49 mol %; said third vertex N represents a condition in which amounts of B 2 O 3 is 80 mol %, SiO 2 is 1 mol % and Li 2 O is 19 mol %; said fourth vertex O represents a condition in which amounts of B 2 O 3 is 89 mol %, SiO 2 is 10 mol % and Li 2 O is 1 mol %; said fifth vertex P represents a condition in which amounts of B 2 O 3 is 19 mol %, SiO 2 is 80 mol % and Li 2 O is 1 mol %; and said sixth vertex Q represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 80 mol % and Li 2 O is 19 mol %.
Claim 11
Independent Claim 155 words
A method for fabricating a ceramic capacitor, comprising the steps of: providing a mixture of non-sintered ceramic powder; forming a non-sintered ceramic sheet consisting of said mixture; fabricating a laminated structure in which said non-sintered ceramic sheet is sandwiched between at least two conductive paste layers; firing said laminated structure under a non-oxidative atmosphere; and heating said fired laminated structure under an oxidative atmosphere; said mixture of non-sintered ceramic powder consisting essentially of a fired mixture of a basic component of 100 parts by weight and an additional component in the range of 0.2 to 5 parts by weight; said basic component consisting essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}.sub.k (Ti.sub.1-y-z Zr.sub.y R.sub.z)O.sub.2-z/2 where, R is one or more elements selected from the group consisting of Sc, Y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu; and w, x, y, z and k are numerals fulfilling the following conditions:
Claim 12
Independent Claim 155 words
A method for fabricating a ceramic capacitor, comprising the steps of: providing a mixture of non-sintered ceramic powder; forming a non-sintered ceramic sheet consisting of said mixture; fabricating a laminated structure in which said non-sintered ceramic sheet is sandwiched between at least two conductive paste layers; firing said laminated structure under a non-oxidative atmosphere; and heating said fired laminated structure under an oxidative atmosphere; said mixture of non-sintered ceramic powder consisting essentially of a fired mixture of a basic component of 100 parts by weight and an additional component in the range of 0.2 to 5 parts by weight; said basic component consisting essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}.sub.k (Ti.sub.1-y-z Zr.sub.y R.sub.z)O.sub.2-z/2 where, R is one or more elements selected from the group consisting of Sc, Y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu; and w, x, y, z and k are numerals fulfilling the following conditions:
Claim 13
Dependent Claim 227 words
00≦w≦0.27 0.001≦x≦0.03 0.05≦y≦0.26 0.002≦z≦0.04 1.00≦k≦1.04 said additional component consisting essentially of Li 2 O, SiO 2 and MO wherein said MO is at least one oxide selected from the group consisting of BaO, SrO, CaO, MgO and ZnO; and a ratio among amounts of Li 2 O, SiO 2 and MO in said additional component is within an area in a ternary system diagram of mol % having five vertexes of first to fifth vertexes, wherein: said first vertex A represents a condition in which amounts of Li 2 O is 1 mol %, SiO 2 is 80 mol % and MO is 19 mol %; said second vertex B represents a condition in which amounts of Li 2 O is 1 mol %, SiO 2 is 39 mol % and MO is 60 mol %; said third vertex C represents a condition in which amounts of Li 2 O is 30 mol %, SiO 2 is 30 mol % and MO is 40 mol %; said fourth vertex D represents a condition in which amounts of Li 2 O is 50 mol %, SiO 2 is 50 mol % and MO is 0 mol %; and said fifth vertex E represents a condition in which amounts of Li 2 O is 20 mol %, SiO 2 is 80 mol % and MO is 0 mol %.
Claim 14
Dependent Claim 227 words
00≦w≦0.27 0.001≦x≦0.03 0.05≦y≦0.26 0.002≦z≦0.04 1.00≦k≦1.04 said additional component consisting essentially of Li 2 O, SiO 2 and MO wherein said MO is at least one oxide selected from the group consisting of BaO, SrO, CaO, MgO and ZnO; and a ratio among amounts of Li 2 O, SiO 2 and MO in said additional component is within an area in a ternary system diagram of mol % having five vertexes of first to fifth vertexes, wherein: said first vertex A represents a condition in which amounts of Li 2 O is 1 mol %, SiO 2 is 80 mol % and MO is 19 mol %; said second vertex B represents a condition in which amounts of Li 2 O is 1 mol %, SiO 2 is 39 mol % and MO is 60 mol %; said third vertex C represents a condition in which amounts of Li 2 O is 30 mol %, SiO 2 is 30 mol % and MO is 40 mol %; said fourth vertex D represents a condition in which amounts of Li 2 O is 50 mol %, SiO 2 is 50 mol % and MO is 0 mol %; and said fifth vertex E represents a condition in which amounts of Li 2 O is 20 mol %, SiO 2 is 80 mol % and MO is 0 mol %.
Claim 15
Independent Claim 156 words
A method for fabricating a ceramic capacitor, comprising the steps of: providing a mixture of non-sintered ceramic powder; forming a non-sintered ceramic sheet consisting of said mixture; fabricating a laminated structure in which said non-sintered ceramic sheet is sandwiched between at least two conductive paste layers; firing said laminated structure under a non-oxidative atmosphere; and heating said fired laminated structure under an oxidative atmosphere; said mixture of non-sintered ceramic powder consisting essentially of a fired mixture of a basic component of 100 parts by weight and an additional component in the range of 0.2 to 5 parts by weight; said basic component consisting essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}.sub.k (Ti.sub.1-y-z Zr.sub.y R.sub.z)O.sub.2-z/2 where, R is one or more metal elements selected from the group consisting of Sc, Y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu; and w, x, y, z and k are numerals fulfilling the following conditions:
Claim 16
Independent Claim 156 words
A method for fabricating a ceramic capacitor, comprising the steps of: providing a mixture of non-sintered ceramic powder; forming a non-sintered ceramic sheet consisting of said mixture; fabricating a laminated structure in which said non-sintered ceramic sheet is sandwiched between at least two conductive paste layers; firing said laminated structure under a non-oxidative atmosphere; and heating said fired laminated structure under an oxidative atmosphere; said mixture of non-sintered ceramic powder consisting essentially of a fired mixture of a basic component of 100 parts by weight and an additional component in the range of 0.2 to 5 parts by weight; said basic component consisting essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}.sub.k (Ti.sub.1-y-z Zr.sub.y R.sub.z)O.sub.2-z/2 where, R is one or more metal elements selected from the group consisting of Sc, Y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu; and w, x, y, z and k are numerals fulfilling the following conditions:
Claim 17
Dependent Claim 269 words
00≦w≦0.27 0.001≦x≦0.03 0.05≦y≦0.26 0.002≦z≦0.04 1.00≦k≦1.04 said additional component consisting essentially of B 2 O 3 , SiO 2 and MO wherein said MO is at least one oxide selected from the group consisting of BaO, SrO, CaO, MgO and ZnO; and a ratio among amounts of B 2 O 3 , SiO 2 and MO in said additional component is within an area in a ternary system diagram of mol % having six vertexes of first to sixth vertexes wherein: said first vertex F represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 80 mol % and MO is 19 mol %; said second vertex G represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 39 mol % and MO is 60 mol %; said third vertex H represents a condition in which amounts of B 2 O 3 is 30 mol %, SiO 2 is 0 mol % and Li 2 O is 70 mol %; said fourth vertex I represents a condition in which amounts of B 2 O 3 is 90 mol %, SiO 2 is 0 mol % and MO is 10 mol %; said fifth vertex J represents a condition in which amounts of B 2 O 3 is 90 mol %, SiO 2 is 10 mol % and MO is 0 mol %; and said sixth vertex K represents a condition in which amounts of B 2 O 3 is 20 mol %, SiO 2 is 80 mol % and MO is 0 mol %.
Claim 18
Dependent Claim 269 words
00≦w≦0.27 0.001≦x≦0.03 0.05≦y≦0.26 0.002≦z≦0.04 1.00≦k≦1.04 said additional component consisting essentially of B 2 O 3 , SiO 2 and MO wherein said MO is at least one oxide selected from the group consisting of BaO, SrO, CaO, MgO and ZnO; and a ratio among amounts of B 2 O 3 , SiO 2 and MO in said additional component is within an area in a ternary system diagram of mol % having six vertexes of first to sixth vertexes wherein: said first vertex F represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 80 mol % and MO is 19 mol %; said second vertex G represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 39 mol % and MO is 60 mol %; said third vertex H represents a condition in which amounts of B 2 O 3 is 30 mol %, SiO 2 is 0 mol % and Li 2 O is 70 mol %; said fourth vertex I represents a condition in which amounts of B 2 O 3 is 90 mol %, SiO 2 is 0 mol % and MO is 10 mol %; said fifth vertex J represents a condition in which amounts of B 2 O 3 is 90 mol %, SiO 2 is 10 mol % and MO is 0 mol %; and said sixth vertex K represents a condition in which amounts of B 2 O 3 is 20 mol %, SiO 2 is 80 mol % and MO is 0 mol %.
Claim 19
Independent Claim 420 words
A method for fabricating a ceramic capacitor, comprising the steps of: providing a mixture of non-sintered ceramic powder; forming a non-sintered ceramic sheet consisting of said mixture; fabricating a laminated structure in which said non-sintered ceramic sheet is sandwiched between at least two conductive paste layers; firing said laminated structure under a non-oxidative atmosphere; and heating said fired laminated structure under an oxidative atmosphere; said mixture of non-sintered ceramic powder consisting essentially of a fired mixture of a basic component of 100 parts by weight and an additional component in the range of 0.2 to 5 parts by weight; said basic component consisting essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}.sub.k (Ti.sub.1-y-z Zr.sub.y R.sub.z)O.sub.2-z/2 where, R is one or more metal elements selected from the group consisting of Sc, i y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu; and w, x, y, z and k are numerals fulfilling the following conditions: 0.00≦w≦0.27 0.001≦x≦0.03 0.05≦y≦0.26 0.002≦z≦0.04 1.00≦k≦1.04 said additional component consisting essentially of B 2 O 3 , SiO 2 and Li 2 O; and a ratio among amounts of B 2 O 3 , SiO 2 and Li 2 O in said additional component is within an area in a ternary system diagram of mol % having six vertexes of first to sixth vertexes wherein: said first vertex L represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 50 mol % and Li 2 O is 49 mol %; said second vertex M represents a condition in which amounts of B 2 O 3 is 50 mol %, SiO 2 is 1 mol % and Li 2 O is 49 mol %; said third vertex N represents a condition in which amounts of B 2 O 3 is 80 mol %, SiO 2 is 1 mol % and Li 2 O is 19 mol %; said fourth vertex O represents a condition in which amounts of B 2 O 3 is 89 mol %, SiO 2 is 10 mol % and Li 2 O is 1 mol %; said fifth vertex P represents a condition in which amounts of B 2 O 3 is 19 mol %, SiO 2 is 80 mol % and Li 2 O is 1 mol %; and said sixth vertex Q represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 80 mol % and Li 2 O is 19 mol %.
Claim 20
Independent Claim 420 words
A method for fabricating a ceramic capacitor, comprising the steps of: providing a mixture of non-sintered ceramic powder; forming a non-sintered ceramic sheet consisting of said mixture; fabricating a laminated structure in which said non-sintered ceramic sheet is sandwiched between at least two conductive paste layers; firing said laminated structure under a non-oxidative atmosphere; and heating said fired laminated structure under an oxidative atmosphere; said mixture of non-sintered ceramic powder consisting essentially of a fired mixture of a basic component of 100 parts by weight and an additional component in the range of 0.2 to 5 parts by weight; said basic component consisting essentially of a material represented by the following formula: {(Ba.sub.1-w-x Ca.sub.w Mg.sub.x)O}.sub.k (Ti.sub.1-y-z Zr.sub.y R.sub.z)O.sub.2-z/2 where, R is one or more metal elements selected from the group consisting of Sc, i y, Gd, Dy, Ho, Er, Yb, Tb, Tm and Lu; and w, x, y, z and k are numerals fulfilling the following conditions: 0.00≦w≦0.27 0.001≦x≦0.03 0.05≦y≦0.26 0.002≦z≦0.04 1.00≦k≦1.04 said additional component consisting essentially of B 2 O 3 , SiO 2 and Li 2 O; and a ratio among amounts of B 2 O 3 , SiO 2 and Li 2 O in said additional component is within an area in a ternary system diagram of mol % having six vertexes of first to sixth vertexes wherein: said first vertex L represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 50 mol % and Li 2 O is 49 mol %; said second vertex M represents a condition in which amounts of B 2 O 3 is 50 mol %, SiO 2 is 1 mol % and Li 2 O is 49 mol %; said third vertex N represents a condition in which amounts of B 2 O 3 is 80 mol %, SiO 2 is 1 mol % and Li 2 O is 19 mol %; said fourth vertex O represents a condition in which amounts of B 2 O 3 is 89 mol %, SiO 2 is 10 mol % and Li 2 O is 1 mol %; said fifth vertex P represents a condition in which amounts of B 2 O 3 is 19 mol %, SiO 2 is 80 mol % and Li 2 O is 1 mol %; and said sixth vertex Q represents a condition in which amounts of B 2 O 3 is 1 mol %, SiO 2 is 80 mol % and Li 2 O is 19 mol %.

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