US5447694A
Expired / Lapsed
US
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Exhaust gas conversion method and apparatus using thermally stable zeolites
Assignee: Corning Inc
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Filing: 1994-01-18
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Granted: 1995-09-05
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Expires: 2014-01-18
Abstract
Abstract A system and method are disclosed for converting exhaust gas which comprises NO x , CO, and hydrocarbons, to innocuous products. Exhaust gas is contacted in undiverted flow with a zeolite suitable for adsorption of hydrocarbons, and with a main catalyst suitable for conversion of NO x , CO, and hydrocarbons to innocuous products. Adsorption occurs when the temperature of the zeolite is suitable therefor. Conversion occurs when the temperature of the main catalyst is suitable therefor. The zeolite and main catalyst are connected directly to one another, that is, in-line, without by-pass valving. The zeolite can be Y zeolite, Beta, ZSM-5, and combinations thereof, and has a SiO 2 to Al 2 O 3 mole ratio of no greater than about 200, and is ion exchanged with a metal which can be rare earth, chromium, and combinations thereof.
Inventors
- 👤 Srinivas H. Swaroop
- 👤 Raja R. Wusirika
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 21:19
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9445; B01D53/945; B01D53/02; B01D53/04; B01D53/0454; B01D53/9481; F; F01; F01N; F01N13/00; F01N13/009; F01N13/0097; F01N3/00; F01N3/08; F01N3/0807; F01N3/0814; F01N3/0828; F01N3/0835; F01N3/0871; F01N2250/00; F01N2250/12; F01N2370/00; F01N2370/22; F01N2370/24; F01N2570/00; F01N2570/14; F01N3/10; F01N3/18; F01N3/20; F01N3/24; F01N3/30; F01N3/32; Y; Y02; Y02A; Y02A50/00; Y02A50/20; Y02T; Y02T10/00; Y02T10/10; Y02T10/12
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
141 words
An apparatus suitable for converting exhaust gases from an exhaust gas generating source, to innocuous products, said apparatus comprising: a) a zeolite unit for adsorbing hydrocarbons, said zeolite being selected from the group consisting of Y zeolite, Beta, ZSM-5, mordenite, and combinations thereof, and having a SiO 2 to Al 2 O 3 mole ratio of no greater than about 200, said zeolite being ion exchanged with a metal consisting of chromium, wherein the chromium content in the zeolite is greater than about 0.5% by weight; b) a main catalyst unit for converting NO x , CO, and hydrocarbons to innocuous products positioned downstream from said zeolite unit; and c) conduit means for connecting said units with one another and with said source, and for providing undiverted passage of said exhaust gas from said source sequentially to and through said units.
Claim 2
Independent Claim
141 words
An apparatus suitable for converting exhaust gases from an exhaust gas generating source, to innocuous products, said apparatus comprising: a) a zeolite unit for adsorbing hydrocarbons, said zeolite being selected from the group consisting of Y zeolite, Beta, ZSM-5, mordenite, and combinations thereof, and having a SiO 2 to Al 2 O 3 mole ratio of no greater than about 200, said zeolite being ion exchanged with a metal consisting of chromium, wherein the chromium content in the zeolite is greater than about 0.5% by weight; b) a main catalyst unit for converting NO x , CO, and hydrocarbons to innocuous products positioned downstream from said zeolite unit; and c) conduit means for connecting said units with one another and with said source, and for providing undiverted passage of said exhaust gas from said source sequentially to and through said units.
Claim 3
Dependent Claim
11 words
An apparatus of claim 1 wherein said zeolite is a Y-type.
Claim 4
Dependent Claim
14 words
An apparatus of claim 1 wherein said ratio is no greater than about 100.
Claim 5
Dependent Claim
15 words
An apparatus of claim 3 wherein said mole ratio is about 3 to about 100.
Claim 6
Dependent Claim
14 words
An apparatus of claim 3 wherein said ratio is about 3 to about 20.
Claim 7
Dependent Claim
23 words
An apparatus of claim 1 wherein the alkali content of said zeolite is less than about 0.5% by weight based on the oxide.
Claim 8
Dependent Claim
17 words
An apparatus of claim 5 wherein said alkali content is no greater than about 0.25% by weight.
Claim 9
Dependent Claim
14 words
An apparatus of claim 1 wherein said zeolite is in contact with a substrate.
Claim 10
Dependent Claim
12 words
An apparatus of claim 8 wherein said substrate is a honeycomb structure.
Claim 11
Dependent Claim
16 words
An apparatus of claim 1 wherein said chromium content is greater than about 1.0% by weight.
Claim 12
Dependent Claim
16 words
An apparatus of claim 10 wherein said chromium content is greater than about 2.0% by weight.
References Cited (Backward Citations)
US5185305A
Cited
EP0541271A1
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1998-09-04 | 1999-03-06 | 1999-09-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2002-09-04 | 2003-03-06 | 2003-09-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2006-09-04 | 2007-03-06 | 2007-09-05 | $7700.00 | Window Closed / Lapsed |