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US5437952A Expired / Lapsed US ⏱️ 0.0 years remaining

Lithographic photosensitive printing plate comprising a photoconductor and a naphtho-quinone diazide sulfonic acid ester of a phenol resin

Assignee: Konica Minolta Inc
•
Filing: 1993-02-26
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Granted: 1995-08-01
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Expires: 2013-02-26
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Abstract

Abstract A photosensitive lithographic printing plate comprises a conductive support and provided thereon, a photoconductive layer of a composition comprising a photoconductor and an esterified compound of o-naphtho-quinonediazide sulfonic acid with a phenol resin, the phenol resin being a polycondensation compound of a monovalent phenol with an aldehyde or a ketone, and the content of the o-naphthoquinonediazide sulfonic acid residue being 0.4×10 -3 to 3.0×10 -3 mole per gram of the photoconductive layer.

Inventors

  • 👤 Katsura Hirai
  • 👤 Yasuo Kojima
  • 👤 Kiyoshi Goto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 16:59
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/05; G03G5/0528; G03G5/0557; G03G5/0567; G03F; G03F7/00; G03F7/004; G03F7/09; G03F7/095; G03G13/00; G03G13/26; G03G13/28; G03G5/0503; G03G5/051; G03G5/0517; G03G5/153

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 73 words
A photosensitive lithographic printing plate comprising a conductive support and provided thereon, a photoconductive layer of a composition comprising a photoconductor and an esterified compound of o-naphthoquinonediazide sulfonic acid with a phenol resin, wherein the phenol resin is a polycondensation compound of m-cresol or p-cresol with an aldehyde or a ketone, and the content of the o-naphthoquinonediazide sulfonic acid residue is 0.4×10 -3 to 3.0×10 -3 mole per gram of the photoconductive layer.
Claim 2
Dependent Claim 73 words
A photosensitive lithographic printing plate comprising a conductive support and provided thereon, a photoconductive layer of a composition comprising a photoconductor and an esterified compound of o-naphthoquinonediazide sulfonic acid with a phenol resin, wherein the phenol resin is a polycondensation compound of m-cresol or p-cresol with an aldehyde or a ketone, and the content of the o-naphthoquinonediazide sulfonic acid residue is 0.4×10 -3 to 3.0×10 -3 mole per gram of the photoconductive layer.
Claim 3
Dependent Claim 86 words
A photosensitive lithographic printing plate comprising a conductive support and provided thereon, a photoconductive layer of a composition comprising a photoconductor and an esterified compound of o-naphthoquinonediazide sulfonic acid with a phenol resin, wherein the phenol resin is a polycondensation compound of a monovalent phenol with an aldehyde or a ketone, the sulfonic acid group is present at the 4-position of the o-naphthoquinonediazide sulfonic acid and the content of the o-naphthoquinonediazide sulfonic acid is 0.4×10 -3 to 3.0×10 -3 mol per gram of the photoconductive layer.
Claim 4
Dependent Claim 86 words
A photosensitive lithographic printing plate comprising a conductive support and provided thereon, a photoconductive layer of a composition comprising a photoconductor and an esterified compound of o-naphthoquinonediazide sulfonic acid with a phenol resin, wherein the phenol resin is a polycondensation compound of a monovalent phenol with an aldehyde or a ketone, the sulfonic acid group is present at the 4-position of the o-naphthoquinonediazide sulfonic acid and the content of the o-naphthoquinonediazide sulfonic acid is 0.4×10 -3 to 3.0×10 -3 mol per gram of the photoconductive layer.
Claim 5
Dependent Claim 12 words
The printing plate of claim 1, wherein the monovalent phenol is p-cresol.
Claim 6
Dependent Claim 29 words
The printing plate of claim 1, wherein the condensation ratio of the o-naphthoquinonediazide sulfonic acid to the hydroxyl group in the phenol resin is 15 to 80 mole %.
Claim 7
Dependent Claim 30 words
The printing plate of claim 1, wherein the photoconductive layer further contains an alkali-soluble resin which is a polycondensation product of a monovalent phenol with an aldehyde or a ketone.
Claim 8
Dependent Claim 33 words
The printing plate of claim 5, wherein the alkali-soluble resin comprises a novolak resin and the novolak resin is contained in an amount of 5 to 70% by weight of the photoconductive layer.
Claim 9
Dependent Claim 21 words
The printing plate of claim 5, wherein the novolak resin comprises a polycondensation product of phenol, m-cresol and p-cresol with formaldehyde.
Claim 10
Dependent Claim 24 words
The printing plate of claim 1, wherein the photoconductor is contained in an amount of 3 to 50% by weight of the photoconductive layer.
Claim 11
Dependent Claim 23 words
The printing plate of claim 1, wherein the sulfonic acid group is present at the 4- or 5-position of the o-naphthoquinonediazide sulfonic acid.
Claim 12
Dependent Claim 99 words
The printing plate of claim 1, wherein the printing plate is manufactured by the method comprising the steps of: dissolving the composition in a solvent, the solvent being selected from the group consisting of propylene glycol monoalkyl ether, the alkyl of which has 1 to 3 carbon atoms; propylene glycol monoalkyl ether acetate, the alkyl of which has 1 to 3 carbon atoms; diethylene glycol dialkyl ether, the alkyl of which has 1 to 2 carbon atoms; and ethylene glycol monopropyl ether; coating the resulting solution on the support+; and drying the coated solution to form the photoconductive layer.
Claim 13
Dependent Claim 39 words
The printing plate of claim 10, wherein the solvent is selected from the group consisting of propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, diethylene glycol dimethyl ether, diethylene glycol methyl ethyl ether and ethylene glycol monopropyl ether.
Claim 14
Dependent Claim 14 words
The printing plate of claim 1, wherein the photoconductor is an organic photoconductive pigment.
Claim 15
Dependent Claim 14 words
The printing plate of claim 12, wherein the organic photoconductive pigment is phthalocyanine pigment.
Claim 16
Dependent Claim 15 words
The printing plate of claim 12, wherein the organic photoconductive pigment is ε-type phthalocyanine pigment.

References Cited (Backward Citations)

US3635709A Cited
US3658662A Cited
US4544627A Cited
US4897329A Cited
US4492740A Cited
US4840869A Cited
US4680244A Cited
US4933248A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-07-31 1999-01-30 1999-08-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-07-31 2003-01-30 2003-08-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-07-31 2007-01-30 2007-08-01 $7700.00 Window Closed / Lapsed

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